The Application of Fiber Ion Exchange Sorbents for Wastewater Treatment and Purification of Gas Mixtures

Ilnur Garipov; Renat Khaydarov; Olga Gapurova; Rashid Khaydarov; Svetlana Evgrafova

doi:doi:10.11648/j.jeece.20200501.12

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The Application of Fiber Ion Exchange Sorbents for Wastewater Treatment and Purification of Gas Mixtures

Ilnur Garipov, Renat Khaydarov, Olga Gapurova, Rashid Khaydarov, Svetlana Evgrafova

Published in Journal of Energy, Environmental & Chemical Engineering (Volume 5, Issue 1)

Received: 7 May 2020 Accepted: 26 May 2020 Published: 15 June 2020

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Abstract

We developed a method of modifying the polyester material to produce ion exchange fiber sorbents. The production of cation exchange sorbents involved the treatment of polyester fibers with a 20–25% solution of NH₂NH₂H₂O at 70–90°C and a 5% solution of NaOH at 40°C. Anion exchange sorbents were prepared by the treatment of cation exchange sorbents with a 1–5% solution of polyethylenimine at ambient temperature. These new types of sorbents can be used to remove radionuclides, heavy metal ions and organic contaminants from wastewater and drinking water. We studied main properties of these sorbents and their ability to remove ⁵⁷Co, ⁶⁰Co, ⁶⁵Zn, ⁸⁹Sr, ⁹⁰Sr, ¹³⁴Cs, ¹³⁷Cs and other radionuclides, heavy metal ions (Zn, Ni, Cu, Sb, Pb, Cd, Cr, U, etc.), organic molecules M (pesticides, phenols, dioxins, benzene, toluene, etc.), radio-labeled organic molecules M-³²P, M-¹³¹I, M-⁹⁹Mo+^99mTc, M-¹⁴C, etc. The static exchange capacity is 1–2 meq/g for cationic sorbents and 0.5–1 meq/g for anionic sorbents. The developed sorbents have been effective in removing low concentrations of contaminants from water (lower than 100–200 mg/L) as well as in purifying the gas mixtures from toxic and aggressive gases: SO₂, SO₃, NH₃, H₂S, etc.

Published in	Journal of Energy, Environmental & Chemical Engineering (Volume 5, Issue 1)
DOI	10.11648/j.jeece.20200501.12
Page(s)	10-13
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2020. Published by Science Publishing Group

Keywords

Polyester, Cation Exchange, Anion Exchange, Fiber Sorbent, Wastewater Treatment

References

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[2]	Kragten J. (1978) Atlas of Metal-Ligand Equilibria in Aqueous Solution, Ellis Horwood Ltd., Chichester.
[3]	Nemilova, T. V., Emets, L. V., Nemilov, V. N. et al. Fibre Chem (1996) 28: 381. doi: 10.1007/BF01061000.
[4]	Zverev M. P. (1981) Fibroid chemosorbents, Chemistry, Moscow.
[5]	Khaydarov R. A, Khaydarov R. R., Cho S., (2009) Natural disaster: prevention of drinking water scarcity, Threats to Global Water Security (Jones, J. et. al.: Eds.), Springer, Netherlands, pp. 381-384.
[6]	Khaydarov R. A, Gapurova O., Khaydarov R. R, Cho S. Y. (2005) Fibroid Sorbents For Water Purification, in Modern Tools and Methods of Water Treatment for Improving Living Standards, NATO Science Series, 1V. Earth and Environmental Sciences – Vol. 48, pp. 101-108.
[7]	Khaydarov R. A, Khaydarov R. R, (2006) Purification of drinking water from ^{134, 137}Cs, ^{89, 90}Sr, ⁶⁰Co and ¹²⁹I, in Medical Treatment of Intoxication and Decontamination of Chemical Agent in the Area of Terrorist Attack, NATO Science Series –A: Chemistry and Biology – Vol. 1, pp. 171-181.
[8]	Khaydarov R. A, Khaydarov R. R (2008) Environmental Change in the Aral Sea Region: New Approaches to Water Treatment in Environmental Change and Human Security: Recognizing and Acting on Hazard Impacts, NATO Science for Peace and Security Series C: Environmental Security, Springer Netherlands, pp. 433-447.
[9]	Ashirov A. (1983) Ion-exchange purification of waste water, solutions and gases, Chemistry, Leningrad, USSR.
[10]	Zverev, M. P. Fibre Chem (1994) 25: 498. doi: 10.1007/BF00550794.
[11]	Astapov A. V., Peregudov Y. S., Kopylova V. D. et al. (2010) The hydration characteristics of chemisorption fiber VION KN-1 in the nickel and zinc forms. Russian Journal of Physical Chemistry A, vol. 84, pp 491–494.
[12]	Khaydarov R. R., Gapurova O., Khaydarov R. A etc «The Application of Fibrous Ion-Exchange Sorbents for Water Treatment and the Purification of Gaseous Mixtures», Advances in Materials Science Research. Nova Science Publishers, Volume 30, 2017, pp. 229-239.
[13]	M. Young (1989) The Technical Writer's Handbook. Mill Valley, CA: University Science.
[14]	Khaydarov R. A., Khaydarov R. R., Gapurova O. U., Nasirova N. (2013) VOC Degradation in the Atmosphere by Nanophotocatalysts. In: Barnes, I (ed) Disposal of Dangerous Chemicals in Urban Areas and Mega Cities, NATO Science for Peace and Security Series C: Environmental Security.- Springer (Netherlands), pp. 139-150.
[15]	Khaydarov R. R., Khaydarov R. A., Mironov V., Gapurova O. Malikov Sh. (2007) Using fibrous sorbents for water treatment from radionuclides. Uzbek Journal of Physics. Tashkent, vol. 9 (2), pp. 144-150.

