A method and the necessary analytical equipment for the mass quantitative determination of sulfate ions in aqueous extracts from soils and in aqueous media is proposed, consisting in the fact that a known amount of 2-aqueous barium chloride with hydrogen chloride is added to the aliquot of the analyzed sample in the form of an aqueous solution. The resulting insoluble barium sulfate compound reduces the initial concentration of barium chloride. The amount of barium chloride remaining in the solution is determined on the specially designed flame spectrophotometric analyzer. This allows you to calculate the amount of sulfate ions associated with barium, which is automatically performed by the device program. The range of reliably determined concentrations of sulfate ions by the proposed method in water samples ranged from 10 to 100 mg/dm3. The range of reliably determined concentrations of sulfate ions in aqueous extracts from soils ranged from 0.2 to 2.4 C(1/2SO4) mol/dm3 (from 10 to 115 mg/dm3). Higher concentrations of sulfate ions must be diluted multiple times with distilled water. The method makes it possible to determine the concentration of sulfate ions in aqueous soil extracts, freshwater reservoirs and rivers, underground sources, tap water, sediments contaminated with sulfuric acid emissions from industrial enterprises. The method is quite simple, accurate and productive. The method is certified by the State Ural Research Institute of Metrology (MVI-66373620-007-2018) and approved by the Federal Agency for technical regulation and Metrology (Rosstandart), as a standard method under No. 253.0080/RA. RU.311866/2019. Patent No. 2681855 of the Russian Federal Service for Intellectual Property with priority dated September 15, 2017 was obtained for the method for determining sulfur in the form of a sulfate ion in an aqueous extract from soils and the equipment necessary for this. Detailed methods for determining sulfate ions in these objects are published in the open press in the book: "Determination of agrochemical and chemical parameters of soils, plants and aquatic environments using flow-decade analysis technology" edited by Academician of the Russian Academy of Sciences R. F. Baibekov.
| Published in | Science Journal of Analytical Chemistry (Volume 11, Issue 1) |
| DOI | 10.11648/j.sjac.20231101.11 |
| Page(s) | 1-8 |
| Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
| Copyright |
Copyright © The Author(s), 2023. Published by Science Publishing Group |
Sulfate Ions, Chemical Analysis, Water Extracts, Soil, Water Samples, Flame Spectrophotometry, Flow-Decade Analysis Technology
| [1] | Aidinyan R. Kh., Ivanova M. S., Soloviev T. G. Methods for the extraction and determination of various forms of sulfur in soils and plants. M.: Soil Institute. V. V. Dokuchaeva, 1968. S. 22. |
| [2] | Soils. Methods for determining the sulfate ion in water extract. GOST 26426-85. Last approval date 07/13/2017. S. 6. |
| [3] | Drinking water. Methods for determining the content of sulfates. GOST 31940-2012. Date of introduction 01.01.2014. S. 16. |
| [4] | V. A. Gasov, Yu. M. Loginov, L. P. Pokhlebkina, A. N. Streltsov, Yu. V. Frolov. A technique for measuring the mass concentration of mobile mineral forms of phosphorus and potassium in an acetic extract from soils using in ten-cell cassettes analysis technology. MVI-66373620-004-2015. Registration code of the measurement technique No. FR.1.31.2016.22430. M. 2015. |
| [5] | V. A. Gasov, E. V. Gasov, P. A. Danilov, V. V. Kuznetsov, S. M. Krivenkov, Yu. Method for determination of organic matter in the soil using ten-cell cassettes analysis. technology. MVI-66373620-005-2015. Registration code of the measurement technique No. FR.1.31.2016.23816. M. 2015. |
| [6] | Poluektov N. S. Flame photometry analysis methods. - M.: GNTI of chemical literature, 1959. S. 179-183. |
| [7] | Yu. M. Loginov, A. N. Streltsov. Automation of analytical work and instrumentation for monitoring soil fertility and the quality of crop production. Moscow. Agribusinesscenter. 2010. P. 324. |
| [8] | Yu. M. Loginov. Application of continuous flow analysis in the Russian Agrochemical Service. In the book: Flow chemical analysis, Volume 17. Moscow. Nauka Publishing House. 2014. |
| [9] | Yu. M. Loginov, E. V. Gazov, S. M. Krivenkov. Determination of agrochemical and chemical parameters of soils, plants and aquatic environments using flow–decade analysis technology. Moscow 2021. |
| [10] | The method of measuring the mass concentration of mobile mineral forms of phosphorus and potassium in carbon-ammonium extract from soils using a flow-decade analysis technology. MVI-66373620-003-2015.01. Moscow 2015. |
| [11] | Methodology for determining soil acidity using flow-decade analysis technology. MVI-66373620-006-2017. |
| [12] | The method of measuring the mass concentration of mobile mineral forms of phosphorus and potassium in hydrochloric acid extract from soils using flow-decade analysis technology. MVI-66373620-002-2015. Moscow 2015. |
| [13] | A method for determining the molar concentration of sulfate ions in aqueous extract from soils by flame photometric method using flow-decade technology. MVI-66373620-007-2018. Moscow. 2018. |
APA Style
Yuri Loginov, Vladimir Kuznetsov. (2023). A New Method for the Quantitative Determination of Sulfate Ions in Aqueous Extracts from Soils and in Aqueous Media, and Analytical Equipment for Its Implementation. Science Journal of Analytical Chemistry, 11(1), 1-8. https://doi.org/10.11648/j.sjac.20231101.11
ACS Style
Yuri Loginov; Vladimir Kuznetsov. A New Method for the Quantitative Determination of Sulfate Ions in Aqueous Extracts from Soils and in Aqueous Media, and Analytical Equipment for Its Implementation. Sci. J. Anal. Chem. 2023, 11(1), 1-8. doi: 10.11648/j.sjac.20231101.11
AMA Style
