Generalized Model of Adsorption Equilibria Prediction for CO<sub>2</sub> on Carbonaceous Adsorbents

Kuerbanjiang Nuermaiti; Ming Li

doi:doi:10.11648/j.ajche.20160402.13

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Generalized Model of Adsorption Equilibria Prediction for CO₂ on Carbonaceous Adsorbents

Kuerbanjiang Nuermaiti, Ming Li

Published in American Journal of Chemical Engineering (Volume 4, Issue 2)

Received: 8 April 2016 Published: 9 April 2016

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Abstract

The carbon molecular sieve CMS-200 and activated carbon Yigao-A have been adopted as adsorbents for the study of CO₂ adsorption capture. The pore size distributions of both adsorbents were characterized by the modified H-K method. Adsorption isotherms of CO₂ on the carbon molecular sieve CMS-200 and activated carbon Yigao-A were measured by the gravimetric method (Hiden, IGA-001) in the temperature region of 253.15-393.15 K and pressure region of 0-2 MPa. The Henry’s law constants of adsorption equilibria for CO₂ were estimated using the Virial equation. The Ruthven’s generalized model was applied to analyze the experimental data on the basis of the values of the Henry’s law constants. The investigation demonstrates that the Ruthven’s generalized model not only is useful to describe the adsorption equilibria for CO₂ on non-porous homogeneous carbonaceous adsorbents in the subcritical region, but also is reliable to predict the adsorption equilibrium data for CO₂ on carbonaceous adsorbents with the uniform pore size distribution and the wide pore size distribution from the subcritical region to the supercritical region.

Published in	American Journal of Chemical Engineering (Volume 4, Issue 2)
DOI	10.11648/j.ajche.20160402.13
Page(s)	46-51
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2016. Published by Science Publishing Group

Keywords

CO₂, Adsorption, Prediction, Henry’s Law Constant, Generalized Model

References

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Kuerbanjiang Nuermaiti, Ming Li. (2016). Generalized Model of Adsorption Equilibria Prediction for CO2 on Carbonaceous Adsorbents. American Journal of Chemical Engineering, 4(2), 46-51. https://doi.org/10.11648/j.ajche.20160402.13

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Kuerbanjiang Nuermaiti; Ming Li. Generalized Model of Adsorption Equilibria Prediction for CO2 on Carbonaceous Adsorbents. Am. J. Chem. Eng. 2016, 4(2), 46-51. doi: 10.11648/j.ajche.20160402.13

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AMA Style

Kuerbanjiang Nuermaiti, Ming Li. Generalized Model of Adsorption Equilibria Prediction for CO2 on Carbonaceous Adsorbents. Am J Chem Eng. 2016;4(2):46-51. doi: 10.11648/j.ajche.20160402.13

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@article{10.11648/j.ajche.20160402.13,
  author = {Kuerbanjiang Nuermaiti and Ming Li},
  title = {Generalized Model of Adsorption Equilibria Prediction for CO2 on Carbonaceous Adsorbents},
  journal = {American Journal of Chemical Engineering},
  volume = {4},
  number = {2},
  pages = {46-51},
  doi = {10.11648/j.ajche.20160402.13},
  url = {https://doi.org/10.11648/j.ajche.20160402.13},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajche.20160402.13},
  abstract = {The carbon molecular sieve CMS-200 and activated carbon Yigao-A have been adopted as adsorbents for the study of CO2 adsorption capture. The pore size distributions of both adsorbents were characterized by the modified H-K method. Adsorption isotherms of CO2 on the carbon molecular sieve CMS-200 and activated carbon Yigao-A were measured by the gravimetric method (Hiden, IGA-001) in the temperature region of 253.15-393.15 K and pressure region of 0-2 MPa. The Henry’s law constants of adsorption equilibria for CO2 were estimated using the Virial equation. The Ruthven’s generalized model was applied to analyze the experimental data on the basis of the values of the Henry’s law constants. The investigation demonstrates that the Ruthven’s generalized model not only is useful to describe the adsorption equilibria for CO2 on non-porous homogeneous carbonaceous adsorbents in the subcritical region, but also is reliable to predict the adsorption equilibrium data for CO2 on carbonaceous adsorbents with the uniform pore size distribution and the wide pore size distribution from the subcritical region to the supercritical region.},
 year = {2016}
}

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TY  - JOUR
T1  - Generalized Model of Adsorption Equilibria Prediction for CO2 on Carbonaceous Adsorbents
AU  - Kuerbanjiang Nuermaiti
AU  - Ming Li
Y1  - 2016/04/09
PY  - 2016
N1  - https://doi.org/10.11648/j.ajche.20160402.13
DO  - 10.11648/j.ajche.20160402.13
T2  - American Journal of Chemical Engineering
JF  - American Journal of Chemical Engineering
JO  - American Journal of Chemical Engineering
SP  - 46
EP  - 51
PB  - Science Publishing Group
SN  - 2330-8613
UR  - https://doi.org/10.11648/j.ajche.20160402.13
AB  - The carbon molecular sieve CMS-200 and activated carbon Yigao-A have been adopted as adsorbents for the study of CO2 adsorption capture. The pore size distributions of both adsorbents were characterized by the modified H-K method. Adsorption isotherms of CO2 on the carbon molecular sieve CMS-200 and activated carbon Yigao-A were measured by the gravimetric method (Hiden, IGA-001) in the temperature region of 253.15-393.15 K and pressure region of 0-2 MPa. The Henry’s law constants of adsorption equilibria for CO2 were estimated using the Virial equation. The Ruthven’s generalized model was applied to analyze the experimental data on the basis of the values of the Henry’s law constants. The investigation demonstrates that the Ruthven’s generalized model not only is useful to describe the adsorption equilibria for CO2 on non-porous homogeneous carbonaceous adsorbents in the subcritical region, but also is reliable to predict the adsorption equilibrium data for CO2 on carbonaceous adsorbents with the uniform pore size distribution and the wide pore size distribution from the subcritical region to the supercritical region.
VL  - 4
IS  - 2
ER  -

