Facilitated Transport of Lysine Acetylsalicylate Through Supported Liquid Membrane Using Methyl Cholate as Carrier: Parameters and Mechanism

Oussama Kamal; Tarik Eljaddi; Habib Mouadili; El Houssaine EL Atmani; Laurent Lebrun; Miloudi Hlaïbi

doi:doi:10.11648/j.ajche.20170504.11

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Facilitated Transport of Lysine Acetylsalicylate Through Supported Liquid Membrane Using Methyl Cholate as Carrier: Parameters and Mechanism

Oussama Kamal, Tarik Eljaddi, Habib Mouadili, El Houssaine EL Atmani, Laurent Lebrun, Miloudi Hlaïbi

Published in American Journal of Chemical Engineering (Volume 5, Issue 4)

Received: 15 April 2017 Accepted: 5 May 2017 Published: 21 June 2017

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Abstract

Transport of lysine acetylsalicylate (LAS) through supported liquid membrane was investigated using methyl cholate (MC) as extractive agent. Kinetic and thermodynamic models were developed, based on the interaction of the substrate LAS with the extractive agent T, and the diffusion of the formed entity (TS) through the membrane. The experimental results verify the models and enable the determination of macroscopic parameters (permeabilities (P) and initial fluxes (J₀)), as well as microscopic parameters (association constants (K_ass), and apparent diffusion coefficients (D^*)), relating to formed entity (TS) and its diffusion through the membrane organic phase. Parameters such as initial concentration of the substrate in the feed phase, pH of the feed and stripping phases and temperature of the extraction medium were studied. The results obtain indicate that the mechanism of the migration of LAS through the membrane organic phase cannot be a pure diffusion movement but it takes place by successive jumps from one site to another of the extractive agent, via interaction reactions with LAS.

Published in	American Journal of Chemical Engineering (Volume 5, Issue 4)
DOI	10.11648/j.ajche.20170504.11
Page(s)	49-55
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2017. Published by Science Publishing Group

Keywords

Facilitated Transport, Supported Liquid Membranes, Permeability, Flux, Activation Parameters

References

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APA Style

Oussama Kamal, Tarik Eljaddi, Habib Mouadili, El Houssaine EL Atmani, Laurent Lebrun, et al. (2017). Facilitated Transport of Lysine Acetylsalicylate Through Supported Liquid Membrane Using Methyl Cholate as Carrier: Parameters and Mechanism. American Journal of Chemical Engineering, 5(4), 49-55. https://doi.org/10.11648/j.ajche.20170504.11

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ACS Style

Oussama Kamal; Tarik Eljaddi; Habib Mouadili; El Houssaine EL Atmani; Laurent Lebrun, et al. Facilitated Transport of Lysine Acetylsalicylate Through Supported Liquid Membrane Using Methyl Cholate as Carrier: Parameters and Mechanism. Am. J. Chem. Eng. 2017, 5(4), 49-55. doi: 10.11648/j.ajche.20170504.11

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AMA Style

Oussama Kamal, Tarik Eljaddi, Habib Mouadili, El Houssaine EL Atmani, Laurent Lebrun, et al. Facilitated Transport of Lysine Acetylsalicylate Through Supported Liquid Membrane Using Methyl Cholate as Carrier: Parameters and Mechanism. Am J Chem Eng. 2017;5(4):49-55. doi: 10.11648/j.ajche.20170504.11