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APA Style

Ilnur Garipov, Renat Khaydarov, Olga Gapurova, Rashid Khaydarov, Svetlana Evgrafova. (2020). The Application of Fiber Ion Exchange Sorbents for Wastewater Treatment and Purification of Gas Mixtures. Journal of Energy, Environmental & Chemical Engineering, 5(1), 10-13. https://doi.org/10.11648/j.jeece.20200501.12

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ACS Style

Ilnur Garipov; Renat Khaydarov; Olga Gapurova; Rashid Khaydarov; Svetlana Evgrafova. The Application of Fiber Ion Exchange Sorbents for Wastewater Treatment and Purification of Gas Mixtures. J. Energy Environ. Chem. Eng. 2020, 5(1), 10-13. doi: 10.11648/j.jeece.20200501.12

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AMA Style

Ilnur Garipov, Renat Khaydarov, Olga Gapurova, Rashid Khaydarov, Svetlana Evgrafova. The Application of Fiber Ion Exchange Sorbents for Wastewater Treatment and Purification of Gas Mixtures. J Energy Environ Chem Eng. 2020;5(1):10-13. doi: 10.11648/j.jeece.20200501.12

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@article{10.11648/j.jeece.20200501.12,
  author = {Ilnur Garipov and Renat Khaydarov and Olga Gapurova and Rashid Khaydarov and Svetlana Evgrafova},
  title = {The Application of Fiber Ion Exchange Sorbents for Wastewater Treatment and Purification of Gas Mixtures},
  journal = {Journal of Energy, Environmental & Chemical Engineering},
  volume = {5},
  number = {1},
  pages = {10-13},
  doi = {10.11648/j.jeece.20200501.12},
  url = {https://doi.org/10.11648/j.jeece.20200501.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.jeece.20200501.12},
  abstract = {We developed a method of modifying the polyester material to produce ion exchange fiber sorbents. The production of cation exchange sorbents involved the treatment of polyester fibers with a 20–25% solution of NH2NH2H2O at 70–90°C and a 5% solution of NaOH at 40°C. Anion exchange sorbents were prepared by the treatment of cation exchange sorbents with a 1–5% solution of polyethylenimine at ambient temperature. These new types of sorbents can be used to remove radionuclides, heavy metal ions and organic contaminants from wastewater and drinking water. We studied main properties of these sorbents and their ability to remove 57Co, 60Co, 65Zn, 89Sr, 90Sr, 134Cs, 137Cs and other radionuclides, heavy metal ions (Zn, Ni, Cu, Sb, Pb, Cd, Cr, U, etc.), organic molecules M (pesticides, phenols, dioxins, benzene, toluene, etc.), radio-labeled organic molecules M-32P, M-131I, M-99Mo+99mTc, M-14C, etc. The static exchange capacity is 1–2 meq/g for cationic sorbents and 0.5–1 meq/g for anionic sorbents. The developed sorbents have been effective in removing low concentrations of contaminants from water (lower than 100–200 mg/L) as well as in purifying the gas mixtures from toxic and aggressive gases: SO2, SO3, NH3, H2S, etc.},
 year = {2020}
}

