Corrosion has adverse environmental consequences since it affects the manufacturing sector resulting in enormous economic loss. The corrosion characteristics and mechanism of mild in the solution of hydrochloric acid was studied. Extract of bush cane (Costus afer) was screened for physicochemical and phytochemical properties and utilized as corrosion inhibitor for mild steel, the process was optimized using Response Surface Methodology (RSM). The presence of OH, NH of alcohols, phenols, or substituents connected to aromatic rings, C=O for amides and ketones, C-N of aliphatic amines, and C=C of alkenes and nitriles were shown using Fourier Transform Infrared Spectroscopy (FTIR). The optimum condition was found by minimizing time, temperature, inhibitor concentration and corrosion rate while maximizing weight loss, and inhibitor efficiency. The results obtained revealed that the bush cane extract contain saponin, flavonoid, alkaloid and tannin, which suggests the potency of the extract as a good inhibitor as it contains a considerable amount of phytochemical with basic heteroatom. The statistical significance of the weight loss, corrosion rate and inhibitor efficiency were evaluated using the analysis of variance (ANOVA). it was observed that the regression was statistically significant at the F-value of 94.60, 25.87 and 4.72 respectively. P-value of > 0.0235, > 0.0001 and 0.0265 respectively. The optimum temperature, inhibitor concentration and contact time were found to be 27.9°C, 20.0% and 5 hours respectively at desirability value of 0.637. At this optimum condition, the weight loss was found to be 0.102%, corrosion rate was 1.583mg/cm2hr and inhibitor efficiency was 62.9%. From the results obtained in this experiment, It is concluded that the bushcane extract can be used as a corrosion inhibitor for the protection of mild steel.
| Published in | World Journal of Applied Chemistry (Volume 9, Issue 2) |
| DOI | 10.11648/j.wjac.20240902.11 |
| Page(s) | 15-24 |
| Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
| Copyright |
Copyright © The Author(s), 2024. Published by Science Publishing Group |
Mild Steel, Plant Extract, Corrosion Inhibitor, Hydrochloric Acid (HCl)
| [1] | Parajuli, D. Sharma, S Oli, H. B. Bohara, D. S. Bhattarai, D. P. Tiwari, A. P. Yadav. A. P. (2022). Comparative Study of Corrosion Inhibition Efficacy of Alkaloid Extract of Artemesia vulgaris and Solanum tuberosum in Mild Steel Samples in 1 M Sulphuric Acid, Electrochem, 3, 416–433. |
| [2] | Oli, H. B. J. Thapa Magar, N. Khadka, A. Subedee, D. P. Bhattarai, B. Pant. (2022). Coriaria nepalensis Stem Alkaloid as a Green Inhibitor for Mild Steel Corrosion in 1 M H2SO4 Solution, Electrochem, 3, 713–727. |
| [3] | Thapa, B, Gupta, D. K. D. and Yadav, Y. P. (2019). Corrosion Inhibition of Bark Extract of Euphorbia royleana on Mild Steel in 1M HCl. Journal of Nepal Chemical Society 40. 25-29. |
| [4] | Landolt, D. (2007). Corrosion and Surface Chemistry of Metals, 1st Ed., EPFL press, New York. |
| [5] | Yaro, A. S., Khadom, A. A., & Wael, R. K. (2013). Apricot juice as green corrosion inhibitor of mild steel in phosphoric acid. Alexandria Engineering Journal, 52(1), 129-135. |
| [6] | Satapathy, A., Gunasekaran, G., Sahoo, S., Amit, K., and Rodrigues, P. (2009). Corrosion inhibition by Justicia gendarussa plant extract in hydrochloric acid solution. Corrosion Science, 51(12), 2848-2856. |
| [7] | Adams, S., Aigbodion, V., Suleiman, I., ancd Momoh, I. (2019). Thermodynamic, Kinetic and Adsorptive Parameters of Corrosion Inhibition of Mild Steel Using Polyalthialongifolia Bark Extract in 0.5 M H2SO4. International Journal of Science and Engineering Invention, 5(11), 1-7. |
| [8] | Al-Otaibi, M., Al-Mayouf, A., Khan, M., Mousa, A., Al-Mazroa, S., &Alkhathlan, H. (2014). Corrosion inhibitory action of some plant extracts on the corrosion of mild steel in acidic media. Arabian Journal of Chemistry, 7(3), 340-346. |
