Separation and Preconcentration of Anionic Dyes Using Magnetic Nanoparticles with Modify Polymer Ionic Liquid

Mahboobeh Falahati; Majid Soleimani; Fateme Aflatouni

doi:doi:10.11648/j.ajhc.20230901.11

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Separation and Preconcentration of Anionic Dyes Using Magnetic Nanoparticles with Modify Polymer Ionic Liquid

Mahboobeh Falahati, Majid Soleimani, Fateme Aflatouni

Published in American Journal of Heterocyclic Chemistry (Volume 9, Issue 1)

Received: 22 January 2023 Accepted: 7 April 2023 Published: 20 April 2023

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Abstract

In this study, functionalized magnetic nanoparticles of poly (ionic liquid) 1-allyl-3-methylimidazolium chloride were prepared through free radical copolymerization method and tested as a high efficient adsorbent for the removal of anionic dyes in water samples. The physical and chemical structure of prepared magnetic nanoparticles (MNPs) were investigated using Fourier transform infrared spectroscopy (FT-IR), X-ray powder diffraction (XRD), transmission electron microscopy (TEM) and scanning electron microscopy (SEM). Next, synthesized magnetic nanoparticles were used in magnetic solid phase extraction (MSPE) method to extract three anionic dyes (Alizarin Red S, Congo Red and Methyl Orange) in water samples. Also, the effect of several parameters such as pH, temperature, contact time and amount of adsorbent was investigated and the optimum values were determined. In addition, the adsorbent has a high ability to remove anionic dyes from water samples containing different dyes. Limit of detection (LOD), limit of quantitation (LOQ), and correlation coefficient were determined for methyl orange, Congo red and alizarin red S dyes under optimum conditions. The synthesized magnetic nanoparticles can be collected by an external magnetic field and regenerated with an alkaline solution (NaOH) and reused. The obtained results showed that the MNPs@PIL method was very efficient and successful in removing dye pollutants in water samples.

Published in	American Journal of Heterocyclic Chemistry (Volume 9, Issue 1)
DOI	10.11648/j.ajhc.20230901.11
Page(s)	1-8
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2023. Published by Science Publishing Group

Keywords

Poly (Ionic Liquid), Magnetic Solid-Phase Extraction (MSPE), Fe₃O₄, Nanoparticles, Alizarin Red S, Congo Red, Methyl Orange

References

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APA Style

Mahboobeh Falahati, Majid Soleimani, Fateme Aflatouni. (2023). Separation and Preconcentration of Anionic Dyes Using Magnetic Nanoparticles with Modify Polymer Ionic Liquid. American Journal of Heterocyclic Chemistry, 9(1), 1-8. https://doi.org/10.11648/j.ajhc.20230901.11

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ACS Style

Mahboobeh Falahati; Majid Soleimani; Fateme Aflatouni. Separation and Preconcentration of Anionic Dyes Using Magnetic Nanoparticles with Modify Polymer Ionic Liquid. Am. J. Heterocycl. Chem. 2023, 9(1), 1-8. doi: 10.11648/j.ajhc.20230901.11

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AMA Style

Mahboobeh Falahati, Majid Soleimani, Fateme Aflatouni. Separation and Preconcentration of Anionic Dyes Using Magnetic Nanoparticles with Modify Polymer Ionic Liquid. Am J Heterocycl Chem. 2023;9(1):1-8. doi: 10.11648/j.ajhc.20230901.11

