Application and Market of 1,4-butanediol Production of Reppe Method in China

Ping Luo; Xiaoding Li

doi:doi:10.11648/j.ajche.20210902.11

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Application and Market of 1,4-butanediol Production of Reppe Method in China

Ping Luo, Xiaoding Li

Published in American Journal of Chemical Engineering (Volume 9, Issue 2)

Received: 21 December 2020 Accepted: 9 March 2021 Published: 17 March 2021

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Abstract

The industrial production methods of 1,4-butanediol (BDO) are: maleic anhydride method (Davy-McKee), butadiene-acetic acid method (Mitsubishi Chemical), propylene oxide method (Lyondell), Reppe method, etc. Among these methods, only the Reppe process has achieved rapid development in China, with capacity far exceeding that of other petrochemical feedstock methods, because China has abundant mineral resources (e.g., coal and calcium carbide) where cheap feedstock is available for the production of 1,4-butanediol. There are three key steps in the production of 1, 4-butynediol by the Reppe method (methanol oxidation, alkynylation of formaldehyde and acetylene, and hydrogenation of 1, 4-butynediol). In recent years, Chinese enterprises have continuously explored and optimized these technologies introduced from abroad, and made some progress in process, equipment, catalyst, environmental protection and other related application technologies, which has promoted the technological progress of the industry. The latest statistical analysis is made on the application and market status of Reppe process for 1,4-butanediol production in China, and some opinions are put forward for the development of enterprises and 1,4-butanediol industry in the future, hoping to provide meaningful reference for the development of industry.

Published in	American Journal of Chemical Engineering (Volume 9, Issue 2)
DOI	10.11648/j.ajche.20210902.11
Page(s)	34-38
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2021. Published by Science Publishing Group

Keywords

1,4-Butanediol, Reppe Method, BDO, Technology and Application

References

[1]	Anfu, Zhou Shuli, Hui Quan. Development and Market Prospect of 1,4-butanediol [J]. Contemporary Petrochemical Industry, 2010, 5: 19.
[2]	National Coal Chemical Industry Information Station. Analysis of 1,4-butanediol Industry in China [J]. Coal Chemical Industry, 2011, 2: 4.
[3]	Shang Rujing, Mu Shifang, Niu Gang, et al. Market analysis of coal based 1,4-butanediol and its derivative fine chemicals [J]. Modern Chemical Industry, 2018, 38 (2): 11.
[4]	Xu Yongcheng, Xiao Dunfeng, Liu Guangzhi. Discussion on the technology of methanol oxidation to formaldehyde [J]. Chemical fertilizer design, 2012, 50 (3): 24~25.
[5]	Sun Jiguang. Analysis and Comparison of the Process technology of producing formaldehyde by electrolytic silver method and iron molybdenum method [J]. Chemical technology and development, 2012, 41 (5): 29.
[6]	Zhang Xiongbin, Lin Tao-hai, Deng Jiankang, et al. Industrial Application of EQ-101 iron-Molybdenum-Formaldehyde Synthesis Catalyst [J]. Coal chemical industry, 2019, 47 (1): 32.
[7]	Luo Ping, Deng Jiankang, Jiang Jijun, et al. Industrial application of synthesis of 1, 4-butynediol EQ-201 alkynating catalyst [J]. Coal chemical industry, 2019, 47 (6): 9.
[8]	Zhou Huanwen, Deng Shaoliang. A catalyst for the production of 1, 4-butynediol and its preparation method: China, CN103480382A [P].2014-01-01.
[9]	Tang Jiwei, Sun Jiguang, Li Xingyi. A gas burner for regenerating oxidation furnace with 1, 4-butynediol catalyst: China, CN202868677U [P]. 2013-04-10.
[10]	Xiao Ming. Research progress on synthesis of 1,4-butanediol by Reppe method [J]. Fine and Specialty Chemicals, 2019, 27 (4): 44.
[11]	Xu Yalin. Preparation of Ni/ Al₂O₃ Catalyst with high hydrothermal stability and Study on Hydrogenation of Butynediol [D]. Shanxi: Shanxi University, 2010.
[12]	Fang Zhiyong, LI Gaolin. Localization of low pressure Hydrogenation catalyst for 1,4-butanediol and its Industrial application [J]. Industrial catalysis, 2020, 28 (5): 69.
[13]	Wang Wei, Liang Qianqian, Tang Jialin. Production technology and market profile of 1,4-butanediol [J]. Chemical intermediates, 2006, 7: 20.
[14]	Cao Hongzhong. Route Selection and Analysis of 1,4-butanediol Process [J]. Coal and Chemical Industry, 2019, 42 (10): 123-128.
[15]	Sinopec Organic raw material Science and Technology Information Center station, BASF intends to shut down Japan 1,4-butanediol plant [J]. Petrochemical Technology and Economy, 2020, 5: 53.

