Analysis of Organic Components by DLLME Based on the Solidification of a Floating Organic Droplet Followed with GC/MS in Wood Vinegar

Qiang Sun; Yuliang Gao; Liyan Wang

doi:doi:10.11648/j.sjac.20200801.12

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Analysis of Organic Components by DLLME Based on the Solidification of a Floating Organic Droplet Followed with GC/MS in Wood Vinegar

Qiang Sun, Yuliang Gao, Liyan Wang

Published in Science Journal of Analytical Chemistry (Volume 8, Issue 1)

Received: 21 December 2019 Accepted: 8 January 2020 Published: 31 January 2020

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Abstract

A simple, efficient and environmentally friendly method has been established for the analysis of organic components in wood vinegar (WV) by dispersive liquid-liquid micro-extraction based on solidification of floating organic droplet (DLLME-SFO) coupled with GC/MS. Several variables that affect the extraction efficiency, including the type and volume of the extractant and dispersant, extraction time and the mass fraction of sodium chloride were optimized. Under the optimum conditions, the sample extracted were analyzed by GC/MS. The result shows that, apart from the main component of acetic acid, many kinds of ketone compound, phenol compound, ester compound, aldehyde and alcohol compound exist in the WV. The proposed method has been successfully employed to determine the organic components in the WV.

Published in	Science Journal of Analytical Chemistry (Volume 8, Issue 1)
DOI	10.11648/j.sjac.20200801.12
Page(s)	5-11
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2020. Published by Science Publishing Group