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@article{10.11648/j.ajche.20170504.11,
  author = {Oussama Kamal and Tarik Eljaddi and Habib Mouadili and El Houssaine EL Atmani and Laurent Lebrun and Miloudi Hlaïbi},
  title = {Facilitated Transport of Lysine Acetylsalicylate Through Supported Liquid Membrane Using Methyl Cholate as Carrier: Parameters and Mechanism},
  journal = {American Journal of Chemical Engineering},
  volume = {5},
  number = {4},
  pages = {49-55},
  doi = {10.11648/j.ajche.20170504.11},
  url = {https://doi.org/10.11648/j.ajche.20170504.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajche.20170504.11},
  abstract = {Transport of lysine acetylsalicylate (LAS) through supported liquid membrane was investigated using methyl cholate (MC) as extractive agent. Kinetic and thermodynamic models were developed, based on the interaction of the substrate LAS with the extractive agent T, and the diffusion of the formed entity (TS) through the membrane. The experimental results verify the models and enable the determination of macroscopic parameters (permeabilities (P) and initial fluxes (J0)), as well as microscopic parameters (association constants (Kass), and apparent diffusion coefficients (D*)), relating to formed entity (TS) and its diffusion through the membrane organic phase. Parameters such as initial concentration of the substrate in the feed phase, pH of the feed and stripping phases and temperature of the extraction medium were studied. The results obtain indicate that the mechanism of the migration of LAS through the membrane organic phase cannot be a pure diffusion movement but it takes place by successive jumps from one site to another of the extractive agent, via interaction reactions with LAS.},
 year = {2017}
}

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TY  - JOUR
T1  - Facilitated Transport of Lysine Acetylsalicylate Through Supported Liquid Membrane Using Methyl Cholate as Carrier: Parameters and Mechanism
AU  - Oussama Kamal
AU  - Tarik Eljaddi
AU  - Habib Mouadili
AU  - El Houssaine EL Atmani
AU  - Laurent Lebrun
AU  - Miloudi Hlaïbi
Y1  - 2017/06/21
PY  - 2017
N1  - https://doi.org/10.11648/j.ajche.20170504.11
DO  - 10.11648/j.ajche.20170504.11
T2  - American Journal of Chemical Engineering
JF  - American Journal of Chemical Engineering
JO  - American Journal of Chemical Engineering
SP  - 49
EP  - 55
PB  - Science Publishing Group
SN  - 2330-8613
UR  - https://doi.org/10.11648/j.ajche.20170504.11
AB  - Transport of lysine acetylsalicylate (LAS) through supported liquid membrane was investigated using methyl cholate (MC) as extractive agent. Kinetic and thermodynamic models were developed, based on the interaction of the substrate LAS with the extractive agent T, and the diffusion of the formed entity (TS) through the membrane. The experimental results verify the models and enable the determination of macroscopic parameters (permeabilities (P) and initial fluxes (J0)), as well as microscopic parameters (association constants (Kass), and apparent diffusion coefficients (D*)), relating to formed entity (TS) and its diffusion through the membrane organic phase. Parameters such as initial concentration of the substrate in the feed phase, pH of the feed and stripping phases and temperature of the extraction medium were studied. The results obtain indicate that the mechanism of the migration of LAS through the membrane organic phase cannot be a pure diffusion movement but it takes place by successive jumps from one site to another of the extractive agent, via interaction reactions with LAS.
VL  - 5
IS  - 4
ER  -

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Author Information

Oussama Kamal

Laboratory of Materials Engineering for the Environment and Valuation, Faculty of Sciences A?n Chock, University Hassan II, Casablanca, Morocco
Tarik Eljaddi

Laboratory of Materials Engineering for the Environment and Valuation, Faculty of Sciences A?n Chock, University Hassan II, Casablanca, Morocco
Habib Mouadili

Laboratory of Materials Engineering for the Environment and Valuation, Faculty of Sciences A?n Chock, University Hassan II, Casablanca, Morocco
El Houssaine EL Atmani

Laboratory of Materials Engineering for the Environment and Valuation, Faculty of Sciences A?n Chock, University Hassan II, Casablanca, Morocco
Laurent Lebrun

Laboratory of Polymeres Biopolymeres Surfaces, Faculty des Sciences, University of Rouen, Mont-Saint-Aignan, France
Miloudi Hlaïbi

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APA Style

Oussama Kamal, Tarik Eljaddi, Habib Mouadili, El Houssaine EL Atmani, Laurent Lebrun, et al. (2017). Facilitated Transport of Lysine Acetylsalicylate Through Supported Liquid Membrane Using Methyl Cholate as Carrier: Parameters and Mechanism. American Journal of Chemical Engineering, 5(4), 49-55. https://doi.org/10.11648/j.ajche.20170504.11