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APA Style

Ping Luo, Xiaoding Li. (2021). Application and Market of 1,4-butanediol Production of Reppe Method in China. American Journal of Chemical Engineering, 9(2), 34-38. https://doi.org/10.11648/j.ajche.20210902.11

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ACS Style

Ping Luo; Xiaoding Li. Application and Market of 1,4-butanediol Production of Reppe Method in China. Am. J. Chem. Eng. 2021, 9(2), 34-38. doi: 10.11648/j.ajche.20210902.11

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AMA Style

Ping Luo, Xiaoding Li. Application and Market of 1,4-butanediol Production of Reppe Method in China. Am J Chem Eng. 2021;9(2):34-38. doi: 10.11648/j.ajche.20210902.11

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@article{10.11648/j.ajche.20210902.11,
  author = {Ping Luo and Xiaoding Li},
  title = {Application and Market of 1,4-butanediol Production of Reppe Method in China},
  journal = {American Journal of Chemical Engineering},
  volume = {9},
  number = {2},
  pages = {34-38},
  doi = {10.11648/j.ajche.20210902.11},
  url = {https://doi.org/10.11648/j.ajche.20210902.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajche.20210902.11},
  abstract = {The industrial production methods of 1,4-butanediol (BDO) are: maleic anhydride method (Davy-McKee), butadiene-acetic acid method (Mitsubishi Chemical), propylene oxide method (Lyondell), Reppe method, etc. Among these methods, only the Reppe process has achieved rapid development in China, with capacity far exceeding that of other petrochemical feedstock methods, because China has abundant mineral resources (e.g., coal and calcium carbide) where cheap feedstock is available for the production of 1,4-butanediol. There are three key steps in the production of 1, 4-butynediol by the Reppe method (methanol oxidation, alkynylation of formaldehyde and acetylene, and hydrogenation of 1, 4-butynediol). In recent years, Chinese enterprises have continuously explored and optimized these technologies introduced from abroad, and made some progress in process, equipment, catalyst, environmental protection and other related application technologies, which has promoted the technological progress of the industry. The latest statistical analysis is made on the application and market status of Reppe process for 1,4-butanediol production in China, and some opinions are put forward for the development of enterprises and 1,4-butanediol industry in the future, hoping to provide meaningful reference for the development of industry.},
 year = {2021}
}

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TY  - JOUR
T1  - Application and Market of 1,4-butanediol Production of Reppe Method in China
AU  - Ping Luo
AU  - Xiaoding Li
Y1  - 2021/03/17
PY  - 2021
N1  - https://doi.org/10.11648/j.ajche.20210902.11
DO  - 10.11648/j.ajche.20210902.11
T2  - American Journal of Chemical Engineering
JF  - American Journal of Chemical Engineering
JO  - American Journal of Chemical Engineering
SP  - 34
EP  - 38
PB  - Science Publishing Group
SN  - 2330-8613
UR  - https://doi.org/10.11648/j.ajche.20210902.11
AB  - The industrial production methods of 1,4-butanediol (BDO) are: maleic anhydride method (Davy-McKee), butadiene-acetic acid method (Mitsubishi Chemical), propylene oxide method (Lyondell), Reppe method, etc. Among these methods, only the Reppe process has achieved rapid development in China, with capacity far exceeding that of other petrochemical feedstock methods, because China has abundant mineral resources (e.g., coal and calcium carbide) where cheap feedstock is available for the production of 1,4-butanediol. There are three key steps in the production of 1, 4-butynediol by the Reppe method (methanol oxidation, alkynylation of formaldehyde and acetylene, and hydrogenation of 1, 4-butynediol). In recent years, Chinese enterprises have continuously explored and optimized these technologies introduced from abroad, and made some progress in process, equipment, catalyst, environmental protection and other related application technologies, which has promoted the technological progress of the industry. The latest statistical analysis is made on the application and market status of Reppe process for 1,4-butanediol production in China, and some opinions are put forward for the development of enterprises and 1,4-butanediol industry in the future, hoping to provide meaningful reference for the development of industry.
VL  - 9
IS  - 2
ER  -

