Comparative Study of Microwave Assisted and Conventional Synthesis of Tp*-Complexes

Hamed Aboajila Alqamoudy; Hussain Ibrahim Alarabi

doi:doi:10.11648/j.jmpt.20180401.14

| Peer-Reviewed

Comparative Study of Microwave Assisted and Conventional Synthesis of Tp*-Complexes

Hamed Aboajila Alqamoudy, Hussain Ibrahim Alarabi

Published in Journal of Photonic Materials and Technology (Volume 4, Issue 1)

Received: 20 January 2018 Accepted: 8 February 2018 Published: 28 February 2018

Views: Downloads:

Download PDF

Share This Article

Twitter
Linked In
Facebook

Abstract

Cobalt, copper and nickel complexes with tris(3,5-dimethyl-1H-pyrazol-1-yl)hydroborate (Tp*) were synthesized by the reaction of potassium tris(3,5-dimethyl-1H-pyrazol-1-yl)hydroborate (KTp*) with the corresponding metal(II) chloride by using conventional reflux methods and microwave methods. The two methods were compared and the microwave method was found to be less time consuming and gave higher yields.

Published in	Journal of Photonic Materials and Technology (Volume 4, Issue 1)
DOI	10.11648/j.jmpt.20180401.14
Page(s)	19-25
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2018. Published by Science Publishing Group

Keywords

Pz* [3,5-dimethyl-1H-pyrazol-1-yl], KTp* [potassium tris(3,5-dimethyl-1H-pyrazol-1-yl)hydroborate], Tp*-complexes, [tris(3,5-dimethyl-1H-pyrazol-1-yl)hydroborate complexes]

References

[1]	H. R. Bigmore, S. C. Lawrence, P. Mountford and C. S. Tredget, Dalton Trans. (2005) 635-651.
[2]	S. Trofimenko, A. Cingolani, C. Pettinari, Science and Technology 86(2004) 94-100.
[3]	S. Trofimenko, J. Am. Chem. Soc., 89 (1967) 3165.
[4]	S. Trofimenko, J. Am. Chem. Soc., 89 (1967) 4948.
[5]	K. Michiue, R. F. Jordan, Organometallics 23 (2004) 460-470.
[6]	R. G. Lawrencea, Christopher J. Jonesa, R. A. Kresinski, Inorg. Chim. Acta 285 (1999) 283-289.
[7]	M. Herberhold, G. Frohmader, T. Hofmann, W. Milius, J. Darkwa, Inorg. Chim. Acta 267(1998)19-25.
[8]	Y.-H. Xing, Bao-Li Zhang, Y.-H. Zhang, H.-Q. Yuan, Z. Sun, Mao Fa Ge, Polyhedron 26 (2007) 3037–3044.
[9]	C.-H. Li, J.-D. Chen, L.-S. Liou, Ju-Chun Wang, Inorg. Chim. Acta 269 (1998) 302-309.
[10]	M. Cano, J. A. Campo, J. V. Heras, E. Pinilla, Polyhedron15(1996)1705-1715.
[11]	C. Manzur, D. Carrillo, F. Robert, P. Gouzerh, P. Hamon, J.-R. Hamon, Inorg. Chim. Acta 268 (1998) 199-204.
[12]	A. A. Eagle, G. N. George, E. R. T. Tiekink, C. G. Young, J. Inorg. Biochem. 76 (1999) 39–45.
[13]	J. C. Dewar, A. S. Thakur, W. W. Brennessel, M. Cafiero, L. W. Peterson, W. T. Eckenhoff. Inorganica Chimica Acta. 473 (2018) 15-19.
[14]	L. Serpasmm, R. R. Baum, A. McGheem, I. lNieto, K. L. Jernigan, M. Zeller, G. M. Ferrence, D. L. Tierney, E. T. Papish. Polyhedron. 114 (2016) 62-71.
[15]	J. Masternak, M. Z. Machnik, K. Kazimierczuk, B. Barszcz. Polyhedron. (2018) 93-104.
[16]	P. A. Petrov, A. I. Smolentsev, A. S. Bogomyakov, S. N. Konchenko. Polyhedron. 129 (2017) 60-64.
[17]	D. Adam, Nature 421 (2003) 571–572.
[18]	R. Gedye, F. Smith, K. Westaway, H. Ali, L. Baldisera, L. Laberge, J. Rousell, Tetrahedron Lett. 27 (1986) 279–282.
[19]	R. J. Giguere, T. L. Bray, S. M. Duncan, G. Majetich, Tetrahedron Lett. 27 (1986) 4945–4958.
[20]	C. O. Kappe Angew. Chem. Int. Ed. 2004, 43, 6250 –62846- H. V. R. Dias, X. Wang, Polyhedron 23 (2004) 2533-2539.
[21]	Microwave Assisted Synthesis of Potassium Hydrotris (3,5-dimethyl-1H-pyrazol-1-yl) borate (KTp*). Hussain Ibrahim Alarabi and Hamed Aboagila Alqamoudy. University Bulletin – ISSUE No.16- Vol. 1 February (2014) 83-102.

