The Removal of Single and Binary Basic Dyes from Synthetic Wastewater Using Bentonite Clay Adsorbent

Olaseni Segun Esan; Akeremale Olaniran Kolawole; Aboluwoye Christopher Olumuyiwa

doi:doi:10.11648/j.ajpst.20190501.13

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The Removal of Single and Binary Basic Dyes from Synthetic Wastewater Using Bentonite Clay Adsorbent

Olaseni Segun Esan, Akeremale Olaniran Kolawole, Aboluwoye Christopher Olumuyiwa

Published in American Journal of Polymer Science and Technology (Volume 5, Issue 1)

Received: 25 September 2018 Accepted: 4 March 2019 Published: 21 March 2019

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Abstract

In order to broaden the application of Bentonite clay, an easily obtainable and bio-available low cost adsorbent, it was employed for the decolourization of synthetic wastewater consisting of single and binary basic dyes (Malachite green and Rhodamine b). The adsorbent was used as obtained without any further modification and also characterized for its specific surface area, point of zero charge and its surface functional groups pre and post dyes sorption was determined using Fourier Transform Infrared Spectroscopy (FTIR). Batch adsorption methods were employed in order to study the effects of pH, Ionic strength and contact time in the single solute system. The parameters of sorption of Rhodamine B (RDB) and Malachite green (MG) were obtained and fitted to three isotherm models; Freundlich, Langmuir and Temkin. The Freundlich plot analysis indicated the process occurred via heterogeneous coverage of adsorbent by both dyes. The kinetics of adsorption data were analyzed using the; pseudo-first order, pseudo-second order, Intraparticle diffusion, film diffusion, and Boyd kinetic models. Over the study of these parameters, the film diffusion mechanism was found to predominate in the sorption process of the dyes. Competitive sorption studies were carried out by using both dyes as either the adsorbate of interest or as the interfering specie. The competitive co-coefficient values obtained from interfering MG in RDB removal were significantly lower than those obtained from interfering RDB in MG removal, indicating that the presence of RDB in the aqua matrix had antagonistic effect on MG adsorption by Bentonite.

Published in	American Journal of Polymer Science and Technology (Volume 5, Issue 1)
DOI	10.11648/j.ajpst.20190501.13
Page(s)	16-28
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2019. Published by Science Publishing Group

Keywords

Freundlich, Langmuir, Temkin, Adsorption, Malachite Green, Bentonite

References

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APA Style

Olaseni Segun Esan, Akeremale Olaniran Kolawole, Aboluwoye Christopher Olumuyiwa. (2019). The Removal of Single and Binary Basic Dyes from Synthetic Wastewater Using Bentonite Clay Adsorbent. American Journal of Polymer Science and Technology, 5(1), 16-28. https://doi.org/10.11648/j.ajpst.20190501.13

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ACS Style

Olaseni Segun Esan; Akeremale Olaniran Kolawole; Aboluwoye Christopher Olumuyiwa. The Removal of Single and Binary Basic Dyes from Synthetic Wastewater Using Bentonite Clay Adsorbent. Am. J. Polym. Sci. Technol. 2019, 5(1), 16-28. doi: 10.11648/j.ajpst.20190501.13

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AMA Style

Olaseni Segun Esan, Akeremale Olaniran Kolawole, Aboluwoye Christopher Olumuyiwa. The Removal of Single and Binary Basic Dyes from Synthetic Wastewater Using Bentonite Clay Adsorbent. Am J Polym Sci Technol. 2019;5(1):16-28. doi: 10.11648/j.ajpst.20190501.13