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TY  - JOUR
T1  - The Application of Fiber Ion Exchange Sorbents for Wastewater Treatment and Purification of Gas Mixtures
AU  - Ilnur Garipov
AU  - Renat Khaydarov
AU  - Olga Gapurova
AU  - Rashid Khaydarov
AU  - Svetlana Evgrafova
Y1  - 2020/06/15
PY  - 2020
N1  - https://doi.org/10.11648/j.jeece.20200501.12
DO  - 10.11648/j.jeece.20200501.12
T2  - Journal of Energy, Environmental & Chemical Engineering
JF  - Journal of Energy, Environmental & Chemical Engineering
JO  - Journal of Energy, Environmental & Chemical Engineering
SP  - 10
EP  - 13
PB  - Science Publishing Group
SN  - 2637-434X
UR  - https://doi.org/10.11648/j.jeece.20200501.12
AB  - We developed a method of modifying the polyester material to produce ion exchange fiber sorbents. The production of cation exchange sorbents involved the treatment of polyester fibers with a 20–25% solution of NH2NH2H2O at 70–90°C and a 5% solution of NaOH at 40°C. Anion exchange sorbents were prepared by the treatment of cation exchange sorbents with a 1–5% solution of polyethylenimine at ambient temperature. These new types of sorbents can be used to remove radionuclides, heavy metal ions and organic contaminants from wastewater and drinking water. We studied main properties of these sorbents and their ability to remove 57Co, 60Co, 65Zn, 89Sr, 90Sr, 134Cs, 137Cs and other radionuclides, heavy metal ions (Zn, Ni, Cu, Sb, Pb, Cd, Cr, U, etc.), organic molecules M (pesticides, phenols, dioxins, benzene, toluene, etc.), radio-labeled organic molecules M-32P, M-131I, M-99Mo+99mTc, M-14C, etc. The static exchange capacity is 1–2 meq/g for cationic sorbents and 0.5–1 meq/g for anionic sorbents. The developed sorbents have been effective in removing low concentrations of contaminants from water (lower than 100–200 mg/L) as well as in purifying the gas mixtures from toxic and aggressive gases: SO2, SO3, NH3, H2S, etc.
VL  - 5
IS  - 1
ER  -

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Author Information

Ilnur Garipov

Laboratory of Interdisciplinary Technologies, Institute of Nuclear Physics, Uzbekistan Academy of Sciences, Tashkent, Uzbekistan
Renat Khaydarov

Laboratory of Interdisciplinary Technologies, Institute of Nuclear Physics, Uzbekistan Academy of Sciences, Tashkent, Uzbekistan
Olga Gapurova

Laboratory of Interdisciplinary Technologies, Institute of Nuclear Physics, Uzbekistan Academy of Sciences, Tashkent, Uzbekistan
Rashid Khaydarov

Laboratory of Interdisciplinary Technologies, Institute of Nuclear Physics, Uzbekistan Academy of Sciences, Tashkent, Uzbekistan
Svetlana Evgrafova

Department of Biotechnology, Siberian Federal University, Krasnoyarsk, Russia

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APA Style

Ilnur Garipov, Renat Khaydarov, Olga Gapurova, Rashid Khaydarov, Svetlana Evgrafova. (2020). The Application of Fiber Ion Exchange Sorbents for Wastewater Treatment and Purification of Gas Mixtures. Journal of Energy, Environmental & Chemical Engineering, 5(1), 10-13. https://doi.org/10.11648/j.jeece.20200501.12

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ACS Style

Ilnur Garipov; Renat Khaydarov; Olga Gapurova; Rashid Khaydarov; Svetlana Evgrafova. The Application of Fiber Ion Exchange Sorbents for Wastewater Treatment and Purification of Gas Mixtures. J. Energy Environ. Chem. Eng. 2020, 5(1), 10-13. doi: 10.11648/j.jeece.20200501.12

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AMA Style

Ilnur Garipov, Renat Khaydarov, Olga Gapurova, Rashid Khaydarov, Svetlana Evgrafova. The Application of Fiber Ion Exchange Sorbents for Wastewater Treatment and Purification of Gas Mixtures. J Energy Environ Chem Eng. 2020;5(1):10-13. doi: 10.11648/j.jeece.20200501.12

