Synthesis and Characterization of Bi-Functional Poly (Acrylic Acid-Co-2-hydroxyethylmethacrylate) Coated Iron Oxide Magnetic Composite Particles

Tania Tofaz; Dhananjoy Chandra Mahanto; Shamima Akhter; Md. Mahbubor Rahman; M. Abdul Latif

doi:doi:10.11648/j.ajpst.20190501.11

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Synthesis and Characterization of Bi-Functional Poly (Acrylic Acid-Co-2-hydroxyethylmethacrylate) Coated Iron Oxide Magnetic Composite Particles

Tania Tofaz, Dhananjoy Chandra Mahanto, Shamima Akhter, Md. Mahbubor Rahman, M. Abdul Latif

Published in American Journal of Polymer Science and Technology (Volume 5, Issue 1)

Received: 7 January 2019 Accepted: 11 February 2019 Published: 5 March 2019

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Abstract

This paper covers the targetable magnetic iron oxide core and biodegradable, cost-effective, eco-friendly polymer shell considering their versatile and extensive use in various fields. In this work, poly (acrylic acid–co-2-hydroxyethylmethacrylate) [P (AA-co-HEMA)] magnetic composite polymer particles were synthesized by the method of two-stage solution polymerization in aqueous media. At first synthesis, the Fe3O4 particles by a traditional co-precipitation method and in the second stage occurs the formation of the polymer using acrylic acid (AA) as monomer and 2-hydroxyethyl methacrylate (HEMA) as co-monomer. Finally, the synthesized iron oxide particles encapsulated by a polymer to modify the surface of composite particles. The modified composite particles were then characterized by Scanning Electron Microscopy (SEM), Fourier Transform Infrared Spectroscopy (FTIR), X-ray Diffractometry (XRD), Dynamic Light Scattering (DLS), Thermo Gravimetric Analysis (TGA) and Vibrating Sample Magnetometry (VSM). The existence of carboxyl (-COOH) & hydroxyl (-OH) groups in the composite particles was confirmed by FTIR. XRD indicated the crystalline cubic spinel structure of magnetic composite particles. VSM results showed that the synthesized coated composite particles were paramagnetic in nature magnetic saturation is obtained 72.72 emu/g and 97.9 emu/g for bare Fe3O4 and coated magnetic composite particles respectively.

Published in	American Journal of Polymer Science and Technology (Volume 5, Issue 1)
DOI	10.11648/j.ajpst.20190501.11
Page(s)	1-8
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2019. Published by Science Publishing Group

Keywords

Radical Copolymerization, AA, HEMA, MNPs

References

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Tania Tofaz, Dhananjoy Chandra Mahanto, Shamima Akhter, Md. Mahbubor Rahman, M. Abdul Latif. (2019). Synthesis and Characterization of Bi-Functional Poly (Acrylic Acid-Co-2-hydroxyethylmethacrylate) Coated Iron Oxide Magnetic Composite Particles. American Journal of Polymer Science and Technology, 5(1), 1-8. https://doi.org/10.11648/j.ajpst.20190501.11

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ACS Style

Tania Tofaz; Dhananjoy Chandra Mahanto; Shamima Akhter; Md. Mahbubor Rahman; M. Abdul Latif. Synthesis and Characterization of Bi-Functional Poly (Acrylic Acid-Co-2-hydroxyethylmethacrylate) Coated Iron Oxide Magnetic Composite Particles. Am. J. Polym. Sci. Technol. 2019, 5(1), 1-8. doi: 10.11648/j.ajpst.20190501.11

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AMA Style

Tania Tofaz, Dhananjoy Chandra Mahanto, Shamima Akhter, Md. Mahbubor Rahman, M. Abdul Latif. Synthesis and Characterization of Bi-Functional Poly (Acrylic Acid-Co-2-hydroxyethylmethacrylate) Coated Iron Oxide Magnetic Composite Particles. Am J Polym Sci Technol. 2019;5(1):1-8. doi: 10.11648/j.ajpst.20190501.11