Keywords

Wood Vinegar, DLLME-SFO, GC/MS, Organic Components

References

[1]	Q. Q. Ren, C. S. Zhao, L. B. Duan and X. P. Chen (2011) NO formation during agricultural straw combustion. Bioresource Technol 102: 7211-7217.
[2]	Q. Wei, X. H. Ma and Dong J. N (2010) Preparation, chemical constituents and antimicrobial activity of pyroligneous acids from walnut tree branches. Journal of Analytical and Applied Pyrolysis. J Anal Appl Pyrol 87 (1): 24-28.
[3]	A. T.. Arif, C. Maschowski and P. Garra (2017) Cytotoxic and genotoxic responses of human lung cells to combustion smoke particles of Miscanthus straw, softwood and beech wood chips. Atmos Environ 163: 138-154.
[4]	Q. M. Wu, S. Y. Zhang and B. X. Hou (2015) Study on the preparation of wood vinegar from biomass residues by carbonization process. Bioresource Technol 179: 98-103.
[5]	Y. Baimark, N. Niamsa (2009) Study on wood vinegars for use as coagulating and antifungal agents on the production of natural rubber sheets. Biomass and Bioenerg 33: 994-998.
[6]	Y. J. Huo, Z. X. Liu and H. Xuan (2016) Effects of bamboo vinegar powder on growth performance and mRNA expression levels of interleukin-10, interleukin-22, and interleukin-25 in immune organs of weaned piglets. Anim Nutr 2: 111-118.
[7]	T. Mungkunkamchao, T. Kesmala and S. Pimratch (2013) Wood vinegar and fermented bioextracts: Natural products to enhance growth and yield of tomato (Solanum lycopersicum L.). Sci Hortic-Amsterdam 154: 66-72.
[8]	H. Yoshimura, H. Washio and S. Yoshida (1995) Promoting effect of wood vinegar compounds on fruit-body formation of Pleurotus ostreatus. Mycoscience 36: 173-177.
[9]	H. Zheng, C. Z. Sun and X. D. Hou (2018) Pyrolysis of Arundo donax L. to produce pyrolytic vinegar and its effect on the growth of dinoflagellate Karenia brevis. Bioresource Technol 247: 273-281.
[10]	H. F. Lu, M. S. Lashari and X. Y. Liu (2015) Changes in soil microbial community structure and enzyme activity with amendment of biochar-manure compost and pyroligneous solution in a saline soil from Central China. Eur J Soil Biol 70: 67-76.
[11]	M. S. Lashari, Y. M. Liu and L. Q. Li (2013) Effects of amendment of biochar-manure compost in conjunction with pyroligneous solution on soil quality and wheat yield of a salt-stressed cropland from Central China Great Plain. Field Crop Res 144: 113-118.
[12]	D. Angin (2013) Effect of pyrolysis temperature and heating rate on biochar obtained from pyrolysis of safflower seed press cake. Bioresource Technol 128: 593-597.
[13]	M. Hagner, O. P. Penttinen and K. Tiilikkala (2013) The effects of biochar, wood vinegar and plants on glyphosate leaching and degradation. Eur J Soil Biol 58: 1-7.
[14]	Y. S. Choi, B. J. Ahn and G. H. Kim (2012) Extraction of chromium, copper, and arsenic from CCA-treated wood by using wood vinegar. Bioresource Technol 120: 328-331.
[15]	K. S. Shiny, O. K. Remadevi (2014) Evaluation of termiticidal activity of coconut shell oil and its comparison to commercial wood preservatives. Eur J Wood Wood Prod 72: 139-141.
[16]	S. Y. Wu, Y. Q. Wu and J. S. Gao (2014) The effect of wood vinegar on hydrothermal liquefaction of cotton stalk under CO atmosphere. Energ Source Part A 36: 411-417.
[17]	Y. X. Li and H. W. Lin (2012) Comparative study on capillary gas chromatographic analysis of organic components of wood vineger and water-extract of wood-tar prepared form hard wood barks. J anal sci 28: 58-62.
[18]	H. Ménard, A. Gaboury and D. Bélanger (1984) High-performance liquid chromatographic analysis of carboxylic acids in pyroligneous liquors. J Anal Appl Pyrol 6: 45-57.
[19]	M. Plessi, D. Bertelli and F. Miglietta (2006) Extraction and identification by GC-MS of phenolic acids in traditional balsamic vinegar from Modena. J Food Compos Anal 19: 49-54.
[20]	M. I. Leong and S. D. Huang (2008) Dispersive liquid-liquid microextraction method based on solidiﬁcation of floating organic drop combined with gas chromatography with electron-capture or mass spectrometry detection. J. Chromatogr. A 1211: 8-12.
[21]	M. I. Leong and S. D. Huang (2009) Dispersive liquid-liquid microextraction method based on solidiﬁcation of ﬂoating organic drop for extraction of organochlorine fungicides in water samples. J. Chromatogr. A 1216: 7645-7650.
[22]	H. Xu, Z. Q. Ding and L. L. Lv (2009) A novel dispersive liquid-liquid microextraction based on solidiﬁcation of ﬂoating organic droplet method for determination of polycyclic aromatic hydrocarbons in aqueous samples. Anal. Chim. Acta 636: 28-33.
[23]	Y. L. Gao, X. J. Guo and P. Sun (2017) Ultrasound-assisted Dispersive Liquid-liquid Microextraction Based on the Solidification of a Floating Organic Droplet Followed by Gas Chromatography for the Determination of Five Pyrethroid Pesticides Residue in Tea Sample. J Tea Sci 37: 527-533.
[24]	P. Sun, Y. J. Gao and J. M. Wang (2016) Dispersive liquid-liquid microextraction based on the solidification of a floating organic droplet followed by gas chromatography for the determination of five pyrethroid pesticides residue in liquid milk sample. Chinese J Pestic Sci 18: 497-502.
[25]	P. Sun, Y. L. Gao and J. M. Wang (2017) Determination of eugenol residue in aquatic using dispersive liquid-liquid microextraction based on the solidification of a floating organic droplet followed by UHPLC-MS/MS. J. Chin. Mass Spectrom. Soc. 38: 342-3428.
[26]	F. R Mansour and N. D. Danielson (2017) Danielson. Solidification of floating organic droplet in dispersive liquid-liquid microextraction as a green analytical tool. Talanta 170: 22-35.
[27]	R. Canales, M. Guiñez and S. Cerutti (2017) Determining heterocyclic aromatic amines in aqueous samples: A novel dispersive liquid-liquid micro-extraction method based on solidification of floating organic drop and ultrasound assisted back extraction followed by UPLC-MS/MS. Talanta 174: 548-555.
[28]	X. C. Wang, B. Shu and B. Qiu (2017) QuEChERS followed by dispersive liquid–liquid microextraction based on solidification of floating organic droplet method for organochlorine pesticides analysis in fish. Talanta 162: 90-97.

