Monitoring the Persistence of Devrinol, Diazinon, and Trifluralin Residues in Soil Following Application of Organic Amendments

George Fouad Antonious

doi:doi:10.11648/j.ijaas.20220803.11

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Monitoring the Persistence of Devrinol, Diazinon, and Trifluralin Residues in Soil Following Application of Organic Amendments

George Fouad Antonious

Published in International Journal of Applied Agricultural Sciences (Volume 8, Issue 3)

Received: 23 February 2022 Accepted: 18 March 2022 Published: 10 May 2022

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Abstract

Pesticides have the potential mobility from the site of application to natural water resources leading to surface water quality problems. Binding pesticides to soil lead to immobilization preventing their mobility into surface water and enhancing their availability for degradation by soil microorganisms and their secreting enzymes. The impact of low-cost organic amendments used in agricultural operations on the persistence of three pesticides; devrinol, diazinon, and trifluralin in agricultural soil was investigated. Pesticide residues in sewage sludge (SS), farm compost (Comp), and no-mulch (NM) control treatment following field application were monitored at different time intervals using solvent partitioning and gas chromatographic procedure (GC). Half-life (T_1/2) values of the three pesticides in soil were determined under three farming practices to investigate how long each pesticide remains in each soil treatment. Results revealed the retention of devrinol by 30%, diazinon by 55%, and trifluralin by 80% in soil amended with SS compared to sole NM soil used as control treatment. This practice might prevent the off-site movement of pesticides. Devrinol T_1/2 value of 14.1 days was significantly (P≤ 0.05) lower in soil amended with Comp compared to SS amended soil due to its high dissipation constant (K). Diazinon residues fluctuated during the first week after spraying and started to decline, reaching a minimum value of 0.004 µg g^-1 soil at 35 days after spraying. Its T_1/2 value of 10.6 days was significantly lower in SS amended soil compared to Comp waste and control treatments (15.8 and 18.5 days, respectively). Trifluralin residues in NM soil showed a low dissipation constant and greater (T_1/2) value of 116 days. Its dissipation and degradation in soil amended with Comp and SS indicated half-life (T_1/2) values of 48.5 and 34.6 days, respectively. The low adsorptive capacity of devrinol due to its high-water solubility requires minimizing its application rates in agricultural regions to prevent environmental contamination of natural water resources.

Published in	International Journal of Applied Agricultural Sciences (Volume 8, Issue 3)
DOI	10.11648/j.ijaas.20220803.11
Page(s)	104-112
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2022. Published by Science Publishing Group

Keywords

Pesticide Binding, Gas Chromatography, Dissipation Constants, Half-Lives, Initial Residues

References

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APA Style

George Fouad Antonious. (2022). Monitoring the Persistence of Devrinol, Diazinon, and Trifluralin Residues in Soil Following Application of Organic Amendments. International Journal of Applied Agricultural Sciences, 8(3), 104-112. https://doi.org/10.11648/j.ijaas.20220803.11

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ACS Style

George Fouad Antonious. Monitoring the Persistence of Devrinol, Diazinon, and Trifluralin Residues in Soil Following Application of Organic Amendments. Int. J. Appl. Agric. Sci. 2022, 8(3), 104-112. doi: 10.11648/j.ijaas.20220803.11

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AMA Style

George Fouad Antonious. Monitoring the Persistence of Devrinol, Diazinon, and Trifluralin Residues in Soil Following Application of Organic Amendments. Int J Appl Agric Sci. 2022;8(3):104-112. doi: 10.11648/j.ijaas.20220803.11

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@article{10.11648/j.ijaas.20220803.11,
  author = {George Fouad Antonious},
  title = {Monitoring the Persistence of Devrinol, Diazinon, and Trifluralin Residues in Soil Following Application of Organic Amendments},
  journal = {International Journal of Applied Agricultural Sciences},
  volume = {8},
  number = {3},
  pages = {104-112},
  doi = {10.11648/j.ijaas.20220803.11},
  url = {https://doi.org/10.11648/j.ijaas.20220803.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijaas.20220803.11},
  abstract = {Pesticides have the potential mobility from the site of application to natural water resources leading to surface water quality problems. Binding pesticides to soil lead to immobilization preventing their mobility into surface water and enhancing their availability for degradation by soil microorganisms and their secreting enzymes. The impact of low-cost organic amendments used in agricultural operations on the persistence of three pesticides; devrinol, diazinon, and trifluralin in agricultural soil was investigated. Pesticide residues in sewage sludge (SS), farm compost (Comp), and no-mulch (NM) control treatment following field application were monitored at different time intervals using solvent partitioning and gas chromatographic procedure (GC). Half-life (T1/2) values of the three pesticides in soil were determined under three farming practices to investigate how long each pesticide remains in each soil treatment. Results revealed the retention of devrinol by 30%, diazinon by 55%, and trifluralin by 80% in soil amended with SS compared to sole NM soil used as control treatment. This practice might prevent the off-site movement of pesticides. Devrinol T1/2 value of 14.1 days was significantly (P≤ 0.05) lower in soil amended with Comp compared to SS amended soil due to its high dissipation constant (K). Diazinon residues fluctuated during the first week after spraying and started to decline, reaching a minimum value of 0.004 µg g-1 soil at 35 days after spraying. Its T1/2 value of 10.6 days was significantly lower in SS amended soil compared to Comp waste and control treatments (15.8 and 18.5 days, respectively). Trifluralin residues in NM soil showed a low dissipation constant and greater (T1/2) value of 116 days. Its dissipation and degradation in soil amended with Comp and SS indicated half-life (T1/2) values of 48.5 and 34.6 days, respectively. The low adsorptive capacity of devrinol due to its high-water solubility requires minimizing its application rates in agricultural regions to prevent environmental contamination of natural water resources.},
 year = {2022}
}