Cite This Article

Plain Text BibTeX RIS

APA Style

Hamed Aboajila Alqamoudy, Hussain Ibrahim Alarabi. (2018). Comparative Study of Microwave Assisted and Conventional Synthesis of Tp*-Complexes. Journal of Photonic Materials and Technology, 4(1), 19-25. https://doi.org/10.11648/j.jmpt.20180401.14

Copy | Download

ACS Style

Hamed Aboajila Alqamoudy; Hussain Ibrahim Alarabi. Comparative Study of Microwave Assisted and Conventional Synthesis of Tp*-Complexes. J. Photonic Mater. Technol. 2018, 4(1), 19-25. doi: 10.11648/j.jmpt.20180401.14

Copy | Download

AMA Style

Hamed Aboajila Alqamoudy, Hussain Ibrahim Alarabi. Comparative Study of Microwave Assisted and Conventional Synthesis of Tp*-Complexes. J Photonic Mater Technol. 2018;4(1):19-25. doi: 10.11648/j.jmpt.20180401.14

Copy | Download

@article{10.11648/j.jmpt.20180401.14,
  author = {Hamed Aboajila Alqamoudy and Hussain Ibrahim Alarabi},
  title = {Comparative Study of Microwave Assisted and Conventional Synthesis of Tp*-Complexes},
  journal = {Journal of Photonic Materials and Technology},
  volume = {4},
  number = {1},
  pages = {19-25},
  doi = {10.11648/j.jmpt.20180401.14},
  url = {https://doi.org/10.11648/j.jmpt.20180401.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.jmpt.20180401.14},
  abstract = {Cobalt, copper and nickel complexes with tris(3,5-dimethyl-1H-pyrazol-1-yl)hydroborate (Tp*) were synthesized by the reaction of potassium tris(3,5-dimethyl-1H-pyrazol-1-yl)hydroborate (KTp*) with the corresponding metal(II) chloride by using conventional reflux methods and microwave methods. The two methods were compared and the microwave method was found to be less time consuming and gave higher yields.},
 year = {2018}
}

Copy | Download

TY  - JOUR
T1  - Comparative Study of Microwave Assisted and Conventional Synthesis of Tp*-Complexes
AU  - Hamed Aboajila Alqamoudy
AU  - Hussain Ibrahim Alarabi
Y1  - 2018/02/28
PY  - 2018
N1  - https://doi.org/10.11648/j.jmpt.20180401.14
DO  - 10.11648/j.jmpt.20180401.14
T2  - Journal of Photonic Materials and Technology
JF  - Journal of Photonic Materials and Technology
JO  - Journal of Photonic Materials and Technology
SP  - 19
EP  - 25
PB  - Science Publishing Group
SN  - 2469-8431
UR  - https://doi.org/10.11648/j.jmpt.20180401.14
AB  - Cobalt, copper and nickel complexes with tris(3,5-dimethyl-1H-pyrazol-1-yl)hydroborate (Tp*) were synthesized by the reaction of potassium tris(3,5-dimethyl-1H-pyrazol-1-yl)hydroborate (KTp*) with the corresponding metal(II) chloride by using conventional reflux methods and microwave methods. The two methods were compared and the microwave method was found to be less time consuming and gave higher yields.
VL  - 4
IS  - 1
ER  -