| [9] | Chigondo, M and Chigondo, F. (2016). Recent Natural Corrosion Inhibitors for Mild Steel: An Overview. Journal of Chemistry 10, 1-7. |
| [10] | Halambek, J., Berkovic, K. Vorkapic ´-Furac, J. (2010), The influence of Lavandula angustifolia L. oil on corrosion of Al–3Mg alloy, Corrosion Science, 53, 978–3983. |
| [11] | Umoren, S. A., Eduok, U. M. Solomon, M. M. and Udoh, A. P. Corrosion inhibition by leaves and stem extracts of Sida acuta for mild steel in 1 M H2SO4 solutions investigated by chemical and spectroscopic techniques, Arabian Journal of Chemistry, 2016, 9, 209-224. |
| [12] | AmithaRani B. E. and Bashu, B. B. J. (2012). Green inhibitors for corrosion protection of metals and alloys: an overview, International Journal of Corrosion, 2012. |
| [13] | Shrestha, P. R., Oli, H. B., Thapa, B., Chaudhary, Y., Gupta, A D. K., Das, K., Nakarmi, K. B., Singh, S., Karki N. and Yadav, A. P. (2019). Bark extract of Lantana camara in 1M HCl as green corrosion inhibitor for mild steel, Engineering Journal, 23(4), 205-211. |
| [14] | Rahman, M. U., Gul, S. Umair, M. Anwar A. and Achakzai, A. K. K. (2016). Anticorrosive activity of Rosemarinus officinalis L. leaves extract against mild steel in dilute hydrochloric acid, International Journal Innovative Research in Advanced Engineering (IJIRAE), 3(3), 38-43. |
| [15] | Akalezi, C. O.; Oguzie, E. E.; Ogukwe, C. E.; EJele, E. A. (2015). Rothmannia longifloraextract as corrosion inhibitor for mild steel in acidic media. International Journal of Industrial Chemistry, 6(4), 273–284. |
| [16] | Al-Shamkhani, M. T. and Ateik, A. A. (2018). Use of Experimental Designs to Evaluate the Influence of Ziziphus Leaves Extracts as a Corrosion Inhibitor for Mild Steel in (3.5 M) NaCl. International Journal of Applied Engineering Research 13(10) 7416-7423. |
| [17] | Ihebrodike, MM; Anthony, AU; Kelechukwu, BO; Alozie, GA; (2010). The inhibition effect of Solanummelongena L, leaf extract on the corrosion of aluminium in tetraoxosulphate (VI) acid, Afr. J. Pure Appl. Chem. 4: 158–165. |
| [18] | Alice A., Abimbola P, and Modupeola D, (2023). Optimization of avocado seed nanoparticle extract (ASNE) as green inhibitor on API X65 steel corrosion using response surface methodology. MATEC Web of Conferences 388, 07007. |
| [19] | Nwachukwu C., Dagwa I. M., Ugheoke B. I. (2021). Optimization of Blended Guava and Fluted Pumpkin Leaves extract as corrosion inhibitor of mild steel in 0.5 m hydrochloric acid. Niger. J. Technol.; 40: 393–403. |
| [20] | Ajeigbe, S. O., Basar, N., Hassan, M. A. and Aziz, M (2017). Optimization of Corrosion Inhibition of Essential Oils of Alpinia Galanga on Mild Steel Using Response Surface Methodology. ARPN Journal of Engineering and Applied Sciences. 12(9), 2762-2771. |
| [21] | Olawale O, Ogunsemi, B. T, Ogundipe, S. J, Abayomi, S. T, Uguru-Okorie D, Okunnola, A. A, Oni, S. O, Kolawole, O. D and Ikpotokin I. (2018). Optimization Of Katemfe Seed Extract As A Corrosion Inhibitor For Mild-Steel In 0.5m Hcl. International Journal of Civil Engineering and Technology (IJCIET). 9(13). 1394-1402. |
| [22] | Kumari, P. and Lavanya, M. (2021). Optimization of Inhibition Efficiency of a Schiff Base on Mild Steel in Acid Medium: Electrochemical and RSM Approach. J Bio Tribo Corros 7, 110. |
| [23] | Oyewole, O., Adeoye, J. B., Udoh, C. V. and Oshin, T. A. (2023). Optimization and corrosion inhibition of Palm kernel leaves on mild steel in oil and gas applications. Egyptian Journal of Petroleum 32 41–46. |
| [24] | Omran, M. A., Fawzy, M., Mahmoud, A. E., Abdullatef O. A. (2023). Optimization of mild steel corrosion inhibition by water hyacinth and common reed extracts in acid media using factorial experimental design. Green Chemistry Letters and Reviews2022, 15(1), 216–232. |