Copy | Download

@article{10.11648/j.jeece.20200501.12,
  author = {Ilnur Garipov and Renat Khaydarov and Olga Gapurova and Rashid Khaydarov and Svetlana Evgrafova},
  title = {The Application of Fiber Ion Exchange Sorbents for Wastewater Treatment and Purification of Gas Mixtures},
  journal = {Journal of Energy, Environmental & Chemical Engineering},
  volume = {5},
  number = {1},
  pages = {10-13},
  doi = {10.11648/j.jeece.20200501.12},
  url = {https://doi.org/10.11648/j.jeece.20200501.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.jeece.20200501.12},
  abstract = {We developed a method of modifying the polyester material to produce ion exchange fiber sorbents. The production of cation exchange sorbents involved the treatment of polyester fibers with a 20–25% solution of NH2NH2H2O at 70–90°C and a 5% solution of NaOH at 40°C. Anion exchange sorbents were prepared by the treatment of cation exchange sorbents with a 1–5% solution of polyethylenimine at ambient temperature. These new types of sorbents can be used to remove radionuclides, heavy metal ions and organic contaminants from wastewater and drinking water. We studied main properties of these sorbents and their ability to remove 57Co, 60Co, 65Zn, 89Sr, 90Sr, 134Cs, 137Cs and other radionuclides, heavy metal ions (Zn, Ni, Cu, Sb, Pb, Cd, Cr, U, etc.), organic molecules M (pesticides, phenols, dioxins, benzene, toluene, etc.), radio-labeled organic molecules M-32P, M-131I, M-99Mo+99mTc, M-14C, etc. The static exchange capacity is 1–2 meq/g for cationic sorbents and 0.5–1 meq/g for anionic sorbents. The developed sorbents have been effective in removing low concentrations of contaminants from water (lower than 100–200 mg/L) as well as in purifying the gas mixtures from toxic and aggressive gases: SO2, SO3, NH3, H2S, etc.},
 year = {2020}
}

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TY  - JOUR
T1  - The Application of Fiber Ion Exchange Sorbents for Wastewater Treatment and Purification of Gas Mixtures
AU  - Ilnur Garipov
AU  - Renat Khaydarov
AU  - Olga Gapurova
AU  - Rashid Khaydarov
AU  - Svetlana Evgrafova
Y1  - 2020/06/15
PY  - 2020
N1  - https://doi.org/10.11648/j.jeece.20200501.12
DO  - 10.11648/j.jeece.20200501.12
T2  - Journal of Energy, Environmental & Chemical Engineering
JF  - Journal of Energy, Environmental & Chemical Engineering
JO  - Journal of Energy, Environmental & Chemical Engineering
SP  - 10
EP  - 13
PB  - Science Publishing Group
SN  - 2637-434X
UR  - https://doi.org/10.11648/j.jeece.20200501.12
AB  - We developed a method of modifying the polyester material to produce ion exchange fiber sorbents. The production of cation exchange sorbents involved the treatment of polyester fibers with a 20–25% solution of NH2NH2H2O at 70–90°C and a 5% solution of NaOH at 40°C. Anion exchange sorbents were prepared by the treatment of cation exchange sorbents with a 1–5% solution of polyethylenimine at ambient temperature. These new types of sorbents can be used to remove radionuclides, heavy metal ions and organic contaminants from wastewater and drinking water. We studied main properties of these sorbents and their ability to remove 57Co, 60Co, 65Zn, 89Sr, 90Sr, 134Cs, 137Cs and other radionuclides, heavy metal ions (Zn, Ni, Cu, Sb, Pb, Cd, Cr, U, etc.), organic molecules M (pesticides, phenols, dioxins, benzene, toluene, etc.), radio-labeled organic molecules M-32P, M-131I, M-99Mo+99mTc, M-14C, etc. The static exchange capacity is 1–2 meq/g for cationic sorbents and 0.5–1 meq/g for anionic sorbents. The developed sorbents have been effective in removing low concentrations of contaminants from water (lower than 100–200 mg/L) as well as in purifying the gas mixtures from toxic and aggressive gases: SO2, SO3, NH3, H2S, etc.
VL  - 5
IS  - 1
ER  -

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