Use of Hydrous Manganese Oxides Nanopowders as a Potential Sorbent for Selective Removal of Nickel Ions from Industrial Waste Water, Kinetics and Isotherm Studies

R. Ghaniem; Y. A. El-Taweil; M. E. Ossman

doi:doi:10.11648/j.ajche.20160406.15

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Use of Hydrous Manganese Oxides Nanopowders as a Potential Sorbent for Selective Removal of Nickel Ions from Industrial Waste Water, Kinetics and Isotherm Studies

R. Ghaniem, Y. A. El-Taweil, M. E. Ossman

Published in American Journal of Chemical Engineering (Volume 4, Issue 6)

Received: 19 November 2016 Accepted: 1 December 2016 Published: 12 January 2017

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Abstract

Hydrous Manganese Oxides Nanopowders as nano adsorbent (MONs) was synthesized and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and transform infrared spectroscopy (FT-IR). The adsorption of Ni (II) ions from aqueous solution on the MONs was investigated with variations in contact time, pH, initial Ni (II) concentration and adsorbent dosage. The results showed that the adsorption of Ni (II) onto MONs increased within 25 min and reached equilibrium gradually and removal percentage were 83%, 57%, 42% and 35% for 25 ppm, 50 ppm, 75 ppm and 100 ppm Ni (II), respectively, by using 1g/l MONs for 90 min at pH 6. The adsorption behavior of Ni (II) onto MONs was best described by the pseudo-second-order model and Freundlish isotherm. The results also indicated that the type of adsorption involved in this study is physiosorption (physical sorption) which usually takes place at low temperature. The results also revealed that MONs was a promising adsorbent for removal of Ni ions from industrial wastewater.

Published in	American Journal of Chemical Engineering (Volume 4, Issue 6)
DOI	10.11648/j.ajche.20160406.15
Page(s)	170-178
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2017. Published by Science Publishing Group

Keywords

Manganese Oxides, Nickel, Adsorption, Metal Oxides, Nano Adsorbent

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R. Ghaniem, Y. A. El-Taweil, M. E. Ossman. (2017). Use of Hydrous Manganese Oxides Nanopowders as a Potential Sorbent for Selective Removal of Nickel Ions from Industrial Waste Water, Kinetics and Isotherm Studies. American Journal of Chemical Engineering, 4(6), 170-178. https://doi.org/10.11648/j.ajche.20160406.15

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ACS Style

R. Ghaniem; Y. A. El-Taweil; M. E. Ossman. Use of Hydrous Manganese Oxides Nanopowders as a Potential Sorbent for Selective Removal of Nickel Ions from Industrial Waste Water, Kinetics and Isotherm Studies. Am. J. Chem. Eng. 2017, 4(6), 170-178. doi: 10.11648/j.ajche.20160406.15

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AMA Style

R. Ghaniem, Y. A. El-Taweil, M. E. Ossman. Use of Hydrous Manganese Oxides Nanopowders as a Potential Sorbent for Selective Removal of Nickel Ions from Industrial Waste Water, Kinetics and Isotherm Studies. Am J Chem Eng. 2017;4(6):170-178. doi: 10.11648/j.ajche.20160406.15

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@article{10.11648/j.ajche.20160406.15,
  author = {R. Ghaniem and Y. A. El-Taweil and M. E. Ossman},
  title = {Use of Hydrous Manganese Oxides Nanopowders as a Potential Sorbent for Selective Removal of Nickel Ions from Industrial Waste Water, Kinetics and Isotherm Studies},
  journal = {American Journal of Chemical Engineering},
  volume = {4},
  number = {6},
  pages = {170-178},
  doi = {10.11648/j.ajche.20160406.15},
  url = {https://doi.org/10.11648/j.ajche.20160406.15},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajche.20160406.15},
  abstract = {Hydrous Manganese Oxides Nanopowders as nano adsorbent (MONs) was synthesized and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and transform infrared spectroscopy (FT-IR). The adsorption of Ni (II) ions from aqueous solution on the MONs was investigated with variations in contact time, pH, initial Ni (II) concentration and adsorbent dosage. The results showed that the adsorption of Ni (II) onto MONs increased within 25 min and reached equilibrium gradually and removal percentage were 83%, 57%, 42% and 35% for 25 ppm, 50 ppm, 75 ppm and 100 ppm Ni (II), respectively, by using 1g/l MONs for 90 min at pH 6. The adsorption behavior of Ni (II) onto MONs was best described by the pseudo-second-order model and Freundlish isotherm. The results also indicated that the type of adsorption involved in this study is physiosorption (physical sorption) which usually takes place at low temperature. The results also revealed that MONs was a promising adsorbent for removal of Ni ions from industrial wastewater.},
 year = {2017}
}