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Author Information

Ping Luo

Haiso Technology Co., Ltd., Wuhan, China
Xiaoding Li

Haiso Technology Co., Ltd., Wuhan, China

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Plain Text BibTeX RIS

APA Style

Ping Luo, Xiaoding Li. (2021). Application and Market of 1,4-butanediol Production of Reppe Method in China. American Journal of Chemical Engineering, 9(2), 34-38. https://doi.org/10.11648/j.ajche.20210902.11

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ACS Style

Ping Luo; Xiaoding Li. Application and Market of 1,4-butanediol Production of Reppe Method in China. Am. J. Chem. Eng. 2021, 9(2), 34-38. doi: 10.11648/j.ajche.20210902.11

Copy | Download

AMA Style

Ping Luo, Xiaoding Li. Application and Market of 1,4-butanediol Production of Reppe Method in China. Am J Chem Eng. 2021;9(2):34-38. doi: 10.11648/j.ajche.20210902.11

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@article{10.11648/j.ajche.20210902.11,
  author = {Ping Luo and Xiaoding Li},
  title = {Application and Market of 1,4-butanediol Production of Reppe Method in China},
  journal = {American Journal of Chemical Engineering},
  volume = {9},
  number = {2},
  pages = {34-38},
  doi = {10.11648/j.ajche.20210902.11},
  url = {https://doi.org/10.11648/j.ajche.20210902.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajche.20210902.11},
  abstract = {The industrial production methods of 1,4-butanediol (BDO) are: maleic anhydride method (Davy-McKee), butadiene-acetic acid method (Mitsubishi Chemical), propylene oxide method (Lyondell), Reppe method, etc. Among these methods, only the Reppe process has achieved rapid development in China, with capacity far exceeding that of other petrochemical feedstock methods, because China has abundant mineral resources (e.g., coal and calcium carbide) where cheap feedstock is available for the production of 1,4-butanediol. There are three key steps in the production of 1, 4-butynediol by the Reppe method (methanol oxidation, alkynylation of formaldehyde and acetylene, and hydrogenation of 1, 4-butynediol). In recent years, Chinese enterprises have continuously explored and optimized these technologies introduced from abroad, and made some progress in process, equipment, catalyst, environmental protection and other related application technologies, which has promoted the technological progress of the industry. The latest statistical analysis is made on the application and market status of Reppe process for 1,4-butanediol production in China, and some opinions are put forward for the development of enterprises and 1,4-butanediol industry in the future, hoping to provide meaningful reference for the development of industry.},
 year = {2021}
}

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TY  - JOUR
T1  - Application and Market of 1,4-butanediol Production of Reppe Method in China
AU  - Ping Luo
AU  - Xiaoding Li
Y1  - 2021/03/17
PY  - 2021
N1  - https://doi.org/10.11648/j.ajche.20210902.11
DO  - 10.11648/j.ajche.20210902.11
T2  - American Journal of Chemical Engineering
JF  - American Journal of Chemical Engineering
JO  - American Journal of Chemical Engineering
SP  - 34
EP  - 38
PB  - Science Publishing Group
SN  - 2330-8613
UR  - https://doi.org/10.11648/j.ajche.20210902.11
AB  - The industrial production methods of 1,4-butanediol (BDO) are: maleic anhydride method (Davy-McKee), butadiene-acetic acid method (Mitsubishi Chemical), propylene oxide method (Lyondell), Reppe method, etc. Among these methods, only the Reppe process has achieved rapid development in China, with capacity far exceeding that of other petrochemical feedstock methods, because China has abundant mineral resources (e.g., coal and calcium carbide) where cheap feedstock is available for the production of 1,4-butanediol. There are three key steps in the production of 1, 4-butynediol by the Reppe method (methanol oxidation, alkynylation of formaldehyde and acetylene, and hydrogenation of 1, 4-butynediol). In recent years, Chinese enterprises have continuously explored and optimized these technologies introduced from abroad, and made some progress in process, equipment, catalyst, environmental protection and other related application technologies, which has promoted the technological progress of the industry. The latest statistical analysis is made on the application and market status of Reppe process for 1,4-butanediol production in China, and some opinions are put forward for the development of enterprises and 1,4-butanediol industry in the future, hoping to provide meaningful reference for the development of industry.
VL  - 9
IS  - 2
ER  -

Copy | Download