Starch-g-polyacrylamide (St-g-PAM) and Starch-g- poly (N, N-dimethylacryl amide) (St-g-PDMA) were prepared by using acrylamide (AM) and N, N-dimethylacrylamide (DMA) by Ce (IV) ion induced aqueous polymerization technique. Various grafting parameters were optimized. The so prepared graft copolymers were characterized by fourier transform infrared spectroscopy (FTIR) spectroscopy, molecular weight determination by size exclusion chromatography (SEC), thermal analysis (TGA / DTG), X-ray powder diffraction (XRD) and biodegradation studies. Flocculation performances of the graft copolymers were compared in 1.0 wt% bentonite clay, 1.0 wt % coal suspensions and 10 wt% malachite green (a textile dye) solution and in a textile dye effluent. Between the two polymers St-g-PAM and St-g-PDMA, the later showed better performance in the flocculation of bentonite and coal suspensions but the former showed better performance in the color removal from the malachite green solution and from one of the textile industrial waste water.
Published in | American Journal of Polymer Science and Technology (Volume 3, Issue 1) |
DOI | 10.11648/j.ajpst.20170301.11 |
Page(s) | 1-11 |
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Copyright © The Author(s), 2017. Published by Science Publishing Group |
Graft Copolymerization, Starch, Color Removal, Flocculation, Poly (N, N-dimethylacrylamide)
[1] | Z. Aksu, Process Biochem, 2005, 40, 997-1026. |
[2] | G. Crini, Bioresour Technol, 2006, 97, 1061-1085. |
[3] | C.H. Weng, Y. T. Lin, Y. J. Chin, Y. C. Sharma, Coloration Technol, 2013, 129, 298-304. |
[4] | G. N. Zaharaddeen, S. B. F. Shikin, A. R. Afidah, J. Chem. Eng. Chem. Res. 2015, 2, 623-633. |
[5] | A. Pala, E. Tokat, Water Resource, 2002, 36, 2920-2925. |
[6] | O. Yavuz, A. H. Aydin, Fresenius Environ Bull, 2002, 11, 377-383. |
[7] | G. Petzold, A. Nebel, H. M. Buchhammer, K. Lunkuitz, Colloid Polym Sci, 1998, 276, 125-130. |
[8] | H. M. Buchhammer, M. Oelmann, G. Petzold, Melliand Int, 2001, 82, 104-105. |
[9] | H. Barkert, J. Hartmann, John wiley & Sons: New York , 1988, 5, 251. |
[10] | R. P. Singh, T. Tripathy, G. P. Karmakar, S. K. Rath, N. C. Karmakar, S. R. Pandey, K. Kannan, S. K. Jain, N. T. Lan, Curr Sci, 2000, 78, 798. |
[11] | S. K. Rath, R. P. Singh, J. Appl polym Sci. 1997, 66, 1721-1729. |
[12] | S. Ghorai, A. Sarkar, M. Raoufi, A. Baran, P. H. Sönherr, S. Pal, ACS Appl. Mater. Interfaces, 2014, 6, 4766-4777. |
[13] | A. K. Sarkar, A. Pal, S, Ghorai, N.R. Mandre, S. Pal, Carbohydr Polym, 2014, 111, 108-115. |
[14] | H. Kolya, T. Tripathy, Int J Biol Macromol, 2013, 62, 557-564. |
[15] | D. Sasmal, R. P. Singh, T. Tripathy, Colloids and surf A, 2015, 482, 575-584. |
[16] | K. Katoka, H. Miyazaki, T. Okano, Y. Sakurai, Macromol, 1994, 27, 1061-1062. |
[17] | C. L. Mc Cormick, G. S. Chen, J Polym Sci Part A Polym Chem 1984, 22, 3633-3647. |
[18] | H. Kolya, T. Tripathy, J Appl Polym Sci, 2013, 127, 2786-2795. |
[19] | H. Kolya, Tripathy, T, Int J Bio Macromol, 2014, 70, 26-36. |
[20] | D. K. Mishra, J. Tripathy, K. Behari, Carbohydr Polym , 2008, 71, 524-534. |
[21] | Yongsheng Niu, Hongchun Li, Industrial & Engineering Chemistry Research, 2012, 51, 12173-12177. |
[22] | J. Clayden, N. Greeves, S. Waren, P. Worthers, Organic Chemistry, Oxford University Press, UK, 2001, p. 293. |
[23] | G. Mino, S. Kaizerman, J Polym Sci, 1958, 31, 242-243. |
[24] | G. F. Fanta, in: R.J. Cresa (Ed.), Block and Graft Copolymerization, Wiley-Inter Science, New York, NY/London, 1973, p. 1–27. |
[25] | K. G. Vamsi, M. Susmita, Int J Eng. Res. Appl. 2012, 2, 390–399. |
[26] | J. Bratby, Flocculation and Coagulation, Uplands Press, Croydon, UK, 1980, Chapter 8. |
[27] | H. Kolya, T. Tripathy, Eur. Polym. J. 2013, 49, 4265-4275. |
[28] | D. Shubo, G. Yu, Peng T Yen, Colloids Surf. B, 2005, 44, 179–186. |
[29] | A. A. Berlin, V. N. Kislenko, Prog. Polym. Sci. 1992, 17, 765–825. |
[30] | D. Prashant, Nirmal K Pandya, P.V.K Patel Sinha, Vijay Kumar Sinha, Int J Polym Mater 2003, 52, 565–571. |
[31] | A. Pandey, D. Banerjee, Terestrial and Aquatic Environmental Toxicology, 20102, 6, 8-13. |