Yuri Loginov, Vladimir Kuznetsov. A New Method for the Quantitative Determination of Sulfate Ions in Aqueous Extracts from Soils and in Aqueous Media, and Analytical Equipment for Its Implementation. Sci J Anal Chem. 2023;11(1):1-8. doi: 10.11648/j.sjac.20231101.11
Share This Article
Twitter
Linked In
Facebook
Copy
Download@article{10.11648/j.sjac.20231101.11,
author = {Yuri Loginov and Vladimir Kuznetsov},
title = {A New Method for the Quantitative Determination of Sulfate Ions in Aqueous Extracts from Soils and in Aqueous Media, and Analytical Equipment for Its Implementation},
journal = {Science Journal of Analytical Chemistry},
volume = {11},
number = {1},
pages = {1-8},
doi = {10.11648/j.sjac.20231101.11},
url = {https://doi.org/10.11648/j.sjac.20231101.11},
eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjac.20231101.11},
abstract = {A method and the necessary analytical equipment for the mass quantitative determination of sulfate ions in aqueous extracts from soils and in aqueous media is proposed, consisting in the fact that a known amount of 2-aqueous barium chloride with hydrogen chloride is added to the aliquot of the analyzed sample in the form of an aqueous solution. The resulting insoluble barium sulfate compound reduces the initial concentration of barium chloride. The amount of barium chloride remaining in the solution is determined on the specially designed flame spectrophotometric analyzer. This allows you to calculate the amount of sulfate ions associated with barium, which is automatically performed by the device program. The range of reliably determined concentrations of sulfate ions by the proposed method in water samples ranged from 10 to 100 mg/dm3. The range of reliably determined concentrations of sulfate ions in aqueous extracts from soils ranged from 0.2 to 2.4 C(1/2SO4) mol/dm3 (from 10 to 115 mg/dm3). Higher concentrations of sulfate ions must be diluted multiple times with distilled water. The method makes it possible to determine the concentration of sulfate ions in aqueous soil extracts, freshwater reservoirs and rivers, underground sources, tap water, sediments contaminated with sulfuric acid emissions from industrial enterprises. The method is quite simple, accurate and productive. The method is certified by the State Ural Research Institute of Metrology (MVI-66373620-007-2018) and approved by the Federal Agency for technical regulation and Metrology (Rosstandart), as a standard method under No. 253.0080/RA. RU.311866/2019. Patent No. 2681855 of the Russian Federal Service for Intellectual Property with priority dated September 15, 2017 was obtained for the method for determining sulfur in the form of a sulfate ion in an aqueous extract from soils and the equipment necessary for this. Detailed methods for determining sulfate ions in these objects are published in the open press in the book: "Determination of agrochemical and chemical parameters of soils, plants and aquatic environments using flow-decade analysis technology" edited by Academician of the Russian Academy of Sciences R. F. Baibekov.},
year = {2023}
}
TY - JOUR T1 - A New Method for the Quantitative Determination of Sulfate Ions in Aqueous Extracts from Soils and in Aqueous Media, and Analytical Equipment for Its Implementation AU - Yuri Loginov AU - Vladimir Kuznetsov Y1 - 2023/02/14 PY - 2023 N1 - https://doi.org/10.11648/j.sjac.20231101.11 DO - 10.11648/j.sjac.20231101.11 T2 - Science Journal of Analytical Chemistry JF - Science Journal of Analytical Chemistry JO - Science Journal of Analytical Chemistry SP - 1 EP - 8 PB - Science Publishing Group SN - 2376-8053 UR - https://doi.org/10.11648/j.sjac.20231101.11 AB - A method and the necessary analytical equipment for the mass quantitative determination of sulfate ions in aqueous extracts from soils and in aqueous media is proposed, consisting in the fact that a known amount of 2-aqueous barium chloride with hydrogen chloride is added to the aliquot of the analyzed sample in the form of an aqueous solution. The resulting insoluble barium sulfate compound reduces the initial concentration of barium chloride. The amount of barium chloride remaining in the solution is determined on the specially designed flame spectrophotometric analyzer. This allows you to calculate the amount of sulfate ions associated with barium, which is automatically performed by the device program. The range of reliably determined concentrations of sulfate ions by the proposed method in water samples ranged from 10 to 100 mg/dm3. The range of reliably determined concentrations of sulfate ions in aqueous extracts from soils ranged from 0.2 to 2.4 C(1/2SO4) mol/dm3 (from 10 to 115 mg/dm3). Higher concentrations of sulfate ions must be diluted multiple times with distilled water. The method makes it possible to determine the concentration of sulfate ions in aqueous soil extracts, freshwater reservoirs and rivers, underground sources, tap water, sediments contaminated with sulfuric acid emissions from industrial enterprises. The method is quite simple, accurate and productive. The method is certified by the State Ural Research Institute of Metrology (MVI-66373620-007-2018) and approved by the Federal Agency for technical regulation and Metrology (Rosstandart), as a standard method under No. 253.0080/RA. RU.311866/2019. Patent No. 2681855 of the Russian Federal Service for Intellectual Property with priority dated September 15, 2017 was obtained for the method for determining sulfur in the form of a sulfate ion in an aqueous extract from soils and the equipment necessary for this. Detailed methods for determining sulfate ions in these objects are published in the open press in the book: "Determination of agrochemical and chemical parameters of soils, plants and aquatic environments using flow-decade analysis technology" edited by Academician of the Russian Academy of Sciences R. F. Baibekov. VL - 11 IS - 1 ER -
Information
Email: