Effect of Henna Leaves on the Corrosion Inhibition of Tin in Acidic and Alkaline Media

Muhammad Bashir Ibrahim; Zakariyau Sulaiman; Bishir Usman; Muhammad Adamu Ibrahim

doi:doi:10.11648/j.wjac.20190404.11

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Effect of Henna Leaves on the Corrosion Inhibition of Tin in Acidic and Alkaline Media

Muhammad Bashir Ibrahim, Zakariyau Sulaiman, Bishir Usman, Muhammad Adamu Ibrahim

Published in World Journal of Applied Chemistry (Volume 4, Issue 4)

Received: 27 August 2019 Accepted: 19 September 2019 Published: 9 October 2019

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Abstract

The corrosion inhibition behaviour of Henna leaves on Tin in 1.0 M HCl and 1.0 M NaOH was investigated using weight loss technique at temperatures ranges, 25-50°C. The maximum inhibition efficiency was found to be 95.45 at optimum inhibitor concentration. The presence of the compound adsorbed on the tin coupons was verified by spectroscopic measurements of the surface before and after corrosion tests. The leaves extract of Lawsonia inermis was found to be more effective in alkaline solution. It also confirmed that the inhibition efficiency decreased with increased in temperature but increased with increasing inhibitor concentrations. The Activation energy, Gibbs free energy were found to be 28.131, 29.589 kJmol^-1; -3.280, -3.245 kJmol^-1 in acidic and alkaline media respectively. The adsorption was found to obey Freundlich isotherm with linear coefficient (R²) and equilibrium parameter K_ads to be 0.972, 0.957; 0.06, 0.05 for both systems in acidic and alkaline media respectively. Physical adsorption mechanism is proposed from the trend of ∆G_ads. The negative values of ∆G_ads shows the spontaneity of the inhibition process. The increase in the activation energy of the inhibition processes with values of 80kJ/mol support the mechanism of physical adsorption process. Lawsonia inermis leaves extract has proved to be more excellent inhibitor for tin in NaOH alkaline.

Published in	World Journal of Applied Chemistry (Volume 4, Issue 4)
DOI	10.11648/j.wjac.20190404.11
Page(s)	45-51
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2019. Published by Science Publishing Group

Keywords

Corrosion, Henna, Tin, Acidic, Alkaline Solution

References

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[8]	Rajendran. S, Agasta. M., Devi. B. R, Devi. S. B, Rajam. k. and JEYASUNDARI (2009). Corrosion Inhibition by an Aqueous Extract of Henna Leaves (LawsoniaInermis L). Scientific paper UDC: 620.1934, Vol 20: pp 77-83.
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[14]	James A. O. and Akaranta O., (2009). The Inhibition of Corrosion of Zinc in 2.0 M Hydrochloric acid Solution with Acetone Extract of red Onion Skin. African Journal of Pure and Applied Chemistry, Vol 3 (11): pp 212.
[15]	Nwabanne, J. T. and Okafor, V. N., (2011). Inhibition of the Corrosion of Mild Steel in Acidic Medium by Vernonia Amygdalina: Adsorption and thermodynamics Study. Journal of Emerging Trends in Engineering and Applied Sciences, Vol 2 (4): pp 619-625.
[16]	Ituen, E. B., Udo, U. E., Odozi, N. W. and Dan, E. U. (2013). Adsorption and Kinetic/Thermodynamic Characterization of Aluminium Corrosion Inhibition in Sulphuric Acid by Extract of Astoniaboonei. IOSR Journal of Applied Chemistry, Vol 3: pp 52-59.
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APA Style

Muhammad Bashir Ibrahim, Zakariyau Sulaiman, Bishir Usman, Muhammad Adamu Ibrahim. (2019). Effect of Henna Leaves on the Corrosion Inhibition of Tin in Acidic and Alkaline Media. World Journal of Applied Chemistry, 4(4), 45-51. https://doi.org/10.11648/j.wjac.20190404.11

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ACS Style

Muhammad Bashir Ibrahim; Zakariyau Sulaiman; Bishir Usman; Muhammad Adamu Ibrahim. Effect of Henna Leaves on the Corrosion Inhibition of Tin in Acidic and Alkaline Media. World J. Appl. Chem. 2019, 4(4), 45-51. doi: 10.11648/j.wjac.20190404.11

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AMA Style

Muhammad Bashir Ibrahim, Zakariyau Sulaiman, Bishir Usman, Muhammad Adamu Ibrahim. Effect of Henna Leaves on the Corrosion Inhibition of Tin in Acidic and Alkaline Media. World J Appl Chem. 2019;4(4):45-51. doi: 10.11648/j.wjac.20190404.11

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@article{10.11648/j.wjac.20190404.11,
  author = {Muhammad Bashir Ibrahim and Zakariyau Sulaiman and Bishir Usman and Muhammad Adamu Ibrahim},
  title = {Effect of Henna Leaves on the Corrosion Inhibition of Tin in Acidic and Alkaline Media},
  journal = {World Journal of Applied Chemistry},
  volume = {4},
  number = {4},
  pages = {45-51},
  doi = {10.11648/j.wjac.20190404.11},
  url = {https://doi.org/10.11648/j.wjac.20190404.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.wjac.20190404.11},
  abstract = {The corrosion inhibition behaviour of Henna leaves on Tin in 1.0 M HCl and 1.0 M NaOH was investigated using weight loss technique at temperatures ranges, 25-50°C. The maximum inhibition efficiency was found to be 95.45 at optimum inhibitor concentration. The presence of the compound adsorbed on the tin coupons was verified by spectroscopic measurements of the surface before and after corrosion tests. The leaves extract of Lawsonia inermis was found to be more effective in alkaline solution. It also confirmed that the inhibition efficiency decreased with increased in temperature but increased with increasing inhibitor concentrations. The Activation energy, Gibbs free energy were found to be 28.131, 29.589 kJmol-1; -3.280, -3.245 kJmol-1 in acidic and alkaline media respectively. The adsorption was found to obey Freundlich isotherm with linear coefficient (R2) and equilibrium parameter Kads to be 0.972, 0.957; 0.06, 0.05 for both systems in acidic and alkaline media respectively. Physical adsorption mechanism is proposed from the trend of ∆Gads. The negative values of ∆Gads shows the spontaneity of the inhibition process. The increase in the activation energy of the inhibition processes with values of 80kJ/mol support the mechanism of physical adsorption process. Lawsonia inermis leaves extract has proved to be more excellent inhibitor for tin in NaOH alkaline.},
 year = {2019}
}

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TY - JOUR
T1 - Effect of Henna Leaves on the Corrosion Inhibition of Tin in Acidic and Alkaline Media
AU - Muhammad Bashir Ibrahim
AU - Zakariyau Sulaiman
AU - Bishir Usman
AU - Muhammad Adamu Ibrahim
Y1 - 2019/10/09
PY - 2019
N1 - https://doi.org/10.11648/j.wjac.20190404.11
DO - 10.11648/j.wjac.20190404.11
T2 - World Journal of Applied Chemistry
JF - World Journal of Applied Chemistry
JO - World Journal of Applied Chemistry
SP - 45
EP - 51
PB - Science Publishing Group
SN - 2637-5982
UR - https://doi.org/10.11648/j.wjac.20190404.11
AB - The corrosion inhibition behaviour of Henna leaves on Tin in 1.0 M HCl and 1.0 M NaOH was investigated using weight loss technique at temperatures ranges, 25-50°C. The maximum inhibition efficiency was found to be 95.45 at optimum inhibitor concentration. The presence of the compound adsorbed on the tin coupons was verified by spectroscopic measurements of the surface before and after corrosion tests. The leaves extract of Lawsonia inermis was found to be more effective in alkaline solution. It also confirmed that the inhibition efficiency decreased with increased in temperature but increased with increasing inhibitor concentrations. The Activation energy, Gibbs free energy were found to be 28.131, 29.589 kJmol-1; -3.280, -3.245 kJmol-1 in acidic and alkaline media respectively. The adsorption was found to obey Freundlich isotherm with linear coefficient (R2) and equilibrium parameter Kads to be 0.972, 0.957; 0.06, 0.05 for both systems in acidic and alkaline media respectively. Physical adsorption mechanism is proposed from the trend of ∆Gads. The negative values of ∆Gads shows the spontaneity of the inhibition process. The increase in the activation energy of the inhibition processes with values of 80kJ/mol support the mechanism of physical adsorption process. Lawsonia inermis leaves extract has proved to be more excellent inhibitor for tin in NaOH alkaline.
VL - 4
IS - 4
ER -