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@article{10.11648/j.ajhc.20230901.11,
  author = {Mahboobeh Falahati and Majid Soleimani and Fateme Aflatouni},
  title = {Separation and Preconcentration of Anionic Dyes Using Magnetic Nanoparticles with Modify Polymer Ionic Liquid},
  journal = {American Journal of Heterocyclic Chemistry},
  volume = {9},
  number = {1},
  pages = {1-8},
  doi = {10.11648/j.ajhc.20230901.11},
  url = {https://doi.org/10.11648/j.ajhc.20230901.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajhc.20230901.11},
  abstract = {In this study, functionalized magnetic nanoparticles of poly (ionic liquid) 1-allyl-3-methylimidazolium chloride were prepared through free radical copolymerization method and tested as a high efficient adsorbent for the removal of anionic dyes in water samples. The physical and chemical structure of prepared magnetic nanoparticles (MNPs) were investigated using Fourier transform infrared spectroscopy (FT-IR), X-ray powder diffraction (XRD), transmission electron microscopy (TEM) and scanning electron microscopy (SEM). Next, synthesized magnetic nanoparticles were used in magnetic solid phase extraction (MSPE) method to extract three anionic dyes (Alizarin Red S, Congo Red and Methyl Orange) in water samples. Also, the effect of several parameters such as pH, temperature, contact time and amount of adsorbent was investigated and the optimum values were determined. In addition, the adsorbent has a high ability to remove anionic dyes from water samples containing different dyes. Limit of detection (LOD), limit of quantitation (LOQ), and correlation coefficient were determined for methyl orange, Congo red and alizarin red S dyes under optimum conditions. The synthesized magnetic nanoparticles can be collected by an external magnetic field and regenerated with an alkaline solution (NaOH) and reused. The obtained results showed that the MNPs@PIL method was very efficient and successful in removing dye pollutants in water samples.},
 year = {2023}
}

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TY  - JOUR
T1  - Separation and Preconcentration of Anionic Dyes Using Magnetic Nanoparticles with Modify Polymer Ionic Liquid
AU  - Mahboobeh Falahati
AU  - Majid Soleimani
AU  - Fateme Aflatouni
Y1  - 2023/04/20
PY  - 2023
N1  - https://doi.org/10.11648/j.ajhc.20230901.11
DO  - 10.11648/j.ajhc.20230901.11
T2  - American Journal of Heterocyclic Chemistry
JF  - American Journal of Heterocyclic Chemistry
JO  - American Journal of Heterocyclic Chemistry
SP  - 1
EP  - 8
PB  - Science Publishing Group
SN  - 2575-5722
UR  - https://doi.org/10.11648/j.ajhc.20230901.11
AB  - In this study, functionalized magnetic nanoparticles of poly (ionic liquid) 1-allyl-3-methylimidazolium chloride were prepared through free radical copolymerization method and tested as a high efficient adsorbent for the removal of anionic dyes in water samples. The physical and chemical structure of prepared magnetic nanoparticles (MNPs) were investigated using Fourier transform infrared spectroscopy (FT-IR), X-ray powder diffraction (XRD), transmission electron microscopy (TEM) and scanning electron microscopy (SEM). Next, synthesized magnetic nanoparticles were used in magnetic solid phase extraction (MSPE) method to extract three anionic dyes (Alizarin Red S, Congo Red and Methyl Orange) in water samples. Also, the effect of several parameters such as pH, temperature, contact time and amount of adsorbent was investigated and the optimum values were determined. In addition, the adsorbent has a high ability to remove anionic dyes from water samples containing different dyes. Limit of detection (LOD), limit of quantitation (LOQ), and correlation coefficient were determined for methyl orange, Congo red and alizarin red S dyes under optimum conditions. The synthesized magnetic nanoparticles can be collected by an external magnetic field and regenerated with an alkaline solution (NaOH) and reused. The obtained results showed that the MNPs@PIL method was very efficient and successful in removing dye pollutants in water samples.
VL  - 9
IS  - 1
ER  -

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Author Information

Mahboobeh Falahati

Department of Chemistry, Imam Khomeini International University (IKIU), Qazvin, Iran
Majid Soleimani

Department of Chemistry, Imam Khomeini International University (IKIU), Qazvin, Iran
Fateme Aflatouni

Department of Chemistry, Imam Khomeini International University (IKIU), Qazvin, Iran

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APA Style

Mahboobeh Falahati, Majid Soleimani, Fateme Aflatouni. (2023). Separation and Preconcentration of Anionic Dyes Using Magnetic Nanoparticles with Modify Polymer Ionic Liquid. American Journal of Heterocyclic Chemistry, 9(1), 1-8. https://doi.org/10.11648/j.ajhc.20230901.11

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ACS Style

Mahboobeh Falahati; Majid Soleimani; Fateme Aflatouni. Separation and Preconcentration of Anionic Dyes Using Magnetic Nanoparticles with Modify Polymer Ionic Liquid. Am. J. Heterocycl. Chem. 2023, 9(1), 1-8. doi: 10.11648/j.ajhc.20230901.11

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AMA Style

Mahboobeh Falahati, Majid Soleimani, Fateme Aflatouni. Separation and Preconcentration of Anionic Dyes Using Magnetic Nanoparticles with Modify Polymer Ionic Liquid. Am J Heterocycl Chem. 2023;9(1):1-8. doi: 10.11648/j.ajhc.20230901.11

Copy | Download

@article{10.11648/j.ajhc.20230901.11,
  author = {Mahboobeh Falahati and Majid Soleimani and Fateme Aflatouni},
  title = {Separation and Preconcentration of Anionic Dyes Using Magnetic Nanoparticles with Modify Polymer Ionic Liquid},
  journal = {American Journal of Heterocyclic Chemistry},
  volume = {9},
  number = {1},
  pages = {1-8},
  doi = {10.11648/j.ajhc.20230901.11},
  url = {https://doi.org/10.11648/j.ajhc.20230901.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajhc.20230901.11},
  abstract = {In this study, functionalized magnetic nanoparticles of poly (ionic liquid) 1-allyl-3-methylimidazolium chloride were prepared through free radical copolymerization method and tested as a high efficient adsorbent for the removal of anionic dyes in water samples. The physical and chemical structure of prepared magnetic nanoparticles (MNPs) were investigated using Fourier transform infrared spectroscopy (FT-IR), X-ray powder diffraction (XRD), transmission electron microscopy (TEM) and scanning electron microscopy (SEM). Next, synthesized magnetic nanoparticles were used in magnetic solid phase extraction (MSPE) method to extract three anionic dyes (Alizarin Red S, Congo Red and Methyl Orange) in water samples. Also, the effect of several parameters such as pH, temperature, contact time and amount of adsorbent was investigated and the optimum values were determined. In addition, the adsorbent has a high ability to remove anionic dyes from water samples containing different dyes. Limit of detection (LOD), limit of quantitation (LOQ), and correlation coefficient were determined for methyl orange, Congo red and alizarin red S dyes under optimum conditions. The synthesized magnetic nanoparticles can be collected by an external magnetic field and regenerated with an alkaline solution (NaOH) and reused. The obtained results showed that the MNPs@PIL method was very efficient and successful in removing dye pollutants in water samples.},
 year = {2023}
}

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TY  - JOUR
T1  - Separation and Preconcentration of Anionic Dyes Using Magnetic Nanoparticles with Modify Polymer Ionic Liquid
AU  - Mahboobeh Falahati
AU  - Majid Soleimani
AU  - Fateme Aflatouni
Y1  - 2023/04/20
PY  - 2023
N1  - https://doi.org/10.11648/j.ajhc.20230901.11
DO  - 10.11648/j.ajhc.20230901.11
T2  - American Journal of Heterocyclic Chemistry
JF  - American Journal of Heterocyclic Chemistry
JO  - American Journal of Heterocyclic Chemistry
SP  - 1
EP  - 8
PB  - Science Publishing Group
SN  - 2575-5722
UR  - https://doi.org/10.11648/j.ajhc.20230901.11
AB  - In this study, functionalized magnetic nanoparticles of poly (ionic liquid) 1-allyl-3-methylimidazolium chloride were prepared through free radical copolymerization method and tested as a high efficient adsorbent for the removal of anionic dyes in water samples. The physical and chemical structure of prepared magnetic nanoparticles (MNPs) were investigated using Fourier transform infrared spectroscopy (FT-IR), X-ray powder diffraction (XRD), transmission electron microscopy (TEM) and scanning electron microscopy (SEM). Next, synthesized magnetic nanoparticles were used in magnetic solid phase extraction (MSPE) method to extract three anionic dyes (Alizarin Red S, Congo Red and Methyl Orange) in water samples. Also, the effect of several parameters such as pH, temperature, contact time and amount of adsorbent was investigated and the optimum values were determined. In addition, the adsorbent has a high ability to remove anionic dyes from water samples containing different dyes. Limit of detection (LOD), limit of quantitation (LOQ), and correlation coefficient were determined for methyl orange, Congo red and alizarin red S dyes under optimum conditions. The synthesized magnetic nanoparticles can be collected by an external magnetic field and regenerated with an alkaline solution (NaOH) and reused. The obtained results showed that the MNPs@PIL method was very efficient and successful in removing dye pollutants in water samples.
VL  - 9
IS  - 1
ER  -

Copy | Download