Copy | Download

Author Information

Hamed Aboajila Alqamoudy

Chemistry Department, Faculty of Science, Zawia University, Az Zawiyah, Libya
Hussain Ibrahim Alarabi

Chemistry Department, Faculty of Science, Zawia University, Az Zawiyah, Libya

Download PDF

Sections

Plain Text BibTeX RIS

APA Style

Hamed Aboajila Alqamoudy, Hussain Ibrahim Alarabi. (2018). Comparative Study of Microwave Assisted and Conventional Synthesis of Tp*-Complexes. Journal of Photonic Materials and Technology, 4(1), 19-25. https://doi.org/10.11648/j.jmpt.20180401.14

Copy | Download

ACS Style

Hamed Aboajila Alqamoudy; Hussain Ibrahim Alarabi. Comparative Study of Microwave Assisted and Conventional Synthesis of Tp*-Complexes. J. Photonic Mater. Technol. 2018, 4(1), 19-25. doi: 10.11648/j.jmpt.20180401.14

Copy | Download

AMA Style

Hamed Aboajila Alqamoudy, Hussain Ibrahim Alarabi. Comparative Study of Microwave Assisted and Conventional Synthesis of Tp*-Complexes. J Photonic Mater Technol. 2018;4(1):19-25. doi: 10.11648/j.jmpt.20180401.14

Copy | Download

@article{10.11648/j.jmpt.20180401.14,
  author = {Hamed Aboajila Alqamoudy and Hussain Ibrahim Alarabi},
  title = {Comparative Study of Microwave Assisted and Conventional Synthesis of Tp*-Complexes},
  journal = {Journal of Photonic Materials and Technology},
  volume = {4},
  number = {1},
  pages = {19-25},
  doi = {10.11648/j.jmpt.20180401.14},
  url = {https://doi.org/10.11648/j.jmpt.20180401.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.jmpt.20180401.14},
  abstract = {Cobalt, copper and nickel complexes with tris(3,5-dimethyl-1H-pyrazol-1-yl)hydroborate (Tp*) were synthesized by the reaction of potassium tris(3,5-dimethyl-1H-pyrazol-1-yl)hydroborate (KTp*) with the corresponding metal(II) chloride by using conventional reflux methods and microwave methods. The two methods were compared and the microwave method was found to be less time consuming and gave higher yields.},
 year = {2018}
}

Copy | Download

TY  - JOUR
T1  - Comparative Study of Microwave Assisted and Conventional Synthesis of Tp*-Complexes
AU  - Hamed Aboajila Alqamoudy
AU  - Hussain Ibrahim Alarabi
Y1  - 2018/02/28
PY  - 2018
N1  - https://doi.org/10.11648/j.jmpt.20180401.14
DO  - 10.11648/j.jmpt.20180401.14
T2  - Journal of Photonic Materials and Technology
JF  - Journal of Photonic Materials and Technology
JO  - Journal of Photonic Materials and Technology
SP  - 19
EP  - 25
PB  - Science Publishing Group
SN  - 2469-8431
UR  - https://doi.org/10.11648/j.jmpt.20180401.14
AB  - Cobalt, copper and nickel complexes with tris(3,5-dimethyl-1H-pyrazol-1-yl)hydroborate (Tp*) were synthesized by the reaction of potassium tris(3,5-dimethyl-1H-pyrazol-1-yl)hydroborate (KTp*) with the corresponding metal(II) chloride by using conventional reflux methods and microwave methods. The two methods were compared and the microwave method was found to be less time consuming and gave higher yields.
VL  - 4
IS  - 1
ER  -

Copy | Download