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APA Style

Qiang Sun, Yuliang Gao, Liyan Wang. (2020). Analysis of Organic Components by DLLME Based on the Solidification of a Floating Organic Droplet Followed with GC/MS in Wood Vinegar. Science Journal of Analytical Chemistry, 8(1), 5-11. https://doi.org/10.11648/j.sjac.20200801.12

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ACS Style

Qiang Sun; Yuliang Gao; Liyan Wang. Analysis of Organic Components by DLLME Based on the Solidification of a Floating Organic Droplet Followed with GC/MS in Wood Vinegar. Sci. J. Anal. Chem. 2020, 8(1), 5-11. doi: 10.11648/j.sjac.20200801.12

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AMA Style

Qiang Sun, Yuliang Gao, Liyan Wang. Analysis of Organic Components by DLLME Based on the Solidification of a Floating Organic Droplet Followed with GC/MS in Wood Vinegar. Sci J Anal Chem. 2020;8(1):5-11. doi: 10.11648/j.sjac.20200801.12

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@article{10.11648/j.sjac.20200801.12,
  author = {Qiang Sun and Yuliang Gao and Liyan Wang},
  title = {Analysis of Organic Components by DLLME Based on the Solidification of a Floating Organic Droplet Followed with GC/MS in Wood Vinegar},
  journal = {Science Journal of Analytical Chemistry},
  volume = {8},
  number = {1},
  pages = {5-11},
  doi = {10.11648/j.sjac.20200801.12},
  url = {https://doi.org/10.11648/j.sjac.20200801.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjac.20200801.12},
  abstract = {A simple, efficient and environmentally friendly method has been established for the analysis of organic components in wood vinegar (WV) by dispersive liquid-liquid micro-extraction based on solidification of floating organic droplet (DLLME-SFO) coupled with GC/MS. Several variables that affect the extraction efficiency, including the type and volume of the extractant and dispersant, extraction time and the mass fraction of sodium chloride were optimized. Under the optimum conditions, the sample extracted were analyzed by GC/MS. The result shows that, apart from the main component of acetic acid, many kinds of ketone compound, phenol compound, ester compound, aldehyde and alcohol compound exist in the WV. The proposed method has been successfully employed to determine the organic components in the WV.},
 year = {2020}
}

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TY  - JOUR
T1  - Analysis of Organic Components by DLLME Based on the Solidification of a Floating Organic Droplet Followed with GC/MS in Wood Vinegar
AU  - Qiang Sun
AU  - Yuliang Gao
AU  - Liyan Wang
Y1  - 2020/01/31
PY  - 2020
N1  - https://doi.org/10.11648/j.sjac.20200801.12
DO  - 10.11648/j.sjac.20200801.12
T2  - Science Journal of Analytical Chemistry
JF  - Science Journal of Analytical Chemistry
JO  - Science Journal of Analytical Chemistry
SP  - 5
EP  - 11
PB  - Science Publishing Group
SN  - 2376-8053
UR  - https://doi.org/10.11648/j.sjac.20200801.12
AB  - A simple, efficient and environmentally friendly method has been established for the analysis of organic components in wood vinegar (WV) by dispersive liquid-liquid micro-extraction based on solidification of floating organic droplet (DLLME-SFO) coupled with GC/MS. Several variables that affect the extraction efficiency, including the type and volume of the extractant and dispersant, extraction time and the mass fraction of sodium chloride were optimized. Under the optimum conditions, the sample extracted were analyzed by GC/MS. The result shows that, apart from the main component of acetic acid, many kinds of ketone compound, phenol compound, ester compound, aldehyde and alcohol compound exist in the WV. The proposed method has been successfully employed to determine the organic components in the WV.
VL  - 8
IS  - 1
ER  -

