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Synthesis and Structural Elucidation of Ni(II), Cu(II), Zn(II) and Cd(II) Metal Complexes of Oxazoline Based Ligands

Received: 11 January 2015     Accepted: 21 January 2015     Published: 16 February 2015
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Abstract

Synthesis of 2-(2'-hydroxyphenyl)-2-oxazoline(2-Phox) and 2-(4-hydroxyphenyl)-2-oxazoline(4-Phox) and their complexes with Ni(II), Cu(II), Zn(II) and Cd(II) have been done. They have been characterized by elemental analysis, magnetic susceptibility, NMR (HH-COSY, HSQC, HMBC), UV-vis, IR spectroscopy and conductance measurement. The complexes were formed in 1:2 (M:L) ratio. Their molar conductance of one millimolar solution measured in DMF indicated them to be non electrolyte. On the basis of these studies a tetrahedral geometry has been assigned for all the complexes.

Published in American Journal of Applied Chemistry (Volume 3, Issue 2)
DOI 10.11648/j.ajac.20150302.12
Page(s) 40-47
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2015. Published by Science Publishing Group

Keywords

Oxazoline, Metal Complexes, Spectroscopy

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    Bitew Kassaw Dessie, Muluye Melak Zenebe, Atnafu Guadie Assefa. (2015). Synthesis and Structural Elucidation of Ni(II), Cu(II), Zn(II) and Cd(II) Metal Complexes of Oxazoline Based Ligands. American Journal of Applied Chemistry, 3(2), 40-47. https://doi.org/10.11648/j.ajac.20150302.12

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    ACS Style

    Bitew Kassaw Dessie; Muluye Melak Zenebe; Atnafu Guadie Assefa. Synthesis and Structural Elucidation of Ni(II), Cu(II), Zn(II) and Cd(II) Metal Complexes of Oxazoline Based Ligands. Am. J. Appl. Chem. 2015, 3(2), 40-47. doi: 10.11648/j.ajac.20150302.12

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    AMA Style

    Bitew Kassaw Dessie, Muluye Melak Zenebe, Atnafu Guadie Assefa. Synthesis and Structural Elucidation of Ni(II), Cu(II), Zn(II) and Cd(II) Metal Complexes of Oxazoline Based Ligands. Am J Appl Chem. 2015;3(2):40-47. doi: 10.11648/j.ajac.20150302.12

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  • @article{10.11648/j.ajac.20150302.12,
      author = {Bitew Kassaw Dessie and Muluye Melak Zenebe and Atnafu Guadie Assefa},
      title = {Synthesis and Structural Elucidation of Ni(II), Cu(II), Zn(II) and Cd(II) Metal Complexes of Oxazoline Based Ligands},
      journal = {American Journal of Applied Chemistry},
      volume = {3},
      number = {2},
      pages = {40-47},
      doi = {10.11648/j.ajac.20150302.12},
      url = {https://doi.org/10.11648/j.ajac.20150302.12},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20150302.12},
      abstract = {Synthesis of 2-(2'-hydroxyphenyl)-2-oxazoline(2-Phox) and 2-(4-hydroxyphenyl)-2-oxazoline(4-Phox) and their complexes with Ni(II), Cu(II), Zn(II) and Cd(II) have been done. They have been characterized by elemental analysis, magnetic susceptibility, NMR (HH-COSY, HSQC, HMBC), UV-vis, IR spectroscopy and conductance measurement. The complexes were formed in 1:2 (M:L) ratio. Their molar conductance of one millimolar solution measured in DMF indicated them to be non electrolyte. On the basis of these studies a tetrahedral geometry has been assigned for all the complexes.},
     year = {2015}
    }
    

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  • TY  - JOUR
    T1  - Synthesis and Structural Elucidation of Ni(II), Cu(II), Zn(II) and Cd(II) Metal Complexes of Oxazoline Based Ligands
    AU  - Bitew Kassaw Dessie
    AU  - Muluye Melak Zenebe
    AU  - Atnafu Guadie Assefa
    Y1  - 2015/02/16
    PY  - 2015
    N1  - https://doi.org/10.11648/j.ajac.20150302.12
    DO  - 10.11648/j.ajac.20150302.12
    T2  - American Journal of Applied Chemistry
    JF  - American Journal of Applied Chemistry
    JO  - American Journal of Applied Chemistry
    SP  - 40
    EP  - 47
    PB  - Science Publishing Group
    SN  - 2330-8745
    UR  - https://doi.org/10.11648/j.ajac.20150302.12
    AB  - Synthesis of 2-(2'-hydroxyphenyl)-2-oxazoline(2-Phox) and 2-(4-hydroxyphenyl)-2-oxazoline(4-Phox) and their complexes with Ni(II), Cu(II), Zn(II) and Cd(II) have been done. They have been characterized by elemental analysis, magnetic susceptibility, NMR (HH-COSY, HSQC, HMBC), UV-vis, IR spectroscopy and conductance measurement. The complexes were formed in 1:2 (M:L) ratio. Their molar conductance of one millimolar solution measured in DMF indicated them to be non electrolyte. On the basis of these studies a tetrahedral geometry has been assigned for all the complexes.
    VL  - 3
    IS  - 2
    ER  - 

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Author Information
  • University of Gondar, Department of Chemistry, Gondar, Ethiopia

  • University of Gondar, Department of Chemistry, Gondar, Ethiopia

  • University of Gondar, Department of Chemistry, Gondar, Ethiopia

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