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TY  - JOUR
T1  - Monitoring the Persistence of Devrinol, Diazinon, and Trifluralin Residues in Soil Following Application of Organic Amendments
AU  - George Fouad Antonious
Y1  - 2022/05/10
PY  - 2022
N1  - https://doi.org/10.11648/j.ijaas.20220803.11
DO  - 10.11648/j.ijaas.20220803.11
T2  - International Journal of Applied Agricultural Sciences
JF  - International Journal of Applied Agricultural Sciences
JO  - International Journal of Applied Agricultural Sciences
SP  - 104
EP  - 112
PB  - Science Publishing Group
SN  - 2469-7885
UR  - https://doi.org/10.11648/j.ijaas.20220803.11
AB  - Pesticides have the potential mobility from the site of application to natural water resources leading to surface water quality problems. Binding pesticides to soil lead to immobilization preventing their mobility into surface water and enhancing their availability for degradation by soil microorganisms and their secreting enzymes. The impact of low-cost organic amendments used in agricultural operations on the persistence of three pesticides; devrinol, diazinon, and trifluralin in agricultural soil was investigated. Pesticide residues in sewage sludge (SS), farm compost (Comp), and no-mulch (NM) control treatment following field application were monitored at different time intervals using solvent partitioning and gas chromatographic procedure (GC). Half-life (T1/2) values of the three pesticides in soil were determined under three farming practices to investigate how long each pesticide remains in each soil treatment. Results revealed the retention of devrinol by 30%, diazinon by 55%, and trifluralin by 80% in soil amended with SS compared to sole NM soil used as control treatment. This practice might prevent the off-site movement of pesticides. Devrinol T1/2 value of 14.1 days was significantly (P≤ 0.05) lower in soil amended with Comp compared to SS amended soil due to its high dissipation constant (K). Diazinon residues fluctuated during the first week after spraying and started to decline, reaching a minimum value of 0.004 µg g-1 soil at 35 days after spraying. Its T1/2 value of 10.6 days was significantly lower in SS amended soil compared to Comp waste and control treatments (15.8 and 18.5 days, respectively). Trifluralin residues in NM soil showed a low dissipation constant and greater (T1/2) value of 116 days. Its dissipation and degradation in soil amended with Comp and SS indicated half-life (T1/2) values of 48.5 and 34.6 days, respectively. The low adsorptive capacity of devrinol due to its high-water solubility requires minimizing its application rates in agricultural regions to prevent environmental contamination of natural water resources.
VL  - 8
IS  - 3
ER  -

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George Fouad Antonious

Division of Environmental Studies, College of Agriculture, Community and the Sciences, Kentucky State University, Frankfort, USA

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APA Style

George Fouad Antonious. (2022). Monitoring the Persistence of Devrinol, Diazinon, and Trifluralin Residues in Soil Following Application of Organic Amendments. International Journal of Applied Agricultural Sciences, 8(3), 104-112. https://doi.org/10.11648/j.ijaas.20220803.11

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ACS Style

George Fouad Antonious. Monitoring the Persistence of Devrinol, Diazinon, and Trifluralin Residues in Soil Following Application of Organic Amendments. Int. J. Appl. Agric. Sci. 2022, 8(3), 104-112. doi: 10.11648/j.ijaas.20220803.11

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AMA Style

George Fouad Antonious. Monitoring the Persistence of Devrinol, Diazinon, and Trifluralin Residues in Soil Following Application of Organic Amendments. Int J Appl Agric Sci. 2022;8(3):104-112. doi: 10.11648/j.ijaas.20220803.11