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@article{10.11648/j.ajpst.20190501.13,
  author = {Olaseni Segun Esan and Akeremale Olaniran Kolawole and Aboluwoye Christopher Olumuyiwa},
  title = {The Removal of Single and Binary Basic Dyes from Synthetic Wastewater Using Bentonite Clay Adsorbent},
  journal = {American Journal of Polymer Science and Technology},
  volume = {5},
  number = {1},
  pages = {16-28},
  doi = {10.11648/j.ajpst.20190501.13},
  url = {https://doi.org/10.11648/j.ajpst.20190501.13},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpst.20190501.13},
  abstract = {In order to broaden the application of Bentonite clay, an easily obtainable and bio-available low cost adsorbent, it was employed for the decolourization of synthetic wastewater consisting of single and binary basic dyes (Malachite green and Rhodamine b). The adsorbent was used as obtained without any further modification and also characterized for its specific surface area, point of zero charge and its surface functional groups pre and post dyes sorption was determined using Fourier Transform Infrared Spectroscopy (FTIR). Batch adsorption methods were employed in order to study the effects of pH, Ionic strength and contact time in the single solute system. The parameters of sorption of Rhodamine B (RDB) and Malachite green (MG) were obtained and fitted to three isotherm models; Freundlich, Langmuir and Temkin. The Freundlich plot analysis indicated the process occurred via heterogeneous coverage of adsorbent by both dyes. The kinetics of adsorption data were analyzed using the; pseudo-first order, pseudo-second order, Intraparticle diffusion, film diffusion, and Boyd kinetic models. Over the study of these parameters, the film diffusion mechanism was found to predominate in the sorption process of the dyes. Competitive sorption studies were carried out by using both dyes as either the adsorbate of interest or as the interfering specie. The competitive co-coefficient values obtained from interfering MG in RDB removal were significantly lower than those obtained from interfering RDB in MG removal, indicating that the presence of RDB in the aqua matrix had antagonistic effect on MG adsorption by Bentonite.},
 year = {2019}
}

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TY  - JOUR
T1  - The Removal of Single and Binary Basic Dyes from Synthetic Wastewater Using Bentonite Clay Adsorbent
AU  - Olaseni Segun Esan
AU  - Akeremale Olaniran Kolawole
AU  - Aboluwoye Christopher Olumuyiwa
Y1  - 2019/03/21
PY  - 2019
N1  - https://doi.org/10.11648/j.ajpst.20190501.13
DO  - 10.11648/j.ajpst.20190501.13
T2  - American Journal of Polymer Science and Technology
JF  - American Journal of Polymer Science and Technology
JO  - American Journal of Polymer Science and Technology
SP  - 16
EP  - 28
PB  - Science Publishing Group
SN  - 2575-5986
UR  - https://doi.org/10.11648/j.ajpst.20190501.13
AB  - In order to broaden the application of Bentonite clay, an easily obtainable and bio-available low cost adsorbent, it was employed for the decolourization of synthetic wastewater consisting of single and binary basic dyes (Malachite green and Rhodamine b). The adsorbent was used as obtained without any further modification and also characterized for its specific surface area, point of zero charge and its surface functional groups pre and post dyes sorption was determined using Fourier Transform Infrared Spectroscopy (FTIR). Batch adsorption methods were employed in order to study the effects of pH, Ionic strength and contact time in the single solute system. The parameters of sorption of Rhodamine B (RDB) and Malachite green (MG) were obtained and fitted to three isotherm models; Freundlich, Langmuir and Temkin. The Freundlich plot analysis indicated the process occurred via heterogeneous coverage of adsorbent by both dyes. The kinetics of adsorption data were analyzed using the; pseudo-first order, pseudo-second order, Intraparticle diffusion, film diffusion, and Boyd kinetic models. Over the study of these parameters, the film diffusion mechanism was found to predominate in the sorption process of the dyes. Competitive sorption studies were carried out by using both dyes as either the adsorbate of interest or as the interfering specie. The competitive co-coefficient values obtained from interfering MG in RDB removal were significantly lower than those obtained from interfering RDB in MG removal, indicating that the presence of RDB in the aqua matrix had antagonistic effect on MG adsorption by Bentonite.
VL  - 5
IS  - 1
ER  -

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Author Information

Olaseni Segun Esan

Department of Chemical Sciences, Adekunle Ajasin University, Akungba-Akoko, Nigeria
Akeremale Olaniran Kolawole

Department of Chemical Sciences, Adekunle Ajasin University, Akungba-Akoko, Nigeria
Aboluwoye Christopher Olumuyiwa

Department of Chemical Sciences, Adekunle Ajasin University, Akungba-Akoko, Nigeria

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APA Style

Olaseni Segun Esan, Akeremale Olaniran Kolawole, Aboluwoye Christopher Olumuyiwa. (2019). The Removal of Single and Binary Basic Dyes from Synthetic Wastewater Using Bentonite Clay Adsorbent. American Journal of Polymer Science and Technology, 5(1), 16-28. https://doi.org/10.11648/j.ajpst.20190501.13

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ACS Style

Olaseni Segun Esan; Akeremale Olaniran Kolawole; Aboluwoye Christopher Olumuyiwa. The Removal of Single and Binary Basic Dyes from Synthetic Wastewater Using Bentonite Clay Adsorbent. Am. J. Polym. Sci. Technol. 2019, 5(1), 16-28. doi: 10.11648/j.ajpst.20190501.13