| [25] | Ikezu U. J. M., Ikpa C. B. C. and Osondu, M. C. (2016). The Preliminary Study on the Pharmaceutical Constituents of Methanol Extract of Costus afer (Okpete). IDOSR Journal of Experimental Sciences 1(1): 21-30. |
| [26] | Anyasor G. N., Ogunwenmo, K. O., Oyelana, O. A. and Akpofunure, B. E. (2010). Phytochemical constituents and antioxidant activities of aqueous and methanol stem extracts of Costus afer Ker Gawl. (Costaceae). African Journal of Biotechnology 9(31), pp. 4880-4884. |
| [27] | Hmamou, D. B., Salghi, R., Bazzi, L. Hammouti, B. Al-Deyab, S. S. Bammoul, L. Bazzi L. and Bouyanzer, A. (2012). Prickly pear seed oil extract: A novel green inhibitor for mild steel corrosion in 1 M HCl solution, International Journal of Electrochemical Science, 7, 1303-1318. |
APA Style
Adam, J. A., Oboh, I. O., Peter, I. S., Adum, U. U. (2024). Utilization of Extract from Bushcane (Costus Afer) as Green Corrosion Inhibitor for Mild Steel. World Journal of Applied Chemistry, 9(2), 15-24. https://doi.org/10.11648/j.wjac.20240902.11
ACS Style
Adam, J. A.; Oboh, I. O.; Peter, I. S.; Adum, U. U. Utilization of Extract from Bushcane (Costus Afer) as Green Corrosion Inhibitor for Mild Steel. World J. Appl. Chem. 2024, 9(2), 15-24. doi: 10.11648/j.wjac.20240902.11
AMA Style
Adam JA, Oboh IO, Peter IS, Adum UU. Utilization of Extract from Bushcane (Costus Afer) as Green Corrosion Inhibitor for Mild Steel. World J Appl Chem. 2024;9(2):15-24. doi: 10.11648/j.wjac.20240902.11
Share This Article
Twitter
Linked In
Facebook
Copy
Download@article{10.11648/j.wjac.20240902.11,
author = {Joshua Asukwo Adam and Innocent Oseribho Oboh and Idara Sylvanus Peter and Ubelejit Uche Adum},
title = {Utilization of Extract from Bushcane (Costus Afer) as Green Corrosion Inhibitor for Mild Steel
},
journal = {World Journal of Applied Chemistry},
volume = {9},
number = {2},
pages = {15-24},
doi = {10.11648/j.wjac.20240902.11},
url = {https://doi.org/10.11648/j.wjac.20240902.11},
eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.wjac.20240902.11},
abstract = {Corrosion has adverse environmental consequences since it affects the manufacturing sector resulting in enormous economic loss. The corrosion characteristics and mechanism of mild in the solution of hydrochloric acid was studied. Extract of bush cane (Costus afer) was screened for physicochemical and phytochemical properties and utilized as corrosion inhibitor for mild steel, the process was optimized using Response Surface Methodology (RSM). The presence of OH, NH of alcohols, phenols, or substituents connected to aromatic rings, C=O for amides and ketones, C-N of aliphatic amines, and C=C of alkenes and nitriles were shown using Fourier Transform Infrared Spectroscopy (FTIR). The optimum condition was found by minimizing time, temperature, inhibitor concentration and corrosion rate while maximizing weight loss, and inhibitor efficiency. The results obtained revealed that the bush cane extract contain saponin, flavonoid, alkaloid and tannin, which suggests the potency of the extract as a good inhibitor as it contains a considerable amount of phytochemical with basic heteroatom. The statistical significance of the weight loss, corrosion rate and inhibitor efficiency were evaluated using the analysis of variance (ANOVA). it was observed that the regression was statistically significant at the F-value of 94.60, 25.87 and 4.72 respectively. P-value of > 0.0235, > 0.0001 and 0.0265 respectively. The optimum temperature, inhibitor concentration and contact time were found to be 27.9°C, 20.0% and 5 hours respectively at desirability value of 0.637. At this optimum condition, the weight loss was found to be 0.102%, corrosion rate was 1.583mg/cm2hr and inhibitor efficiency was 62.9%. From the results obtained in this experiment, It is concluded that the bushcane extract can be used as a corrosion inhibitor for the protection of mild steel.