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Author Information

Qiang Sun

Agonomy College, Heilongjiang Bayi Agricultural University, Daqing, China
Yuliang Gao

Agonomy College, Heilongjiang Bayi Agricultural University, Daqing, China
Liyan Wang

Agonomy College, Heilongjiang Bayi Agricultural University, Daqing, China

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Plain Text BibTeX RIS

APA Style

Qiang Sun, Yuliang Gao, Liyan Wang. (2020). Analysis of Organic Components by DLLME Based on the Solidification of a Floating Organic Droplet Followed with GC/MS in Wood Vinegar. Science Journal of Analytical Chemistry, 8(1), 5-11. https://doi.org/10.11648/j.sjac.20200801.12

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ACS Style

Qiang Sun; Yuliang Gao; Liyan Wang. Analysis of Organic Components by DLLME Based on the Solidification of a Floating Organic Droplet Followed with GC/MS in Wood Vinegar. Sci. J. Anal. Chem. 2020, 8(1), 5-11. doi: 10.11648/j.sjac.20200801.12

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AMA Style

Qiang Sun, Yuliang Gao, Liyan Wang. Analysis of Organic Components by DLLME Based on the Solidification of a Floating Organic Droplet Followed with GC/MS in Wood Vinegar. Sci J Anal Chem. 2020;8(1):5-11. doi: 10.11648/j.sjac.20200801.12

Copy | Download

@article{10.11648/j.sjac.20200801.12,
  author = {Qiang Sun and Yuliang Gao and Liyan Wang},
  title = {Analysis of Organic Components by DLLME Based on the Solidification of a Floating Organic Droplet Followed with GC/MS in Wood Vinegar},
  journal = {Science Journal of Analytical Chemistry},
  volume = {8},
  number = {1},
  pages = {5-11},
  doi = {10.11648/j.sjac.20200801.12},
  url = {https://doi.org/10.11648/j.sjac.20200801.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjac.20200801.12},
  abstract = {A simple, efficient and environmentally friendly method has been established for the analysis of organic components in wood vinegar (WV) by dispersive liquid-liquid micro-extraction based on solidification of floating organic droplet (DLLME-SFO) coupled with GC/MS. Several variables that affect the extraction efficiency, including the type and volume of the extractant and dispersant, extraction time and the mass fraction of sodium chloride were optimized. Under the optimum conditions, the sample extracted were analyzed by GC/MS. The result shows that, apart from the main component of acetic acid, many kinds of ketone compound, phenol compound, ester compound, aldehyde and alcohol compound exist in the WV. The proposed method has been successfully employed to determine the organic components in the WV.},
 year = {2020}
}

Copy | Download

TY  - JOUR
T1  - Analysis of Organic Components by DLLME Based on the Solidification of a Floating Organic Droplet Followed with GC/MS in Wood Vinegar
AU  - Qiang Sun
AU  - Yuliang Gao
AU  - Liyan Wang
Y1  - 2020/01/31
PY  - 2020
N1  - https://doi.org/10.11648/j.sjac.20200801.12
DO  - 10.11648/j.sjac.20200801.12
T2  - Science Journal of Analytical Chemistry
JF  - Science Journal of Analytical Chemistry
JO  - Science Journal of Analytical Chemistry
SP  - 5
EP  - 11
PB  - Science Publishing Group
SN  - 2376-8053
UR  - https://doi.org/10.11648/j.sjac.20200801.12
AB  - A simple, efficient and environmentally friendly method has been established for the analysis of organic components in wood vinegar (WV) by dispersive liquid-liquid micro-extraction based on solidification of floating organic droplet (DLLME-SFO) coupled with GC/MS. Several variables that affect the extraction efficiency, including the type and volume of the extractant and dispersant, extraction time and the mass fraction of sodium chloride were optimized. Under the optimum conditions, the sample extracted were analyzed by GC/MS. The result shows that, apart from the main component of acetic acid, many kinds of ketone compound, phenol compound, ester compound, aldehyde and alcohol compound exist in the WV. The proposed method has been successfully employed to determine the organic components in the WV.
VL  - 8
IS  - 1
ER  -

Copy | Download