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ACS Style

Oussama Kamal; Tarik Eljaddi; Habib Mouadili; El Houssaine EL Atmani; Laurent Lebrun, et al. Facilitated Transport of Lysine Acetylsalicylate Through Supported Liquid Membrane Using Methyl Cholate as Carrier: Parameters and Mechanism. Am. J. Chem. Eng. 2017, 5(4), 49-55. doi: 10.11648/j.ajche.20170504.11

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AMA Style

Oussama Kamal, Tarik Eljaddi, Habib Mouadili, El Houssaine EL Atmani, Laurent Lebrun, et al. Facilitated Transport of Lysine Acetylsalicylate Through Supported Liquid Membrane Using Methyl Cholate as Carrier: Parameters and Mechanism. Am J Chem Eng. 2017;5(4):49-55. doi: 10.11648/j.ajche.20170504.11

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@article{10.11648/j.ajche.20170504.11,
  author = {Oussama Kamal and Tarik Eljaddi and Habib Mouadili and El Houssaine EL Atmani and Laurent Lebrun and Miloudi Hlaïbi},
  title = {Facilitated Transport of Lysine Acetylsalicylate Through Supported Liquid Membrane Using Methyl Cholate as Carrier: Parameters and Mechanism},
  journal = {American Journal of Chemical Engineering},
  volume = {5},
  number = {4},
  pages = {49-55},
  doi = {10.11648/j.ajche.20170504.11},
  url = {https://doi.org/10.11648/j.ajche.20170504.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajche.20170504.11},
  abstract = {Transport of lysine acetylsalicylate (LAS) through supported liquid membrane was investigated using methyl cholate (MC) as extractive agent. Kinetic and thermodynamic models were developed, based on the interaction of the substrate LAS with the extractive agent T, and the diffusion of the formed entity (TS) through the membrane. The experimental results verify the models and enable the determination of macroscopic parameters (permeabilities (P) and initial fluxes (J0)), as well as microscopic parameters (association constants (Kass), and apparent diffusion coefficients (D*)), relating to formed entity (TS) and its diffusion through the membrane organic phase. Parameters such as initial concentration of the substrate in the feed phase, pH of the feed and stripping phases and temperature of the extraction medium were studied. The results obtain indicate that the mechanism of the migration of LAS through the membrane organic phase cannot be a pure diffusion movement but it takes place by successive jumps from one site to another of the extractive agent, via interaction reactions with LAS.},
 year = {2017}
}

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TY  - JOUR
T1  - Facilitated Transport of Lysine Acetylsalicylate Through Supported Liquid Membrane Using Methyl Cholate as Carrier: Parameters and Mechanism
AU  - Oussama Kamal
AU  - Tarik Eljaddi
AU  - Habib Mouadili
AU  - El Houssaine EL Atmani
AU  - Laurent Lebrun
AU  - Miloudi Hlaïbi
Y1  - 2017/06/21
PY  - 2017
N1  - https://doi.org/10.11648/j.ajche.20170504.11
DO  - 10.11648/j.ajche.20170504.11
T2  - American Journal of Chemical Engineering
JF  - American Journal of Chemical Engineering
JO  - American Journal of Chemical Engineering
SP  - 49
EP  - 55
PB  - Science Publishing Group
SN  - 2330-8613
UR  - https://doi.org/10.11648/j.ajche.20170504.11
AB  - Transport of lysine acetylsalicylate (LAS) through supported liquid membrane was investigated using methyl cholate (MC) as extractive agent. Kinetic and thermodynamic models were developed, based on the interaction of the substrate LAS with the extractive agent T, and the diffusion of the formed entity (TS) through the membrane. The experimental results verify the models and enable the determination of macroscopic parameters (permeabilities (P) and initial fluxes (J0)), as well as microscopic parameters (association constants (Kass), and apparent diffusion coefficients (D*)), relating to formed entity (TS) and its diffusion through the membrane organic phase. Parameters such as initial concentration of the substrate in the feed phase, pH of the feed and stripping phases and temperature of the extraction medium were studied. The results obtain indicate that the mechanism of the migration of LAS through the membrane organic phase cannot be a pure diffusion movement but it takes place by successive jumps from one site to another of the extractive agent, via interaction reactions with LAS.
VL  - 5
IS  - 4
ER  -

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