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Adsorption of Metallic Ions in Lamellar Crystalline Compounds Intercalated with Organic Molecules

Received: 16 September 2016     Accepted: 2 November 2016     Published: 13 January 2017
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Abstract

This work describes the synthesis and characterization of crystalline lamellar calcium phosphate intercalated with m-aminobenzoic acid (CaP/MABA), and results of a study of adsorption and preconcentration of Zn(II), Ni(II), Co(II) and Cu(II), and in ethanol medium. The adsorption isotherms from ethanol gave the maximum adsorption capacities of 1.43, 1.04, .030 and 0.19 mmol g-1 for copper, nickel, cobalt and zinc, respectively, which average stability constants followed Zn(II) > Ni(II) > Co(II) > Cu(II); the number of ligands was determined as four for both cations. The results obtained in flow experiments showed a retention and recovery of ca. 100% of the metal ion with packed CaP/MABA columns from solution containing a mixture of these cations.

Published in American Journal of Polymer Science and Technology (Volume 2, Issue 2)
DOI 10.11648/j.ajpst.20160202.15
Page(s) 47-53
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2017. Published by Science Publishing Group

Keywords

Inorganic Compounds, Chemical Synthesis, Adsorption, Preconcentration

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    Mauricio Guilherme Vieira, Angélica Machi Lazarin. (2017). Adsorption of Metallic Ions in Lamellar Crystalline Compounds Intercalated with Organic Molecules. American Journal of Polymer Science and Technology, 2(2), 47-53. https://doi.org/10.11648/j.ajpst.20160202.15

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    ACS Style

    Mauricio Guilherme Vieira; Angélica Machi Lazarin. Adsorption of Metallic Ions in Lamellar Crystalline Compounds Intercalated with Organic Molecules. Am. J. Polym. Sci. Technol. 2017, 2(2), 47-53. doi: 10.11648/j.ajpst.20160202.15

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    AMA Style

    Mauricio Guilherme Vieira, Angélica Machi Lazarin. Adsorption of Metallic Ions in Lamellar Crystalline Compounds Intercalated with Organic Molecules. Am J Polym Sci Technol. 2017;2(2):47-53. doi: 10.11648/j.ajpst.20160202.15

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  • @article{10.11648/j.ajpst.20160202.15,
      author = {Mauricio Guilherme Vieira and Angélica Machi Lazarin},
      title = {Adsorption of Metallic Ions in Lamellar Crystalline Compounds Intercalated with Organic Molecules},
      journal = {American Journal of Polymer Science and Technology},
      volume = {2},
      number = {2},
      pages = {47-53},
      doi = {10.11648/j.ajpst.20160202.15},
      url = {https://doi.org/10.11648/j.ajpst.20160202.15},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpst.20160202.15},
      abstract = {This work describes the synthesis and characterization of crystalline lamellar calcium phosphate intercalated with m-aminobenzoic acid (CaP/MABA), and results of a study of adsorption and preconcentration of Zn(II), Ni(II), Co(II) and Cu(II), and in ethanol medium. The adsorption isotherms from ethanol gave the maximum adsorption capacities of 1.43, 1.04, .030 and 0.19 mmol g-1 for copper, nickel, cobalt and zinc, respectively, which average stability constants followed Zn(II) > Ni(II) > Co(II) > Cu(II); the number of ligands was determined as four for both cations. The results obtained in flow experiments showed a retention and recovery of ca. 100% of the metal ion with packed CaP/MABA columns from solution containing a mixture of these cations.},
     year = {2017}
    }
    

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  • TY  - JOUR
    T1  - Adsorption of Metallic Ions in Lamellar Crystalline Compounds Intercalated with Organic Molecules
    AU  - Mauricio Guilherme Vieira
    AU  - Angélica Machi Lazarin
    Y1  - 2017/01/13
    PY  - 2017
    N1  - https://doi.org/10.11648/j.ajpst.20160202.15
    DO  - 10.11648/j.ajpst.20160202.15
    T2  - American Journal of Polymer Science and Technology
    JF  - American Journal of Polymer Science and Technology
    JO  - American Journal of Polymer Science and Technology
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    PB  - Science Publishing Group
    SN  - 2575-5986
    UR  - https://doi.org/10.11648/j.ajpst.20160202.15
    AB  - This work describes the synthesis and characterization of crystalline lamellar calcium phosphate intercalated with m-aminobenzoic acid (CaP/MABA), and results of a study of adsorption and preconcentration of Zn(II), Ni(II), Co(II) and Cu(II), and in ethanol medium. The adsorption isotherms from ethanol gave the maximum adsorption capacities of 1.43, 1.04, .030 and 0.19 mmol g-1 for copper, nickel, cobalt and zinc, respectively, which average stability constants followed Zn(II) > Ni(II) > Co(II) > Cu(II); the number of ligands was determined as four for both cations. The results obtained in flow experiments showed a retention and recovery of ca. 100% of the metal ion with packed CaP/MABA columns from solution containing a mixture of these cations.
    VL  - 2
    IS  - 2
    ER  - 

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Author Information
  • Department of Chemistry, State University of Maringá, Avenue Colombo, Maringá, PR, Brazil

  • Department of Chemistry, State University of Maringá, Avenue Colombo, Maringá, PR, Brazil

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