In this paper we investigated the parameters determining the performance of hydrogen production by using the solar water electrolysis system (SWES), without the need of high additional electrical energy. The electrolyte after and before using in solar electrolysis was described to understand the mechanism responsible on the hydrogen production enhancement. Additionally, the employed electrolyte (deposit) was characterized by FT-IR, UV-visible and electrochemical impedance spectroscopy. As results the salt addition can obtained 40% more hydrogen efficiency. Also the pH values that varied between 3 to 6 and 8.5 to 12 could further improve hydrogen yield. The deposit provided a discriminate environment which is proposed to be responsible for the hydrogen production improvement. In addition, hydroxyl ions are mainly transported through the exchange anion, to maintain charge neutrality, and thus the anode and cathode electrode resulting in a low transport resistance. This can be assumed that the proton transport facilitated by water permeation can lower the transport resistance, and consequently increase hydrogen production.
Published in | World Journal of Applied Chemistry (Volume 2, Issue 2) |
DOI | 10.11648/j.wjac.20170202.11 |
Page(s) | 34-47 |
Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
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Copyright © The Author(s), 2017. Published by Science Publishing Group |
Solar Electrolysis, Hydrogen Production, Deposit, Electrochemical Impedance Spectroscopy
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APA Style
A. Benghnia, B. Nabil, R. Ben Slama, B. Chaouachi. (2017). On the Water Electrolysis with Photovoltaic Solar Energy for Hydrogen Production. World Journal of Applied Chemistry, 2(2), 34-47. https://doi.org/10.11648/j.wjac.20170202.11
ACS Style
A. Benghnia; B. Nabil; R. Ben Slama; B. Chaouachi. On the Water Electrolysis with Photovoltaic Solar Energy for Hydrogen Production. World J. Appl. Chem. 2017, 2(2), 34-47. doi: 10.11648/j.wjac.20170202.11
@article{10.11648/j.wjac.20170202.11, author = {A. Benghnia and B. Nabil and R. Ben Slama and B. Chaouachi}, title = {On the Water Electrolysis with Photovoltaic Solar Energy for Hydrogen Production}, journal = {World Journal of Applied Chemistry}, volume = {2}, number = {2}, pages = {34-47}, doi = {10.11648/j.wjac.20170202.11}, url = {https://doi.org/10.11648/j.wjac.20170202.11}, eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.wjac.20170202.11}, abstract = {In this paper we investigated the parameters determining the performance of hydrogen production by using the solar water electrolysis system (SWES), without the need of high additional electrical energy. The electrolyte after and before using in solar electrolysis was described to understand the mechanism responsible on the hydrogen production enhancement. Additionally, the employed electrolyte (deposit) was characterized by FT-IR, UV-visible and electrochemical impedance spectroscopy. As results the salt addition can obtained 40% more hydrogen efficiency. Also the pH values that varied between 3 to 6 and 8.5 to 12 could further improve hydrogen yield. The deposit provided a discriminate environment which is proposed to be responsible for the hydrogen production improvement. In addition, hydroxyl ions are mainly transported through the exchange anion, to maintain charge neutrality, and thus the anode and cathode electrode resulting in a low transport resistance. This can be assumed that the proton transport facilitated by water permeation can lower the transport resistance, and consequently increase hydrogen production.}, year = {2017} }
TY - JOUR T1 - On the Water Electrolysis with Photovoltaic Solar Energy for Hydrogen Production AU - A. Benghnia AU - B. Nabil AU - R. Ben Slama AU - B. Chaouachi Y1 - 2017/03/10 PY - 2017 N1 - https://doi.org/10.11648/j.wjac.20170202.11 DO - 10.11648/j.wjac.20170202.11 T2 - World Journal of Applied Chemistry JF - World Journal of Applied Chemistry JO - World Journal of Applied Chemistry SP - 34 EP - 47 PB - Science Publishing Group SN - 2637-5982 UR - https://doi.org/10.11648/j.wjac.20170202.11 AB - In this paper we investigated the parameters determining the performance of hydrogen production by using the solar water electrolysis system (SWES), without the need of high additional electrical energy. The electrolyte after and before using in solar electrolysis was described to understand the mechanism responsible on the hydrogen production enhancement. Additionally, the employed electrolyte (deposit) was characterized by FT-IR, UV-visible and electrochemical impedance spectroscopy. As results the salt addition can obtained 40% more hydrogen efficiency. Also the pH values that varied between 3 to 6 and 8.5 to 12 could further improve hydrogen yield. The deposit provided a discriminate environment which is proposed to be responsible for the hydrogen production improvement. In addition, hydroxyl ions are mainly transported through the exchange anion, to maintain charge neutrality, and thus the anode and cathode electrode resulting in a low transport resistance. This can be assumed that the proton transport facilitated by water permeation can lower the transport resistance, and consequently increase hydrogen production. VL - 2 IS - 2 ER -