Synthesis and Structural Elucidation of Ni(II), Cu(II), Zn(II) and Cd(II) Metal Complexes of Oxazoline Based Ligands

Bitew Kassaw Dessie; Muluye Melak Zenebe; Atnafu Guadie Assefa

doi:doi:10.11648/j.ajac.20150302.12

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Synthesis and Structural Elucidation of Ni(II), Cu(II), Zn(II) and Cd(II) Metal Complexes of Oxazoline Based Ligands

Bitew Kassaw Dessie, Muluye Melak Zenebe, Atnafu Guadie Assefa

Published in American Journal of Applied Chemistry (Volume 3, Issue 2)

Received: 11 January 2015 Accepted: 21 January 2015 Published: 16 February 2015

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Abstract

Synthesis of 2-(2'-hydroxyphenyl)-2-oxazoline(2-Phox) and 2-(4-hydroxyphenyl)-2-oxazoline(4-Phox) and their complexes with Ni(II), Cu(II), Zn(II) and Cd(II) have been done. They have been characterized by elemental analysis, magnetic susceptibility, NMR (HH-COSY, HSQC, HMBC), UV-vis, IR spectroscopy and conductance measurement. The complexes were formed in 1:2 (M:L) ratio. Their molar conductance of one millimolar solution measured in DMF indicated them to be non electrolyte. On the basis of these studies a tetrahedral geometry has been assigned for all the complexes.

Published in	American Journal of Applied Chemistry (Volume 3, Issue 2)
DOI	10.11648/j.ajac.20150302.12
Page(s)	40-47
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2015. Published by Science Publishing Group

Keywords

Oxazoline, Metal Complexes, Spectroscopy

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Bitew Kassaw Dessie, Muluye Melak Zenebe, Atnafu Guadie Assefa. (2015). Synthesis and Structural Elucidation of Ni(II), Cu(II), Zn(II) and Cd(II) Metal Complexes of Oxazoline Based Ligands. American Journal of Applied Chemistry, 3(2), 40-47. https://doi.org/10.11648/j.ajac.20150302.12

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ACS Style

Bitew Kassaw Dessie; Muluye Melak Zenebe; Atnafu Guadie Assefa. Synthesis and Structural Elucidation of Ni(II), Cu(II), Zn(II) and Cd(II) Metal Complexes of Oxazoline Based Ligands. Am. J. Appl. Chem. 2015, 3(2), 40-47. doi: 10.11648/j.ajac.20150302.12

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AMA Style

Bitew Kassaw Dessie, Muluye Melak Zenebe, Atnafu Guadie Assefa. Synthesis and Structural Elucidation of Ni(II), Cu(II), Zn(II) and Cd(II) Metal Complexes of Oxazoline Based Ligands. Am J Appl Chem. 2015;3(2):40-47. doi: 10.11648/j.ajac.20150302.12

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@article{10.11648/j.ajac.20150302.12,
  author = {Bitew Kassaw Dessie and Muluye Melak Zenebe and Atnafu Guadie Assefa},
  title = {Synthesis and Structural Elucidation of Ni(II), Cu(II), Zn(II) and Cd(II) Metal Complexes of Oxazoline Based Ligands},
  journal = {American Journal of Applied Chemistry},
  volume = {3},
  number = {2},
  pages = {40-47},
  doi = {10.11648/j.ajac.20150302.12},
  url = {https://doi.org/10.11648/j.ajac.20150302.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20150302.12},
  abstract = {Synthesis of 2-(2'-hydroxyphenyl)-2-oxazoline(2-Phox) and 2-(4-hydroxyphenyl)-2-oxazoline(4-Phox) and their complexes with Ni(II), Cu(II), Zn(II) and Cd(II) have been done. They have been characterized by elemental analysis, magnetic susceptibility, NMR (HH-COSY, HSQC, HMBC), UV-vis, IR spectroscopy and conductance measurement. The complexes were formed in 1:2 (M:L) ratio. Their molar conductance of one millimolar solution measured in DMF indicated them to be non electrolyte. On the basis of these studies a tetrahedral geometry has been assigned for all the complexes.},
 year = {2015}
}

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TY  - JOUR
T1  - Synthesis and Structural Elucidation of Ni(II), Cu(II), Zn(II) and Cd(II) Metal Complexes of Oxazoline Based Ligands
AU  - Bitew Kassaw Dessie
AU  - Muluye Melak Zenebe
AU  - Atnafu Guadie Assefa
Y1  - 2015/02/16
PY  - 2015
N1  - https://doi.org/10.11648/j.ajac.20150302.12
DO  - 10.11648/j.ajac.20150302.12
T2  - American Journal of Applied Chemistry
JF  - American Journal of Applied Chemistry
JO  - American Journal of Applied Chemistry
SP  - 40
EP  - 47
PB  - Science Publishing Group
SN  - 2330-8745
UR  - https://doi.org/10.11648/j.ajac.20150302.12
AB  - Synthesis of 2-(2'-hydroxyphenyl)-2-oxazoline(2-Phox) and 2-(4-hydroxyphenyl)-2-oxazoline(4-Phox) and their complexes with Ni(II), Cu(II), Zn(II) and Cd(II) have been done. They have been characterized by elemental analysis, magnetic susceptibility, NMR (HH-COSY, HSQC, HMBC), UV-vis, IR spectroscopy and conductance measurement. The complexes were formed in 1:2 (M:L) ratio. Their molar conductance of one millimolar solution measured in DMF indicated them to be non electrolyte. On the basis of these studies a tetrahedral geometry has been assigned for all the complexes.
VL  - 3
IS  - 2
ER  -

