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Supercritical Adsorption Based CO2 Capture from N2/CO2 Mixture by Activated Carbon and Carbon Molecular Sieve

Received: 10 May 2017     Published: 10 May 2017
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Abstract

The adsorption equilibria of pure supercritical N2 and CO2 on the activated carbon Yigao-A and carbon molecular sieve CMS-200 were measured by the gravimetric method (IGA-001, Hiden) in the temperature region of 313.15-393.15 K and pressure region of 0-2 MPa. The adsorption kinetics of N2 and of CO2 on the activated carbon Yigao-A and carbon molecular sieve CMS-200 at 313.15 K in 50 kPa were tested. The Langmuir-Freundlich model was applied to analyze the adsorption isotherms. The adsorption kinetics was investigated with the Fickian model. The analysis of adsorption equilibria showed that a high temperature, low pressure is beneficial to the equilibria based selective adsorption of supercritical CO2 on the activated carbon Yigao-A and carbon molecular sieve CMS-200. The investigation of adsorption kinetics exposed that the carbon molecular sieve CMS-200 is able to separate CO2 from the N2/CO2 mixture by its kinetic effect, and lower temperature is preferred.

Published in American Journal of Chemical Engineering (Volume 5, Issue 3)
DOI 10.11648/j.ajche.20170503.11
Page(s) 27-36
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2017. Published by Science Publishing Group

Keywords

Supercritical Adsorption, CO2 Capture, Activated Carbon, Carbon Molecular Sieve

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  • APA Style

    Kuerbanjiang Nuermaiti, Ming Li. (2017). Supercritical Adsorption Based CO2 Capture from N2/CO2 Mixture by Activated Carbon and Carbon Molecular Sieve. American Journal of Chemical Engineering, 5(3), 27-36. https://doi.org/10.11648/j.ajche.20170503.11

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    ACS Style

    Kuerbanjiang Nuermaiti; Ming Li. Supercritical Adsorption Based CO2 Capture from N2/CO2 Mixture by Activated Carbon and Carbon Molecular Sieve. Am. J. Chem. Eng. 2017, 5(3), 27-36. doi: 10.11648/j.ajche.20170503.11

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    AMA Style

    Kuerbanjiang Nuermaiti, Ming Li. Supercritical Adsorption Based CO2 Capture from N2/CO2 Mixture by Activated Carbon and Carbon Molecular Sieve. Am J Chem Eng. 2017;5(3):27-36. doi: 10.11648/j.ajche.20170503.11

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  • @article{10.11648/j.ajche.20170503.11,
      author = {Kuerbanjiang Nuermaiti and Ming Li},
      title = {Supercritical Adsorption Based CO2 Capture from N2/CO2 Mixture by Activated Carbon and Carbon Molecular Sieve},
      journal = {American Journal of Chemical Engineering},
      volume = {5},
      number = {3},
      pages = {27-36},
      doi = {10.11648/j.ajche.20170503.11},
      url = {https://doi.org/10.11648/j.ajche.20170503.11},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajche.20170503.11},
      abstract = {The adsorption equilibria of pure supercritical N2 and CO2 on the activated carbon Yigao-A and carbon molecular sieve CMS-200 were measured by the gravimetric method (IGA-001, Hiden) in the temperature region of 313.15-393.15 K and pressure region of 0-2 MPa. The adsorption kinetics of N2 and of CO2 on the activated carbon Yigao-A and carbon molecular sieve CMS-200 at 313.15 K in 50 kPa were tested. The Langmuir-Freundlich model was applied to analyze the adsorption isotherms. The adsorption kinetics was investigated with the Fickian model. The analysis of adsorption equilibria showed that a high temperature, low pressure is beneficial to the equilibria based selective adsorption of supercritical CO2 on the activated carbon Yigao-A and carbon molecular sieve CMS-200. The investigation of adsorption kinetics exposed that the carbon molecular sieve CMS-200 is able to separate CO2 from the N2/CO2 mixture by its kinetic effect, and lower temperature is preferred.},
     year = {2017}
    }
    

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  • TY  - JOUR
    T1  - Supercritical Adsorption Based CO2 Capture from N2/CO2 Mixture by Activated Carbon and Carbon Molecular Sieve
    AU  - Kuerbanjiang Nuermaiti
    AU  - Ming Li
    Y1  - 2017/05/10
    PY  - 2017
    N1  - https://doi.org/10.11648/j.ajche.20170503.11
    DO  - 10.11648/j.ajche.20170503.11
    T2  - American Journal of Chemical Engineering
    JF  - American Journal of Chemical Engineering
    JO  - American Journal of Chemical Engineering
    SP  - 27
    EP  - 36
    PB  - Science Publishing Group
    SN  - 2330-8613
    UR  - https://doi.org/10.11648/j.ajche.20170503.11
    AB  - The adsorption equilibria of pure supercritical N2 and CO2 on the activated carbon Yigao-A and carbon molecular sieve CMS-200 were measured by the gravimetric method (IGA-001, Hiden) in the temperature region of 313.15-393.15 K and pressure region of 0-2 MPa. The adsorption kinetics of N2 and of CO2 on the activated carbon Yigao-A and carbon molecular sieve CMS-200 at 313.15 K in 50 kPa were tested. The Langmuir-Freundlich model was applied to analyze the adsorption isotherms. The adsorption kinetics was investigated with the Fickian model. The analysis of adsorption equilibria showed that a high temperature, low pressure is beneficial to the equilibria based selective adsorption of supercritical CO2 on the activated carbon Yigao-A and carbon molecular sieve CMS-200. The investigation of adsorption kinetics exposed that the carbon molecular sieve CMS-200 is able to separate CO2 from the N2/CO2 mixture by its kinetic effect, and lower temperature is preferred.
    VL  - 5
    IS  - 3
    ER  - 

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Author Information
  • College of Chemistry and Environmental Science, Kashgar University, Kashgar, China

  • School of Chemical Science and Engineering, Tongji University, Shanghai, China

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