Physic and Chemical Transformations for Metal Polymer Nano-composite on Basic Pyrolyzed Polyacrylonitrile (C3H3N)<sub>n</sub> and Their Impact on Properties

Dmitry Podgorny; Alexey Rodin; Xu Ren

doi:doi:10.11648/j.cm.20220601.13

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Physic and Chemical Transformations for Metal Polymer Nano-composite on Basic Pyrolyzed Polyacrylonitrile (C3H3N)_n and Their Impact on Properties

Dmitry Podgorny, Alexey Rodin, Xu Ren

Published in Composite Materials (Volume 6, Issue 1)

Received: 9 January 2022 Accepted: 25 January 2022 Published: 5 February 2022

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Abstract

In this review, we discuss the basic concepts related to various methods (such as Metal Spraying on Polymers, Microencapsulation…) and the properties of electrical Superparamagnetic applied in polymer-metal nanocomposite films. Within the organic-inorganic hybrid nanocomposites research framework, the field related to metal-polymer nanocomposites is attracting much interest. In fact, it is opening pathways for engineering flexible composites that exhibit advantageous electrical, optical, or mechanical properties. The metal-polymer nanocomposites research field is, now, a wide, complex, and important part of the nanotechnology revolution. So, with this review we aim, starting from the discussion of specific cases, to focus our attention on the basic microscopic mechanisms and processes and the general concepts suitable for the interpretation of material properties and structure–property correlations. The review aims, in addition, to provide a comprehensive schematization of the main technological applications currently in development worldwide. So here we show that nanocomposite films of Metal Polymer Based polyacrylonitrile (PAN) films were manufactured using the method of pyrolysis under incoherent IRradiation and were studied using AFM, XPS, and XRD atomic force microscopy (AFM), Xray photoelectron spectroscopy (XPS), and Xray diffraction (XRD) methods (Some of those methods are widely used in material research study, here we don’t want to introduce them more). The XPS method was used to determine the elemental composition and the chemical and electron states of the elements of the film material. The XRD method showed that the obtained materials contained crystalline inclusions of Me_a(CO)_b, Me(CO)_x(NO)_y (where Me is a metal) in an organic matrix of PAN. Then by using experimental methods referred in this article, we can achieve a result of polymer pyrolysis, a metal-polymer nanocomposite is formed with nanoparticles less than 100 nm in size, containing a metal or a metal oxide for the research of material properties.

Published in	Composite Materials (Volume 6, Issue 1)
DOI	10.11648/j.cm.20220601.13
Page(s)	17-31
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2022. Published by Science Publishing Group

Keywords

Physical and Chemical Transformations, Electronic Analyse Method, Metal Polymer Nanocomposite

References

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Dmitry Podgorny, Alexey Rodin, Xu Ren. (2022). Physic and Chemical Transformations for Metal Polymer Nano-composite on Basic Pyrolyzed Polyacrylonitrile (C3H3N)n and Their Impact on Properties. Composite Materials, 6(1), 17-31. https://doi.org/10.11648/j.cm.20220601.13

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Dmitry Podgorny; Alexey Rodin; Xu Ren. Physic and Chemical Transformations for Metal Polymer Nano-composite on Basic Pyrolyzed Polyacrylonitrile (C3H3N)n and Their Impact on Properties. Compos. Mater. 2022, 6(1), 17-31. doi: 10.11648/j.cm.20220601.13

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Dmitry Podgorny, Alexey Rodin, Xu Ren. Physic and Chemical Transformations for Metal Polymer Nano-composite on Basic Pyrolyzed Polyacrylonitrile (C3H3N)n and Their Impact on Properties. Compos Mater. 2022;6(1):17-31. doi: 10.11648/j.cm.20220601.13

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@article{10.11648/j.cm.20220601.13,
  author = {Dmitry Podgorny and Alexey Rodin and Xu Ren},
  title = {Physic and Chemical Transformations for Metal Polymer Nano-composite on Basic Pyrolyzed Polyacrylonitrile (C3H3N)n and Their Impact on Properties},
  journal = {Composite Materials},
  volume = {6},
  number = {1},
  pages = {17-31},
  doi = {10.11648/j.cm.20220601.13},
  url = {https://doi.org/10.11648/j.cm.20220601.13},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.cm.20220601.13},
  abstract = {In this review, we discuss the basic concepts related to various methods (such as Metal Spraying on Polymers, Microencapsulation…) and the properties of electrical Superparamagnetic applied in polymer-metal nanocomposite films. Within the organic-inorganic hybrid nanocomposites research framework, the field related to metal-polymer nanocomposites is attracting much interest. In fact, it is opening pathways for engineering flexible composites that exhibit advantageous electrical, optical, or mechanical properties. The metal-polymer nanocomposites research field is, now, a wide, complex, and important part of the nanotechnology revolution. So, with this review we aim, starting from the discussion of specific cases, to focus our attention on the basic microscopic mechanisms and processes and the general concepts suitable for the interpretation of material properties and structure–property correlations. The review aims, in addition, to provide a comprehensive schematization of the main technological applications currently in development worldwide. So here we show that nanocomposite films of Metal Polymer Based polyacrylonitrile (PAN) films were manufactured using the method of pyrolysis under incoherent IRradiation and were studied using AFM, XPS, and XRD atomic force microscopy (AFM), Xray photoelectron spectroscopy (XPS), and Xray diffraction (XRD) methods (Some of those methods are widely used in material research study, here we don’t want to introduce them more). The XPS method was used to determine the elemental composition and the chemical and electron states of the elements of the film material. The XRD method showed that the obtained materials contained crystalline inclusions of Mea(CO)b, Me(CO)x(NO)y (where Me is a metal) in an organic matrix of PAN. Then by using experimental methods referred in this article, we can achieve a result of polymer pyrolysis, a metal-polymer nanocomposite is formed with nanoparticles less than 100 nm in size, containing a metal or a metal oxide for the research of material properties.},
 year = {2022}
}

