Abstract: In this study, functionalized magnetic nanoparticles of poly (ionic liquid) 1-allyl-3-methylimidazolium chloride were prepared through free radical copolymerization method and tested as a high efficient adsorbent for the removal of anionic dyes in water samples. The physical and chemical structure of prepared magnetic nanoparticles (MNPs) were investigated using Fourier transform infrared spectroscopy (FT-IR), X-ray powder diffraction (XRD), transmission electron microscopy (TEM) and scanning electron microscopy (SEM). Next, synthesized magnetic nanoparticles were used in magnetic solid phase extraction (MSPE) method to extract three anionic dyes (Alizarin Red S, Congo Red and Methyl Orange) in water samples. Also, the effect of several parameters such as pH, temperature, contact time and amount of adsorbent was investigated and the optimum values were determined. In addition, the adsorbent has a high ability to remove anionic dyes from water samples containing different dyes. Limit of detection (LOD), limit of quantitation (LOQ), and correlation coefficient were determined for methyl orange, Congo red and alizarin red S dyes under optimum conditions. The synthesized magnetic nanoparticles can be collected by an external magnetic field and regenerated with an alkaline solution (NaOH) and reused. The obtained results showed that the MNPs@PIL method was very efficient and successful in removing dye pollutants in water samples.Abstract: In this study, functionalized magnetic nanoparticles of poly (ionic liquid) 1-allyl-3-methylimidazolium chloride were prepared through free radical copolymerization method and tested as a high efficient adsorbent for the removal of anionic dyes in water samples. The physical and chemical structure of prepared magnetic nanoparticles (MNPs) were inve...Show More
Abstract: N-Alkyl-C1-dialkyl chains iminocyclitols with D or L-ribitol stereochemistry are synthesized with high diastereoselectivity after Grignard reagents addition to N-quaternary pyrrolines salts, and tested for antiviral activity in bovine viral diarrhea virus (BVDV), surrogate for hepatitis C virus (HCV). Dihedral angles are calculated from carbon chemical shift (δCn[ppm]) with 3-sphere method without building units. 3-Sphere, a hypersphere in 4D, under Hopf fibration and Lie algebra mathematics theories enable calculation of the dihedral angles from the NMR data (vicinal coupling constant 3JHnHn+1[Hz], chemical shift δCn[ppm]). Instead of 3D manifold equations on seven sets unit or six sets units are proposed equations between 4D – 2D, in function of the curvature. The relationship between the antiviral activity and the iminocyclitol structure reveals that monoalkyl chain, N-n-C1-dodecyl β-L-ribitol trifloroacetate salt 30 (IC50 1.5 uM) has higher antiviral activity in tangential space, relative to three alkyl chain, N-Methyl-C1-butil, nonyl-L-ribitol. HCl 26 (IC50 < 2 uM) with torus and Dupin cyclide coordinate, both with coordinates in 2D. Three alkyl chain isopropylidene protected pyrrolidine 25 has in 4D with all equations for calculation of the dihedral angles, and in protected pyrroline 19b double bond moves the coordinates in 2D.Abstract: N-Alkyl-C1-dialkyl chains iminocyclitols with D or L-ribitol stereochemistry are synthesized with high diastereoselectivity after Grignard reagents addition to N-quaternary pyrrolines salts, and tested for antiviral activity in bovine viral diarrhea virus (BVDV), surrogate for hepatitis C virus (HCV). Dihedral angles are calculated from carbon chem...Show More