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Author Information

Kuerbanjiang Nuermaiti

Department of Chemistry, Tongji University, Shanghai, China
Ming Li

Department of Chemistry, Tongji University, Shanghai, China

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APA Style

Kuerbanjiang Nuermaiti, Ming Li. (2016). Generalized Model of Adsorption Equilibria Prediction for CO2 on Carbonaceous Adsorbents. American Journal of Chemical Engineering, 4(2), 46-51. https://doi.org/10.11648/j.ajche.20160402.13

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ACS Style

Kuerbanjiang Nuermaiti; Ming Li. Generalized Model of Adsorption Equilibria Prediction for CO2 on Carbonaceous Adsorbents. Am. J. Chem. Eng. 2016, 4(2), 46-51. doi: 10.11648/j.ajche.20160402.13

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AMA Style

Kuerbanjiang Nuermaiti, Ming Li. Generalized Model of Adsorption Equilibria Prediction for CO2 on Carbonaceous Adsorbents. Am J Chem Eng. 2016;4(2):46-51. doi: 10.11648/j.ajche.20160402.13

Copy | Download

@article{10.11648/j.ajche.20160402.13,
  author = {Kuerbanjiang Nuermaiti and Ming Li},
  title = {Generalized Model of Adsorption Equilibria Prediction for CO2 on Carbonaceous Adsorbents},
  journal = {American Journal of Chemical Engineering},
  volume = {4},
  number = {2},
  pages = {46-51},
  doi = {10.11648/j.ajche.20160402.13},
  url = {https://doi.org/10.11648/j.ajche.20160402.13},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajche.20160402.13},
  abstract = {The carbon molecular sieve CMS-200 and activated carbon Yigao-A have been adopted as adsorbents for the study of CO2 adsorption capture. The pore size distributions of both adsorbents were characterized by the modified H-K method. Adsorption isotherms of CO2 on the carbon molecular sieve CMS-200 and activated carbon Yigao-A were measured by the gravimetric method (Hiden, IGA-001) in the temperature region of 253.15-393.15 K and pressure region of 0-2 MPa. The Henry’s law constants of adsorption equilibria for CO2 were estimated using the Virial equation. The Ruthven’s generalized model was applied to analyze the experimental data on the basis of the values of the Henry’s law constants. The investigation demonstrates that the Ruthven’s generalized model not only is useful to describe the adsorption equilibria for CO2 on non-porous homogeneous carbonaceous adsorbents in the subcritical region, but also is reliable to predict the adsorption equilibrium data for CO2 on carbonaceous adsorbents with the uniform pore size distribution and the wide pore size distribution from the subcritical region to the supercritical region.},
 year = {2016}
}

Copy | Download

TY  - JOUR
T1  - Generalized Model of Adsorption Equilibria Prediction for CO2 on Carbonaceous Adsorbents
AU  - Kuerbanjiang Nuermaiti
AU  - Ming Li
Y1  - 2016/04/09
PY  - 2016
N1  - https://doi.org/10.11648/j.ajche.20160402.13
DO  - 10.11648/j.ajche.20160402.13
T2  - American Journal of Chemical Engineering
JF  - American Journal of Chemical Engineering
JO  - American Journal of Chemical Engineering
SP  - 46
EP  - 51
PB  - Science Publishing Group
SN  - 2330-8613
UR  - https://doi.org/10.11648/j.ajche.20160402.13
AB  - The carbon molecular sieve CMS-200 and activated carbon Yigao-A have been adopted as adsorbents for the study of CO2 adsorption capture. The pore size distributions of both adsorbents were characterized by the modified H-K method. Adsorption isotherms of CO2 on the carbon molecular sieve CMS-200 and activated carbon Yigao-A were measured by the gravimetric method (Hiden, IGA-001) in the temperature region of 253.15-393.15 K and pressure region of 0-2 MPa. The Henry’s law constants of adsorption equilibria for CO2 were estimated using the Virial equation. The Ruthven’s generalized model was applied to analyze the experimental data on the basis of the values of the Henry’s law constants. The investigation demonstrates that the Ruthven’s generalized model not only is useful to describe the adsorption equilibria for CO2 on non-porous homogeneous carbonaceous adsorbents in the subcritical region, but also is reliable to predict the adsorption equilibrium data for CO2 on carbonaceous adsorbents with the uniform pore size distribution and the wide pore size distribution from the subcritical region to the supercritical region.
VL  - 4
IS  - 2
ER  -

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