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Author Information

Muhammad Bashir Ibrahim

Department of Pure and Industrial Chemistry, Bayero University, Kano, Nigeria
Zakariyau Sulaiman

Department of Pure and Industrial Chemistry, Bayero University, Kano, Nigeria
Bishir Usman

Department of Pure and Industrial Chemistry, Bayero University, Kano, Nigeria
Muhammad Adamu Ibrahim

Department of Pure and Industrial Chemistry, Bayero University, Kano, Nigeria

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APA Style

Muhammad Bashir Ibrahim, Zakariyau Sulaiman, Bishir Usman, Muhammad Adamu Ibrahim. (2019). Effect of Henna Leaves on the Corrosion Inhibition of Tin in Acidic and Alkaline Media. World Journal of Applied Chemistry, 4(4), 45-51. https://doi.org/10.11648/j.wjac.20190404.11

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ACS Style

Muhammad Bashir Ibrahim; Zakariyau Sulaiman; Bishir Usman; Muhammad Adamu Ibrahim. Effect of Henna Leaves on the Corrosion Inhibition of Tin in Acidic and Alkaline Media. World J. Appl. Chem. 2019, 4(4), 45-51. doi: 10.11648/j.wjac.20190404.11

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AMA Style

Muhammad Bashir Ibrahim, Zakariyau Sulaiman, Bishir Usman, Muhammad Adamu Ibrahim. Effect of Henna Leaves on the Corrosion Inhibition of Tin in Acidic and Alkaline Media. World J Appl Chem. 2019;4(4):45-51. doi: 10.11648/j.wjac.20190404.11

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@article{10.11648/j.wjac.20190404.11,
  author = {Muhammad Bashir Ibrahim and Zakariyau Sulaiman and Bishir Usman and Muhammad Adamu Ibrahim},
  title = {Effect of Henna Leaves on the Corrosion Inhibition of Tin in Acidic and Alkaline Media},
  journal = {World Journal of Applied Chemistry},
  volume = {4},
  number = {4},
  pages = {45-51},
  doi = {10.11648/j.wjac.20190404.11},
  url = {https://doi.org/10.11648/j.wjac.20190404.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.wjac.20190404.11},
  abstract = {The corrosion inhibition behaviour of Henna leaves on Tin in 1.0 M HCl and 1.0 M NaOH was investigated using weight loss technique at temperatures ranges, 25-50°C. The maximum inhibition efficiency was found to be 95.45 at optimum inhibitor concentration. The presence of the compound adsorbed on the tin coupons was verified by spectroscopic measurements of the surface before and after corrosion tests. The leaves extract of Lawsonia inermis was found to be more effective in alkaline solution. It also confirmed that the inhibition efficiency decreased with increased in temperature but increased with increasing inhibitor concentrations. The Activation energy, Gibbs free energy were found to be 28.131, 29.589 kJmol-1; -3.280, -3.245 kJmol-1 in acidic and alkaline media respectively. The adsorption was found to obey Freundlich isotherm with linear coefficient (R2) and equilibrium parameter Kads to be 0.972, 0.957; 0.06, 0.05 for both systems in acidic and alkaline media respectively. Physical adsorption mechanism is proposed from the trend of ∆Gads. The negative values of ∆Gads shows the spontaneity of the inhibition process. The increase in the activation energy of the inhibition processes with values of 80kJ/mol support the mechanism of physical adsorption process. Lawsonia inermis leaves extract has proved to be more excellent inhibitor for tin in NaOH alkaline.},
 year = {2019}
}

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