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AMA Style

Olaseni Segun Esan, Akeremale Olaniran Kolawole, Aboluwoye Christopher Olumuyiwa. The Removal of Single and Binary Basic Dyes from Synthetic Wastewater Using Bentonite Clay Adsorbent. Am J Polym Sci Technol. 2019;5(1):16-28. doi: 10.11648/j.ajpst.20190501.13

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@article{10.11648/j.ajpst.20190501.13,
  author = {Olaseni Segun Esan and Akeremale Olaniran Kolawole and Aboluwoye Christopher Olumuyiwa},
  title = {The Removal of Single and Binary Basic Dyes from Synthetic Wastewater Using Bentonite Clay Adsorbent},
  journal = {American Journal of Polymer Science and Technology},
  volume = {5},
  number = {1},
  pages = {16-28},
  doi = {10.11648/j.ajpst.20190501.13},
  url = {https://doi.org/10.11648/j.ajpst.20190501.13},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpst.20190501.13},
  abstract = {In order to broaden the application of Bentonite clay, an easily obtainable and bio-available low cost adsorbent, it was employed for the decolourization of synthetic wastewater consisting of single and binary basic dyes (Malachite green and Rhodamine b). The adsorbent was used as obtained without any further modification and also characterized for its specific surface area, point of zero charge and its surface functional groups pre and post dyes sorption was determined using Fourier Transform Infrared Spectroscopy (FTIR). Batch adsorption methods were employed in order to study the effects of pH, Ionic strength and contact time in the single solute system. The parameters of sorption of Rhodamine B (RDB) and Malachite green (MG) were obtained and fitted to three isotherm models; Freundlich, Langmuir and Temkin. The Freundlich plot analysis indicated the process occurred via heterogeneous coverage of adsorbent by both dyes. The kinetics of adsorption data were analyzed using the; pseudo-first order, pseudo-second order, Intraparticle diffusion, film diffusion, and Boyd kinetic models. Over the study of these parameters, the film diffusion mechanism was found to predominate in the sorption process of the dyes. Competitive sorption studies were carried out by using both dyes as either the adsorbate of interest or as the interfering specie. The competitive co-coefficient values obtained from interfering MG in RDB removal were significantly lower than those obtained from interfering RDB in MG removal, indicating that the presence of RDB in the aqua matrix had antagonistic effect on MG adsorption by Bentonite.},
 year = {2019}
}

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TY  - JOUR
T1  - The Removal of Single and Binary Basic Dyes from Synthetic Wastewater Using Bentonite Clay Adsorbent
AU  - Olaseni Segun Esan
AU  - Akeremale Olaniran Kolawole
AU  - Aboluwoye Christopher Olumuyiwa
Y1  - 2019/03/21
PY  - 2019
N1  - https://doi.org/10.11648/j.ajpst.20190501.13
DO  - 10.11648/j.ajpst.20190501.13
T2  - American Journal of Polymer Science and Technology
JF  - American Journal of Polymer Science and Technology
JO  - American Journal of Polymer Science and Technology
SP  - 16
EP  - 28
PB  - Science Publishing Group
SN  - 2575-5986
UR  - https://doi.org/10.11648/j.ajpst.20190501.13
AB  - In order to broaden the application of Bentonite clay, an easily obtainable and bio-available low cost adsorbent, it was employed for the decolourization of synthetic wastewater consisting of single and binary basic dyes (Malachite green and Rhodamine b). The adsorbent was used as obtained without any further modification and also characterized for its specific surface area, point of zero charge and its surface functional groups pre and post dyes sorption was determined using Fourier Transform Infrared Spectroscopy (FTIR). Batch adsorption methods were employed in order to study the effects of pH, Ionic strength and contact time in the single solute system. The parameters of sorption of Rhodamine B (RDB) and Malachite green (MG) were obtained and fitted to three isotherm models; Freundlich, Langmuir and Temkin. The Freundlich plot analysis indicated the process occurred via heterogeneous coverage of adsorbent by both dyes. The kinetics of adsorption data were analyzed using the; pseudo-first order, pseudo-second order, Intraparticle diffusion, film diffusion, and Boyd kinetic models. Over the study of these parameters, the film diffusion mechanism was found to predominate in the sorption process of the dyes. Competitive sorption studies were carried out by using both dyes as either the adsorbate of interest or as the interfering specie. The competitive co-coefficient values obtained from interfering MG in RDB removal were significantly lower than those obtained from interfering RDB in MG removal, indicating that the presence of RDB in the aqua matrix had antagonistic effect on MG adsorption by Bentonite.
VL  - 5
IS  - 1
ER  -

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