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@article{10.11648/j.ajpst.20190501.11,
  author = {Tania Tofaz and Dhananjoy Chandra Mahanto and Shamima Akhter and Md. Mahbubor Rahman and M. Abdul Latif},
  title = {Synthesis and Characterization of Bi-Functional Poly (Acrylic Acid-Co-2-hydroxyethylmethacrylate) Coated Iron Oxide Magnetic Composite Particles},
  journal = {American Journal of Polymer Science and Technology},
  volume = {5},
  number = {1},
  pages = {1-8},
  doi = {10.11648/j.ajpst.20190501.11},
  url = {https://doi.org/10.11648/j.ajpst.20190501.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpst.20190501.11},
  abstract = {This paper covers the targetable magnetic iron oxide core and biodegradable, cost-effective, eco-friendly polymer shell considering their versatile and extensive use in various fields. In this work, poly (acrylic acid–co-2-hydroxyethylmethacrylate) [P (AA-co-HEMA)] magnetic composite polymer particles were synthesized by the method of two-stage solution polymerization in aqueous media. At first synthesis, the Fe3O4 particles by a traditional co-precipitation method and in the second stage occurs the formation of the polymer using acrylic acid (AA) as monomer and 2-hydroxyethyl methacrylate (HEMA) as co-monomer. Finally, the synthesized iron oxide particles encapsulated by a polymer to modify the surface of composite particles. The modified composite particles were then characterized by Scanning Electron Microscopy (SEM), Fourier Transform Infrared Spectroscopy (FTIR), X-ray Diffractometry (XRD), Dynamic Light Scattering (DLS), Thermo Gravimetric Analysis (TGA) and Vibrating Sample Magnetometry (VSM). The existence of carboxyl (-COOH) & hydroxyl (-OH) groups in the composite particles was confirmed by FTIR. XRD indicated the crystalline cubic spinel structure of magnetic composite particles. VSM results showed that the synthesized coated composite particles were paramagnetic in nature magnetic saturation is obtained 72.72 emu/g and 97.9 emu/g for bare Fe3O4 and coated magnetic composite particles respectively.},
 year = {2019}
}

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TY  - JOUR
T1  - Synthesis and Characterization of Bi-Functional Poly (Acrylic Acid-Co-2-hydroxyethylmethacrylate) Coated Iron Oxide Magnetic Composite Particles
AU  - Tania Tofaz
AU  - Dhananjoy Chandra Mahanto
AU  - Shamima Akhter
AU  - Md. Mahbubor Rahman
AU  - M. Abdul Latif
Y1  - 2019/03/05
PY  - 2019
N1  - https://doi.org/10.11648/j.ajpst.20190501.11
DO  - 10.11648/j.ajpst.20190501.11
T2  - American Journal of Polymer Science and Technology
JF  - American Journal of Polymer Science and Technology
JO  - American Journal of Polymer Science and Technology
SP  - 1
EP  - 8
PB  - Science Publishing Group
SN  - 2575-5986
UR  - https://doi.org/10.11648/j.ajpst.20190501.11
AB  - This paper covers the targetable magnetic iron oxide core and biodegradable, cost-effective, eco-friendly polymer shell considering their versatile and extensive use in various fields. In this work, poly (acrylic acid–co-2-hydroxyethylmethacrylate) [P (AA-co-HEMA)] magnetic composite polymer particles were synthesized by the method of two-stage solution polymerization in aqueous media. At first synthesis, the Fe3O4 particles by a traditional co-precipitation method and in the second stage occurs the formation of the polymer using acrylic acid (AA) as monomer and 2-hydroxyethyl methacrylate (HEMA) as co-monomer. Finally, the synthesized iron oxide particles encapsulated by a polymer to modify the surface of composite particles. The modified composite particles were then characterized by Scanning Electron Microscopy (SEM), Fourier Transform Infrared Spectroscopy (FTIR), X-ray Diffractometry (XRD), Dynamic Light Scattering (DLS), Thermo Gravimetric Analysis (TGA) and Vibrating Sample Magnetometry (VSM). The existence of carboxyl (-COOH) & hydroxyl (-OH) groups in the composite particles was confirmed by FTIR. XRD indicated the crystalline cubic spinel structure of magnetic composite particles. VSM results showed that the synthesized coated composite particles were paramagnetic in nature magnetic saturation is obtained 72.72 emu/g and 97.9 emu/g for bare Fe3O4 and coated magnetic composite particles respectively.
VL  - 5
IS  - 1
ER  -

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Author Information

Tania Tofaz

Department of Chemistry, Begum Rokeya University, Rangpur, Bangladesh
Dhananjoy Chandra Mahanto

Department of Chemistry, Begum Rokeya University, Rangpur, Bangladesh
Shamima Akhter

Department of Chemistry, Begum Rokeya University, Rangpur, Bangladesh
Md. Mahbubor Rahman

Department of Chemistry, University of Rajshahi, Rajshahi, Bangladesh
M. Abdul Latif

Department of Chemistry, Begum Rokeya University, Rangpur, Bangladesh

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Tania Tofaz, Dhananjoy Chandra Mahanto, Shamima Akhter, Md. Mahbubor Rahman, M. Abdul Latif. (2019). Synthesis and Characterization of Bi-Functional Poly (Acrylic Acid-Co-2-hydroxyethylmethacrylate) Coated Iron Oxide Magnetic Composite Particles. American Journal of Polymer Science and Technology, 5(1), 1-8. https://doi.org/10.11648/j.ajpst.20190501.11

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ACS Style

Tania Tofaz; Dhananjoy Chandra Mahanto; Shamima Akhter; Md. Mahbubor Rahman; M. Abdul Latif. Synthesis and Characterization of Bi-Functional Poly (Acrylic Acid-Co-2-hydroxyethylmethacrylate) Coated Iron Oxide Magnetic Composite Particles. Am. J. Polym. Sci. Technol. 2019, 5(1), 1-8. doi: 10.11648/j.ajpst.20190501.11

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AMA Style

Tania Tofaz, Dhananjoy Chandra Mahanto, Shamima Akhter, Md. Mahbubor Rahman, M. Abdul Latif. Synthesis and Characterization of Bi-Functional Poly (Acrylic Acid-Co-2-hydroxyethylmethacrylate) Coated Iron Oxide Magnetic Composite Particles. Am J Polym Sci Technol. 2019;5(1):1-8. doi: 10.11648/j.ajpst.20190501.11

Copy | Download

@article{10.11648/j.ajpst.20190501.11,
  author = {Tania Tofaz and Dhananjoy Chandra Mahanto and Shamima Akhter and Md. Mahbubor Rahman and M. Abdul Latif},
  title = {Synthesis and Characterization of Bi-Functional Poly (Acrylic Acid-Co-2-hydroxyethylmethacrylate) Coated Iron Oxide Magnetic Composite Particles},
  journal = {American Journal of Polymer Science and Technology},
  volume = {5},
  number = {1},
  pages = {1-8},
  doi = {10.11648/j.ajpst.20190501.11},
  url = {https://doi.org/10.11648/j.ajpst.20190501.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpst.20190501.11},
  abstract = {This paper covers the targetable magnetic iron oxide core and biodegradable, cost-effective, eco-friendly polymer shell considering their versatile and extensive use in various fields. In this work, poly (acrylic acid–co-2-hydroxyethylmethacrylate) [P (AA-co-HEMA)] magnetic composite polymer particles were synthesized by the method of two-stage solution polymerization in aqueous media. At first synthesis, the Fe3O4 particles by a traditional co-precipitation method and in the second stage occurs the formation of the polymer using acrylic acid (AA) as monomer and 2-hydroxyethyl methacrylate (HEMA) as co-monomer. Finally, the synthesized iron oxide particles encapsulated by a polymer to modify the surface of composite particles. The modified composite particles were then characterized by Scanning Electron Microscopy (SEM), Fourier Transform Infrared Spectroscopy (FTIR), X-ray Diffractometry (XRD), Dynamic Light Scattering (DLS), Thermo Gravimetric Analysis (TGA) and Vibrating Sample Magnetometry (VSM). The existence of carboxyl (-COOH) & hydroxyl (-OH) groups in the composite particles was confirmed by FTIR. XRD indicated the crystalline cubic spinel structure of magnetic composite particles. VSM results showed that the synthesized coated composite particles were paramagnetic in nature magnetic saturation is obtained 72.72 emu/g and 97.9 emu/g for bare Fe3O4 and coated magnetic composite particles respectively.},
 year = {2019}
}

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TY  - JOUR
T1  - Synthesis and Characterization of Bi-Functional Poly (Acrylic Acid-Co-2-hydroxyethylmethacrylate) Coated Iron Oxide Magnetic Composite Particles
AU  - Tania Tofaz
AU  - Dhananjoy Chandra Mahanto
AU  - Shamima Akhter
AU  - Md. Mahbubor Rahman
AU  - M. Abdul Latif
Y1  - 2019/03/05
PY  - 2019
N1  - https://doi.org/10.11648/j.ajpst.20190501.11
DO  - 10.11648/j.ajpst.20190501.11
T2  - American Journal of Polymer Science and Technology
JF  - American Journal of Polymer Science and Technology
JO  - American Journal of Polymer Science and Technology
SP  - 1
EP  - 8
PB  - Science Publishing Group
SN  - 2575-5986
UR  - https://doi.org/10.11648/j.ajpst.20190501.11
AB  - This paper covers the targetable magnetic iron oxide core and biodegradable, cost-effective, eco-friendly polymer shell considering their versatile and extensive use in various fields. In this work, poly (acrylic acid–co-2-hydroxyethylmethacrylate) [P (AA-co-HEMA)] magnetic composite polymer particles were synthesized by the method of two-stage solution polymerization in aqueous media. At first synthesis, the Fe3O4 particles by a traditional co-precipitation method and in the second stage occurs the formation of the polymer using acrylic acid (AA) as monomer and 2-hydroxyethyl methacrylate (HEMA) as co-monomer. Finally, the synthesized iron oxide particles encapsulated by a polymer to modify the surface of composite particles. The modified composite particles were then characterized by Scanning Electron Microscopy (SEM), Fourier Transform Infrared Spectroscopy (FTIR), X-ray Diffractometry (XRD), Dynamic Light Scattering (DLS), Thermo Gravimetric Analysis (TGA) and Vibrating Sample Magnetometry (VSM). The existence of carboxyl (-COOH) & hydroxyl (-OH) groups in the composite particles was confirmed by FTIR. XRD indicated the crystalline cubic spinel structure of magnetic composite particles. VSM results showed that the synthesized coated composite particles were paramagnetic in nature magnetic saturation is obtained 72.72 emu/g and 97.9 emu/g for bare Fe3O4 and coated magnetic composite particles respectively.
VL  - 5
IS  - 1
ER  -

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