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TY  - JOUR
T1  - Physic and Chemical Transformations for Metal Polymer Nano-composite on Basic Pyrolyzed Polyacrylonitrile (C3H3N)n and Their Impact on Properties
AU  - Dmitry Podgorny
AU  - Alexey Rodin
AU  - Xu Ren
Y1  - 2022/02/05
PY  - 2022
N1  - https://doi.org/10.11648/j.cm.20220601.13
DO  - 10.11648/j.cm.20220601.13
T2  - Composite Materials
JF  - Composite Materials
JO  - Composite Materials
SP  - 17
EP  - 31
PB  - Science Publishing Group
SN  - 2994-7103
UR  - https://doi.org/10.11648/j.cm.20220601.13
AB  - In this review, we discuss the basic concepts related to various methods (such as Metal Spraying on Polymers, Microencapsulation…) and the properties of electrical Superparamagnetic applied in polymer-metal nanocomposite films. Within the organic-inorganic hybrid nanocomposites research framework, the field related to metal-polymer nanocomposites is attracting much interest. In fact, it is opening pathways for engineering flexible composites that exhibit advantageous electrical, optical, or mechanical properties. The metal-polymer nanocomposites research field is, now, a wide, complex, and important part of the nanotechnology revolution. So, with this review we aim, starting from the discussion of specific cases, to focus our attention on the basic microscopic mechanisms and processes and the general concepts suitable for the interpretation of material properties and structure–property correlations. The review aims, in addition, to provide a comprehensive schematization of the main technological applications currently in development worldwide. So here we show that nanocomposite films of Metal Polymer Based polyacrylonitrile (PAN) films were manufactured using the method of pyrolysis under incoherent IRradiation and were studied using AFM, XPS, and XRD atomic force microscopy (AFM), Xray photoelectron spectroscopy (XPS), and Xray diffraction (XRD) methods (Some of those methods are widely used in material research study, here we don’t want to introduce them more). The XPS method was used to determine the elemental composition and the chemical and electron states of the elements of the film material. The XRD method showed that the obtained materials contained crystalline inclusions of Mea(CO)b, Me(CO)x(NO)y (where Me is a metal) in an organic matrix of PAN. Then by using experimental methods referred in this article, we can achieve a result of polymer pyrolysis, a metal-polymer nanocomposite is formed with nanoparticles less than 100 nm in size, containing a metal or a metal oxide for the research of material properties.
VL  - 6
IS  - 1
ER  -

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Dmitry Podgorny

Institute for New Material and Nanotechnology, National University of Science and Technology "MISIS" (Moscow Institute of Steel and Alloys), Moscow, Russian
Alexey Rodin

Institute for New Material and Nanotechnology, National University of Science and Technology "MISIS" (Moscow Institute of Steel and Alloys), Moscow, Russian
Xu Ren

Institute for New Material and Nanotechnology, National University of Science and Technology "MISIS" (Moscow Institute of Steel and Alloys), Moscow, Russian

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Dmitry Podgorny, Alexey Rodin, Xu Ren. (2022). Physic and Chemical Transformations for Metal Polymer Nano-composite on Basic Pyrolyzed Polyacrylonitrile (C3H3N)n and Their Impact on Properties. Composite Materials, 6(1), 17-31. https://doi.org/10.11648/j.cm.20220601.13

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ACS Style

Dmitry Podgorny; Alexey Rodin; Xu Ren. Physic and Chemical Transformations for Metal Polymer Nano-composite on Basic Pyrolyzed Polyacrylonitrile (C3H3N)n and Their Impact on Properties. Compos. Mater. 2022, 6(1), 17-31. doi: 10.11648/j.cm.20220601.13