[32] | W. M. Kulicke, R. Kniewske, J. Klein, Prog. Polym. Sci. 1982, 8, 373. |
APA Style
Haradhan Kolya, Tridib Tripathy. (2017). Flocculation and Color Removal Performances of Polyacrylamide and Poly N, N-Dimethylacrylamide Grafted Starch: A Comparative Study. American Journal of Polymer Science and Technology, 3(1), 1-11. https://doi.org/10.11648/j.ajpst.20170301.11
ACS Style
Haradhan Kolya; Tridib Tripathy. Flocculation and Color Removal Performances of Polyacrylamide and Poly N, N-Dimethylacrylamide Grafted Starch: A Comparative Study. Am. J. Polym. Sci. Technol. 2017, 3(1), 1-11. doi: 10.11648/j.ajpst.20170301.11
AMA Style
Haradhan Kolya, Tridib Tripathy. Flocculation and Color Removal Performances of Polyacrylamide and Poly N, N-Dimethylacrylamide Grafted Starch: A Comparative Study. Am J Polym Sci Technol. 2017;3(1):1-11. doi: 10.11648/j.ajpst.20170301.11
@article{10.11648/j.ajpst.20170301.11, author = {Haradhan Kolya and Tridib Tripathy}, title = {Flocculation and Color Removal Performances of Polyacrylamide and Poly N, N-Dimethylacrylamide Grafted Starch: A Comparative Study}, journal = {American Journal of Polymer Science and Technology}, volume = {3}, number = {1}, pages = {1-11}, doi = {10.11648/j.ajpst.20170301.11}, url = {https://doi.org/10.11648/j.ajpst.20170301.11}, eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpst.20170301.11}, abstract = {Starch-g-polyacrylamide (St-g-PAM) and Starch-g- poly (N, N-dimethylacryl amide) (St-g-PDMA) were prepared by using acrylamide (AM) and N, N-dimethylacrylamide (DMA) by Ce (IV) ion induced aqueous polymerization technique. Various grafting parameters were optimized. The so prepared graft copolymers were characterized by fourier transform infrared spectroscopy (FTIR) spectroscopy, molecular weight determination by size exclusion chromatography (SEC), thermal analysis (TGA / DTG), X-ray powder diffraction (XRD) and biodegradation studies. Flocculation performances of the graft copolymers were compared in 1.0 wt% bentonite clay, 1.0 wt % coal suspensions and 10 wt% malachite green (a textile dye) solution and in a textile dye effluent. Between the two polymers St-g-PAM and St-g-PDMA, the later showed better performance in the flocculation of bentonite and coal suspensions but the former showed better performance in the color removal from the malachite green solution and from one of the textile industrial waste water.}, year = {2017} }
TY - JOUR T1 - Flocculation and Color Removal Performances of Polyacrylamide and Poly N, N-Dimethylacrylamide Grafted Starch: A Comparative Study AU - Haradhan Kolya AU - Tridib Tripathy Y1 - 2017/02/13 PY - 2017 N1 - https://doi.org/10.11648/j.ajpst.20170301.11 DO - 10.11648/j.ajpst.20170301.11 T2 - American Journal of Polymer Science and Technology JF - American Journal of Polymer Science and Technology JO - American Journal of Polymer Science and Technology SP - 1 EP - 11 PB - Science Publishing Group SN - 2575-5986 UR - https://doi.org/10.11648/j.ajpst.20170301.11 AB - Starch-g-polyacrylamide (St-g-PAM) and Starch-g- poly (N, N-dimethylacryl amide) (St-g-PDMA) were prepared by using acrylamide (AM) and N, N-dimethylacrylamide (DMA) by Ce (IV) ion induced aqueous polymerization technique. Various grafting parameters were optimized. The so prepared graft copolymers were characterized by fourier transform infrared spectroscopy (FTIR) spectroscopy, molecular weight determination by size exclusion chromatography (SEC), thermal analysis (TGA / DTG), X-ray powder diffraction (XRD) and biodegradation studies. Flocculation performances of the graft copolymers were compared in 1.0 wt% bentonite clay, 1.0 wt % coal suspensions and 10 wt% malachite green (a textile dye) solution and in a textile dye effluent. Between the two polymers St-g-PAM and St-g-PDMA, the later showed better performance in the flocculation of bentonite and coal suspensions but the former showed better performance in the color removal from the malachite green solution and from one of the textile industrial waste water. VL - 3 IS - 1 ER -