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TY - JOUR
T1 - Use of Hydrous Manganese Oxides Nanopowders as a Potential Sorbent for Selective Removal of Nickel Ions from Industrial Waste Water, Kinetics and Isotherm Studies
AU - R. Ghaniem
AU - Y. A. El-Taweil
AU - M. E. Ossman
Y1 - 2017/01/12
PY - 2017
N1 - https://doi.org/10.11648/j.ajche.20160406.15
DO - 10.11648/j.ajche.20160406.15
T2 - American Journal of Chemical Engineering
JF - American Journal of Chemical Engineering
JO - American Journal of Chemical Engineering
SP - 170
EP - 178
PB - Science Publishing Group
SN - 2330-8613
UR - https://doi.org/10.11648/j.ajche.20160406.15
AB - Hydrous Manganese Oxides Nanopowders as nano adsorbent (MONs) was synthesized and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and transform infrared spectroscopy (FT-IR). The adsorption of Ni (II) ions from aqueous solution on the MONs was investigated with variations in contact time, pH, initial Ni (II) concentration and adsorbent dosage. The results showed that the adsorption of Ni (II) onto MONs increased within 25 min and reached equilibrium gradually and removal percentage were 83%, 57%, 42% and 35% for 25 ppm, 50 ppm, 75 ppm and 100 ppm Ni (II), respectively, by using 1g/l MONs for 90 min at pH 6. The adsorption behavior of Ni (II) onto MONs was best described by the pseudo-second-order model and Freundlish isotherm. The results also indicated that the type of adsorption involved in this study is physiosorption (physical sorption) which usually takes place at low temperature. The results also revealed that MONs was a promising adsorbent for removal of Ni ions from industrial wastewater.
VL - 4
IS - 6
ER -

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Author Information

R. Ghaniem

Chemical Engineering Department, Alexandria University, Alexandria, Egypt
Y. A. El-Taweil

Chemical Engineering Department, Alexandria University, Alexandria, Egypt
M. E. Ossman

Petrochemical Engineering Department, Pharos University, PUA, Alexandria, Egypt

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R. Ghaniem, Y. A. El-Taweil, M. E. Ossman. (2017). Use of Hydrous Manganese Oxides Nanopowders as a Potential Sorbent for Selective Removal of Nickel Ions from Industrial Waste Water, Kinetics and Isotherm Studies. American Journal of Chemical Engineering, 4(6), 170-178. https://doi.org/10.11648/j.ajche.20160406.15

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ACS Style

R. Ghaniem; Y. A. El-Taweil; M. E. Ossman. Use of Hydrous Manganese Oxides Nanopowders as a Potential Sorbent for Selective Removal of Nickel Ions from Industrial Waste Water, Kinetics and Isotherm Studies. Am. J. Chem. Eng. 2017, 4(6), 170-178. doi: 10.11648/j.ajche.20160406.15

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AMA Style

R. Ghaniem, Y. A. El-Taweil, M. E. Ossman. Use of Hydrous Manganese Oxides Nanopowders as a Potential Sorbent for Selective Removal of Nickel Ions from Industrial Waste Water, Kinetics and Isotherm Studies. Am J Chem Eng. 2017;4(6):170-178. doi: 10.11648/j.ajche.20160406.15

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@article{10.11648/j.ajche.20160406.15,
  author = {R. Ghaniem and Y. A. El-Taweil and M. E. Ossman},
  title = {Use of Hydrous Manganese Oxides Nanopowders as a Potential Sorbent for Selective Removal of Nickel Ions from Industrial Waste Water, Kinetics and Isotherm Studies},
  journal = {American Journal of Chemical Engineering},
  volume = {4},
  number = {6},
  pages = {170-178},
  doi = {10.11648/j.ajche.20160406.15},
  url = {https://doi.org/10.11648/j.ajche.20160406.15},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajche.20160406.15},
  abstract = {Hydrous Manganese Oxides Nanopowders as nano adsorbent (MONs) was synthesized and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and transform infrared spectroscopy (FT-IR). The adsorption of Ni (II) ions from aqueous solution on the MONs was investigated with variations in contact time, pH, initial Ni (II) concentration and adsorbent dosage. The results showed that the adsorption of Ni (II) onto MONs increased within 25 min and reached equilibrium gradually and removal percentage were 83%, 57%, 42% and 35% for 25 ppm, 50 ppm, 75 ppm and 100 ppm Ni (II), respectively, by using 1g/l MONs for 90 min at pH 6. The adsorption behavior of Ni (II) onto MONs was best described by the pseudo-second-order model and Freundlish isotherm. The results also indicated that the type of adsorption involved in this study is physiosorption (physical sorption) which usually takes place at low temperature. The results also revealed that MONs was a promising adsorbent for removal of Ni ions from industrial wastewater.},
 year = {2017}
}

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