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@article{10.11648/j.ijaas.20220803.11,
  author = {George Fouad Antonious},
  title = {Monitoring the Persistence of Devrinol, Diazinon, and Trifluralin Residues in Soil Following Application of Organic Amendments},
  journal = {International Journal of Applied Agricultural Sciences},
  volume = {8},
  number = {3},
  pages = {104-112},
  doi = {10.11648/j.ijaas.20220803.11},
  url = {https://doi.org/10.11648/j.ijaas.20220803.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijaas.20220803.11},
  abstract = {Pesticides have the potential mobility from the site of application to natural water resources leading to surface water quality problems. Binding pesticides to soil lead to immobilization preventing their mobility into surface water and enhancing their availability for degradation by soil microorganisms and their secreting enzymes. The impact of low-cost organic amendments used in agricultural operations on the persistence of three pesticides; devrinol, diazinon, and trifluralin in agricultural soil was investigated. Pesticide residues in sewage sludge (SS), farm compost (Comp), and no-mulch (NM) control treatment following field application were monitored at different time intervals using solvent partitioning and gas chromatographic procedure (GC). Half-life (T1/2) values of the three pesticides in soil were determined under three farming practices to investigate how long each pesticide remains in each soil treatment. Results revealed the retention of devrinol by 30%, diazinon by 55%, and trifluralin by 80% in soil amended with SS compared to sole NM soil used as control treatment. This practice might prevent the off-site movement of pesticides. Devrinol T1/2 value of 14.1 days was significantly (P≤ 0.05) lower in soil amended with Comp compared to SS amended soil due to its high dissipation constant (K). Diazinon residues fluctuated during the first week after spraying and started to decline, reaching a minimum value of 0.004 µg g-1 soil at 35 days after spraying. Its T1/2 value of 10.6 days was significantly lower in SS amended soil compared to Comp waste and control treatments (15.8 and 18.5 days, respectively). Trifluralin residues in NM soil showed a low dissipation constant and greater (T1/2) value of 116 days. Its dissipation and degradation in soil amended with Comp and SS indicated half-life (T1/2) values of 48.5 and 34.6 days, respectively. The low adsorptive capacity of devrinol due to its high-water solubility requires minimizing its application rates in agricultural regions to prevent environmental contamination of natural water resources.},
 year = {2022}
}

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TY  - JOUR
T1  - Monitoring the Persistence of Devrinol, Diazinon, and Trifluralin Residues in Soil Following Application of Organic Amendments
AU  - George Fouad Antonious
Y1  - 2022/05/10
PY  - 2022
N1  - https://doi.org/10.11648/j.ijaas.20220803.11
DO  - 10.11648/j.ijaas.20220803.11
T2  - International Journal of Applied Agricultural Sciences
JF  - International Journal of Applied Agricultural Sciences
JO  - International Journal of Applied Agricultural Sciences
SP  - 104
EP  - 112
PB  - Science Publishing Group
SN  - 2469-7885
UR  - https://doi.org/10.11648/j.ijaas.20220803.11
AB  - Pesticides have the potential mobility from the site of application to natural water resources leading to surface water quality problems. Binding pesticides to soil lead to immobilization preventing their mobility into surface water and enhancing their availability for degradation by soil microorganisms and their secreting enzymes. The impact of low-cost organic amendments used in agricultural operations on the persistence of three pesticides; devrinol, diazinon, and trifluralin in agricultural soil was investigated. Pesticide residues in sewage sludge (SS), farm compost (Comp), and no-mulch (NM) control treatment following field application were monitored at different time intervals using solvent partitioning and gas chromatographic procedure (GC). Half-life (T1/2) values of the three pesticides in soil were determined under three farming practices to investigate how long each pesticide remains in each soil treatment. Results revealed the retention of devrinol by 30%, diazinon by 55%, and trifluralin by 80% in soil amended with SS compared to sole NM soil used as control treatment. This practice might prevent the off-site movement of pesticides. Devrinol T1/2 value of 14.1 days was significantly (P≤ 0.05) lower in soil amended with Comp compared to SS amended soil due to its high dissipation constant (K). Diazinon residues fluctuated during the first week after spraying and started to decline, reaching a minimum value of 0.004 µg g-1 soil at 35 days after spraying. Its T1/2 value of 10.6 days was significantly lower in SS amended soil compared to Comp waste and control treatments (15.8 and 18.5 days, respectively). Trifluralin residues in NM soil showed a low dissipation constant and greater (T1/2) value of 116 days. Its dissipation and degradation in soil amended with Comp and SS indicated half-life (T1/2) values of 48.5 and 34.6 days, respectively. The low adsorptive capacity of devrinol due to its high-water solubility requires minimizing its application rates in agricultural regions to prevent environmental contamination of natural water resources.
VL  - 8
IS  - 3
ER  -

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