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Dmitry Podgorny, Alexey Rodin, Xu Ren. Physic and Chemical Transformations for Metal Polymer Nano-composite on Basic Pyrolyzed Polyacrylonitrile (C3H3N)n and Their Impact on Properties. Compos Mater. 2022;6(1):17-31. doi: 10.11648/j.cm.20220601.13

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@article{10.11648/j.cm.20220601.13,
  author = {Dmitry Podgorny and Alexey Rodin and Xu Ren},
  title = {Physic and Chemical Transformations for Metal Polymer Nano-composite on Basic Pyrolyzed Polyacrylonitrile (C3H3N)n and Their Impact on Properties},
  journal = {Composite Materials},
  volume = {6},
  number = {1},
  pages = {17-31},
  doi = {10.11648/j.cm.20220601.13},
  url = {https://doi.org/10.11648/j.cm.20220601.13},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.cm.20220601.13},
  abstract = {In this review, we discuss the basic concepts related to various methods (such as Metal Spraying on Polymers, Microencapsulation…) and the properties of electrical Superparamagnetic applied in polymer-metal nanocomposite films. Within the organic-inorganic hybrid nanocomposites research framework, the field related to metal-polymer nanocomposites is attracting much interest. In fact, it is opening pathways for engineering flexible composites that exhibit advantageous electrical, optical, or mechanical properties. The metal-polymer nanocomposites research field is, now, a wide, complex, and important part of the nanotechnology revolution. So, with this review we aim, starting from the discussion of specific cases, to focus our attention on the basic microscopic mechanisms and processes and the general concepts suitable for the interpretation of material properties and structure–property correlations. The review aims, in addition, to provide a comprehensive schematization of the main technological applications currently in development worldwide. So here we show that nanocomposite films of Metal Polymer Based polyacrylonitrile (PAN) films were manufactured using the method of pyrolysis under incoherent IRradiation and were studied using AFM, XPS, and XRD atomic force microscopy (AFM), Xray photoelectron spectroscopy (XPS), and Xray diffraction (XRD) methods (Some of those methods are widely used in material research study, here we don’t want to introduce them more). The XPS method was used to determine the elemental composition and the chemical and electron states of the elements of the film material. The XRD method showed that the obtained materials contained crystalline inclusions of Mea(CO)b, Me(CO)x(NO)y (where Me is a metal) in an organic matrix of PAN. Then by using experimental methods referred in this article, we can achieve a result of polymer pyrolysis, a metal-polymer nanocomposite is formed with nanoparticles less than 100 nm in size, containing a metal or a metal oxide for the research of material properties.},
 year = {2022}
}

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TY  - JOUR
T1  - Physic and Chemical Transformations for Metal Polymer Nano-composite on Basic Pyrolyzed Polyacrylonitrile (C3H3N)n and Their Impact on Properties
AU  - Dmitry Podgorny
AU  - Alexey Rodin
AU  - Xu Ren
Y1  - 2022/02/05
PY  - 2022
N1  - https://doi.org/10.11648/j.cm.20220601.13
DO  - 10.11648/j.cm.20220601.13
T2  - Composite Materials
JF  - Composite Materials
JO  - Composite Materials
SP  - 17
EP  - 31
PB  - Science Publishing Group
SN  - 2994-7103
UR  - https://doi.org/10.11648/j.cm.20220601.13
AB  - In this review, we discuss the basic concepts related to various methods (such as Metal Spraying on Polymers, Microencapsulation…) and the properties of electrical Superparamagnetic applied in polymer-metal nanocomposite films. Within the organic-inorganic hybrid nanocomposites research framework, the field related to metal-polymer nanocomposites is attracting much interest. In fact, it is opening pathways for engineering flexible composites that exhibit advantageous electrical, optical, or mechanical properties. The metal-polymer nanocomposites research field is, now, a wide, complex, and important part of the nanotechnology revolution. So, with this review we aim, starting from the discussion of specific cases, to focus our attention on the basic microscopic mechanisms and processes and the general concepts suitable for the interpretation of material properties and structure–property correlations. The review aims, in addition, to provide a comprehensive schematization of the main technological applications currently in development worldwide. So here we show that nanocomposite films of Metal Polymer Based polyacrylonitrile (PAN) films were manufactured using the method of pyrolysis under incoherent IRradiation and were studied using AFM, XPS, and XRD atomic force microscopy (AFM), Xray photoelectron spectroscopy (XPS), and Xray diffraction (XRD) methods (Some of those methods are widely used in material research study, here we don’t want to introduce them more). The XPS method was used to determine the elemental composition and the chemical and electron states of the elements of the film material. The XRD method showed that the obtained materials contained crystalline inclusions of Mea(CO)b, Me(CO)x(NO)y (where Me is a metal) in an organic matrix of PAN. Then by using experimental methods referred in this article, we can achieve a result of polymer pyrolysis, a metal-polymer nanocomposite is formed with nanoparticles less than 100 nm in size, containing a metal or a metal oxide for the research of material properties.
VL  - 6
IS  - 1
ER  -

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