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Constructing of Highly Ordered 3D Network of Carbon Nanotube inside Polymer Matrix and the Improvements in Properties of the Composites

Received: 21 January 2019     Accepted: 28 February 2019     Published: 21 March 2019
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Abstract

In the past few decades, carbon nanotube-filled polymer composites have attracted the attention of many researchers with their excellent performance. However, the currently known methods of preparing composite materials do not maximize the performance of the carbon nanotubes themselves. In this work, by using our proposed “particle-constructing” method, multi-wall carbon nanotubes (MWCNTs) connected with each other to form highly ordered 3D network structure in polystyrene (PS) matrix. The strategy contains two steps as follows. First, MWCNTs-coated PS composite particles were prepared by the thermodynamic driving heterocoargulation method, without any requirement to surface modification or surface treatment whether for the MWCNTs or the PS microspheres. Then, the resultant MWCNTs-coated PS composite particles are used as building blocks to fabricate the highly ordered 3D MWCNT-based PS composite materials by a general compression mould at room temperature and a subsequent heat treatment at an appropriate temperature. We discuss in detail the effects of PS particle size, oxidation of MWCNTs and their length on the electrical conductivity of materials. The fabricated MWCNT-based PS composite materials exhibited excellent properties such as a much higher electrical and mechanical properties. Moreover, the method and process are pretty simple, convenient and environment-friendly for obtaining the unique composite structure and excellent properties.

Published in American Journal of Polymer Science and Technology (Volume 5, Issue 1)
DOI 10.11648/j.ajpst.20190501.12
Page(s) 9-15
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2019. Published by Science Publishing Group

Keywords

Carbon Nanotube, Conductive Material, Polymer Nanocomposites, 3D Network Structure

References
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Cite This Article
  • APA Style

    Liang Yang, Yan Zheng, Min Hou, Wanyi Chen, Zhaoqun Wang. (2019). Constructing of Highly Ordered 3D Network of Carbon Nanotube inside Polymer Matrix and the Improvements in Properties of the Composites. American Journal of Polymer Science and Technology, 5(1), 9-15. https://doi.org/10.11648/j.ajpst.20190501.12

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    ACS Style

    Liang Yang; Yan Zheng; Min Hou; Wanyi Chen; Zhaoqun Wang. Constructing of Highly Ordered 3D Network of Carbon Nanotube inside Polymer Matrix and the Improvements in Properties of the Composites. Am. J. Polym. Sci. Technol. 2019, 5(1), 9-15. doi: 10.11648/j.ajpst.20190501.12

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    AMA Style

    Liang Yang, Yan Zheng, Min Hou, Wanyi Chen, Zhaoqun Wang. Constructing of Highly Ordered 3D Network of Carbon Nanotube inside Polymer Matrix and the Improvements in Properties of the Composites. Am J Polym Sci Technol. 2019;5(1):9-15. doi: 10.11648/j.ajpst.20190501.12

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  • @article{10.11648/j.ajpst.20190501.12,
      author = {Liang Yang and Yan Zheng and Min Hou and Wanyi Chen and Zhaoqun Wang},
      title = {Constructing of Highly Ordered 3D Network of Carbon Nanotube inside Polymer Matrix and the Improvements in Properties of the Composites},
      journal = {American Journal of Polymer Science and Technology},
      volume = {5},
      number = {1},
      pages = {9-15},
      doi = {10.11648/j.ajpst.20190501.12},
      url = {https://doi.org/10.11648/j.ajpst.20190501.12},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpst.20190501.12},
      abstract = {In the past few decades, carbon nanotube-filled polymer composites have attracted the attention of many researchers with their excellent performance. However, the currently known methods of preparing composite materials do not maximize the performance of the carbon nanotubes themselves. In this work, by using our proposed “particle-constructing” method, multi-wall carbon nanotubes (MWCNTs) connected with each other to form highly ordered 3D network structure in polystyrene (PS) matrix. The strategy contains two steps as follows. First, MWCNTs-coated PS composite particles were prepared by the thermodynamic driving heterocoargulation method, without any requirement to surface modification or surface treatment whether for the MWCNTs or the PS microspheres. Then, the resultant MWCNTs-coated PS composite particles are used as building blocks to fabricate the highly ordered 3D MWCNT-based PS composite materials by a general compression mould at room temperature and a subsequent heat treatment at an appropriate temperature. We discuss in detail the effects of PS particle size, oxidation of MWCNTs and their length on the electrical conductivity of materials. The fabricated MWCNT-based PS composite materials exhibited excellent properties such as a much higher electrical and mechanical properties. Moreover, the method and process are pretty simple, convenient and environment-friendly for obtaining the unique composite structure and excellent properties.},
     year = {2019}
    }
    

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  • TY  - JOUR
    T1  - Constructing of Highly Ordered 3D Network of Carbon Nanotube inside Polymer Matrix and the Improvements in Properties of the Composites
    AU  - Liang Yang
    AU  - Yan Zheng
    AU  - Min Hou
    AU  - Wanyi Chen
    AU  - Zhaoqun Wang
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    PY  - 2019
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    DO  - 10.11648/j.ajpst.20190501.12
    T2  - American Journal of Polymer Science and Technology
    JF  - American Journal of Polymer Science and Technology
    JO  - American Journal of Polymer Science and Technology
    SP  - 9
    EP  - 15
    PB  - Science Publishing Group
    SN  - 2575-5986
    UR  - https://doi.org/10.11648/j.ajpst.20190501.12
    AB  - In the past few decades, carbon nanotube-filled polymer composites have attracted the attention of many researchers with their excellent performance. However, the currently known methods of preparing composite materials do not maximize the performance of the carbon nanotubes themselves. In this work, by using our proposed “particle-constructing” method, multi-wall carbon nanotubes (MWCNTs) connected with each other to form highly ordered 3D network structure in polystyrene (PS) matrix. The strategy contains two steps as follows. First, MWCNTs-coated PS composite particles were prepared by the thermodynamic driving heterocoargulation method, without any requirement to surface modification or surface treatment whether for the MWCNTs or the PS microspheres. Then, the resultant MWCNTs-coated PS composite particles are used as building blocks to fabricate the highly ordered 3D MWCNT-based PS composite materials by a general compression mould at room temperature and a subsequent heat treatment at an appropriate temperature. We discuss in detail the effects of PS particle size, oxidation of MWCNTs and their length on the electrical conductivity of materials. The fabricated MWCNT-based PS composite materials exhibited excellent properties such as a much higher electrical and mechanical properties. Moreover, the method and process are pretty simple, convenient and environment-friendly for obtaining the unique composite structure and excellent properties.
    VL  - 5
    IS  - 1
    ER  - 

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Author Information
  • Department of Polymer Science and Engineering, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, P. R. China

  • Department of Polymer Science and Engineering, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, P. R. China

  • Department of Polymer Science and Engineering, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, P. R. China

  • Department of Polymer Science and Engineering, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, P. R. China

  • Department of Polymer Science and Engineering, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, P. R. China

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