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Author Information

Bitew Kassaw Dessie

University of Gondar, Department of Chemistry, Gondar, Ethiopia
Muluye Melak Zenebe

University of Gondar, Department of Chemistry, Gondar, Ethiopia
Atnafu Guadie Assefa

University of Gondar, Department of Chemistry, Gondar, Ethiopia

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APA Style

Bitew Kassaw Dessie, Muluye Melak Zenebe, Atnafu Guadie Assefa. (2015). Synthesis and Structural Elucidation of Ni(II), Cu(II), Zn(II) and Cd(II) Metal Complexes of Oxazoline Based Ligands. American Journal of Applied Chemistry, 3(2), 40-47. https://doi.org/10.11648/j.ajac.20150302.12

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ACS Style

Bitew Kassaw Dessie; Muluye Melak Zenebe; Atnafu Guadie Assefa. Synthesis and Structural Elucidation of Ni(II), Cu(II), Zn(II) and Cd(II) Metal Complexes of Oxazoline Based Ligands. Am. J. Appl. Chem. 2015, 3(2), 40-47. doi: 10.11648/j.ajac.20150302.12

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AMA Style

Bitew Kassaw Dessie, Muluye Melak Zenebe, Atnafu Guadie Assefa. Synthesis and Structural Elucidation of Ni(II), Cu(II), Zn(II) and Cd(II) Metal Complexes of Oxazoline Based Ligands. Am J Appl Chem. 2015;3(2):40-47. doi: 10.11648/j.ajac.20150302.12

Copy | Download

@article{10.11648/j.ajac.20150302.12,
  author = {Bitew Kassaw Dessie and Muluye Melak Zenebe and Atnafu Guadie Assefa},
  title = {Synthesis and Structural Elucidation of Ni(II), Cu(II), Zn(II) and Cd(II) Metal Complexes of Oxazoline Based Ligands},
  journal = {American Journal of Applied Chemistry},
  volume = {3},
  number = {2},
  pages = {40-47},
  doi = {10.11648/j.ajac.20150302.12},
  url = {https://doi.org/10.11648/j.ajac.20150302.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20150302.12},
  abstract = {Synthesis of 2-(2'-hydroxyphenyl)-2-oxazoline(2-Phox) and 2-(4-hydroxyphenyl)-2-oxazoline(4-Phox) and their complexes with Ni(II), Cu(II), Zn(II) and Cd(II) have been done. They have been characterized by elemental analysis, magnetic susceptibility, NMR (HH-COSY, HSQC, HMBC), UV-vis, IR spectroscopy and conductance measurement. The complexes were formed in 1:2 (M:L) ratio. Their molar conductance of one millimolar solution measured in DMF indicated them to be non electrolyte. On the basis of these studies a tetrahedral geometry has been assigned for all the complexes.},
 year = {2015}
}

Copy | Download

TY  - JOUR
T1  - Synthesis and Structural Elucidation of Ni(II), Cu(II), Zn(II) and Cd(II) Metal Complexes of Oxazoline Based Ligands
AU  - Bitew Kassaw Dessie
AU  - Muluye Melak Zenebe
AU  - Atnafu Guadie Assefa
Y1  - 2015/02/16
PY  - 2015
N1  - https://doi.org/10.11648/j.ajac.20150302.12
DO  - 10.11648/j.ajac.20150302.12
T2  - American Journal of Applied Chemistry
JF  - American Journal of Applied Chemistry
JO  - American Journal of Applied Chemistry
SP  - 40
EP  - 47
PB  - Science Publishing Group
SN  - 2330-8745
UR  - https://doi.org/10.11648/j.ajac.20150302.12
AB  - Synthesis of 2-(2'-hydroxyphenyl)-2-oxazoline(2-Phox) and 2-(4-hydroxyphenyl)-2-oxazoline(4-Phox) and their complexes with Ni(II), Cu(II), Zn(II) and Cd(II) have been done. They have been characterized by elemental analysis, magnetic susceptibility, NMR (HH-COSY, HSQC, HMBC), UV-vis, IR spectroscopy and conductance measurement. The complexes were formed in 1:2 (M:L) ratio. Their molar conductance of one millimolar solution measured in DMF indicated them to be non electrolyte. On the basis of these studies a tetrahedral geometry has been assigned for all the complexes.
VL  - 3
IS  - 2
ER  -

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