},
year = {2024}
}
TY - JOUR T1 - Utilization of Extract from Bushcane (Costus Afer) as Green Corrosion Inhibitor for Mild Steel AU - Joshua Asukwo Adam AU - Innocent Oseribho Oboh AU - Idara Sylvanus Peter AU - Ubelejit Uche Adum Y1 - 2024/05/10 PY - 2024 N1 - https://doi.org/10.11648/j.wjac.20240902.11 DO - 10.11648/j.wjac.20240902.11 T2 - World Journal of Applied Chemistry JF - World Journal of Applied Chemistry JO - World Journal of Applied Chemistry SP - 15 EP - 24 PB - Science Publishing Group SN - 2637-5982 UR - https://doi.org/10.11648/j.wjac.20240902.11 AB - Corrosion has adverse environmental consequences since it affects the manufacturing sector resulting in enormous economic loss. The corrosion characteristics and mechanism of mild in the solution of hydrochloric acid was studied. Extract of bush cane (Costus afer) was screened for physicochemical and phytochemical properties and utilized as corrosion inhibitor for mild steel, the process was optimized using Response Surface Methodology (RSM). The presence of OH, NH of alcohols, phenols, or substituents connected to aromatic rings, C=O for amides and ketones, C-N of aliphatic amines, and C=C of alkenes and nitriles were shown using Fourier Transform Infrared Spectroscopy (FTIR). The optimum condition was found by minimizing time, temperature, inhibitor concentration and corrosion rate while maximizing weight loss, and inhibitor efficiency. The results obtained revealed that the bush cane extract contain saponin, flavonoid, alkaloid and tannin, which suggests the potency of the extract as a good inhibitor as it contains a considerable amount of phytochemical with basic heteroatom. The statistical significance of the weight loss, corrosion rate and inhibitor efficiency were evaluated using the analysis of variance (ANOVA). it was observed that the regression was statistically significant at the F-value of 94.60, 25.87 and 4.72 respectively. P-value of > 0.0235, > 0.0001 and 0.0265 respectively. The optimum temperature, inhibitor concentration and contact time were found to be 27.9°C, 20.0% and 5 hours respectively at desirability value of 0.637. At this optimum condition, the weight loss was found to be 0.102%, corrosion rate was 1.583mg/cm2hr and inhibitor efficiency was 62.9%. From the results obtained in this experiment, It is concluded that the bushcane extract can be used as a corrosion inhibitor for the protection of mild steel. VL - 9 IS - 2 ER -
Department of Chemical and Petroleum Engineering, Faculty of Engineering, University of Uyo, Uyo, Nigeria
Department of Chemical and Petroleum Engineering, Faculty of Engineering, University of Uyo, Uyo, Nigeria
Department of Chemical and Petroleum Engineering, Faculty of Engineering, University of Uyo, Uyo, Nigeria
Department of Chemical and Petroleum Engineering, Faculty of Engineering, University of Uyo, Uyo, Nigeria
Information