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Synthesis and Structural Characterization of New Ladder Organostannoxanes Derived from Sulfonic Acid Derivatives

Received: 16 February 2022     Accepted: 7 March 2022     Published: 15 March 2022
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Abstract

Two new ladder n-dibutyltin(IV) compounds with general formulae [n-Bu2Sn]4(μ3-O)2(μ2-OH)2(OSO2R)2 with R=4-HO-C6H4-(1) and CH3-(2) have been synthetized and characterized by elemental analysis, FT-IR, 1H NMR and Mass spectroscopies techniques as well as single crystal X-ray diffraction study. The complex 1 crystallizes in the triclinic space group P1 with a=12.808 (8), b=15.391 (9), c=15.803 (10) Å, α=87.910 (5), β=66.650 (6), γ=80.283 (5)°, V=2817.6 (3) Å3 and Z=1. The crystal structure reveal them to be tetranuclear tin (IV) ladder-like structure containing two deprotonated ligands an three-rung-staircase Sn4O4 core. The structure is a centro-symmetric dimer of an oxoditin (IV) unit having a central four-member ring. In this complex, the central tin (IV) atoms are pentacoordinated, where the sulfonate base acts as monodentate ligands. Supramolecular architecture is formed by extensive hydrogen-bonding interactions, O-H…O.

Published in American Journal of Applied Chemistry (Volume 10, Issue 2)
DOI 10.11648/j.ajac.20221002.11
Page(s) 38-42
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This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2022. Published by Science Publishing Group

Keywords

Organostannoxane, Pyridine-3-sulfonate, 4-hydroxylbenzenesulfonate, Tetranuclear Ladder

References
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    Tidiane Diop, Adrienne Ndiolene, Mouhamadou Abdoulaye Diallo, Daouda Ndoye. (2022). Synthesis and Structural Characterization of New Ladder Organostannoxanes Derived from Sulfonic Acid Derivatives. American Journal of Applied Chemistry, 10(2), 38-42. https://doi.org/10.11648/j.ajac.20221002.11

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    ACS Style

    Tidiane Diop; Adrienne Ndiolene; Mouhamadou Abdoulaye Diallo; Daouda Ndoye. Synthesis and Structural Characterization of New Ladder Organostannoxanes Derived from Sulfonic Acid Derivatives. Am. J. Appl. Chem. 2022, 10(2), 38-42. doi: 10.11648/j.ajac.20221002.11

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    AMA Style

    Tidiane Diop, Adrienne Ndiolene, Mouhamadou Abdoulaye Diallo, Daouda Ndoye. Synthesis and Structural Characterization of New Ladder Organostannoxanes Derived from Sulfonic Acid Derivatives. Am J Appl Chem. 2022;10(2):38-42. doi: 10.11648/j.ajac.20221002.11

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  • @article{10.11648/j.ajac.20221002.11,
      author = {Tidiane Diop and Adrienne Ndiolene and Mouhamadou Abdoulaye Diallo and Daouda Ndoye},
      title = {Synthesis and Structural Characterization of New Ladder Organostannoxanes Derived from Sulfonic Acid Derivatives},
      journal = {American Journal of Applied Chemistry},
      volume = {10},
      number = {2},
      pages = {38-42},
      doi = {10.11648/j.ajac.20221002.11},
      url = {https://doi.org/10.11648/j.ajac.20221002.11},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20221002.11},
      abstract = {Two new ladder n-dibutyltin(IV) compounds with general formulae [n-Bu2Sn]4(μ3-O)2(μ2-OH)2(OSO2R)2 with R=4-HO-C6H4-(1) and CH3-(2) have been synthetized and characterized by elemental analysis, FT-IR, 1H NMR and Mass spectroscopies techniques as well as single crystal X-ray diffraction study. The complex 1 crystallizes in the triclinic space group P1 with a=12.808 (8), b=15.391 (9), c=15.803 (10) Å, α=87.910 (5), β=66.650 (6), γ=80.283 (5)°, V=2817.6 (3) Å3 and Z=1. The crystal structure reveal them to be tetranuclear tin (IV) ladder-like structure containing two deprotonated ligands an three-rung-staircase Sn4O4 core. The structure is a centro-symmetric dimer of an oxoditin (IV) unit having a central four-member ring. In this complex, the central tin (IV) atoms are pentacoordinated, where the sulfonate base acts as monodentate ligands. Supramolecular architecture is formed by extensive hydrogen-bonding interactions, O-H…O.},
     year = {2022}
    }
    

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  • TY  - JOUR
    T1  - Synthesis and Structural Characterization of New Ladder Organostannoxanes Derived from Sulfonic Acid Derivatives
    AU  - Tidiane Diop
    AU  - Adrienne Ndiolene
    AU  - Mouhamadou Abdoulaye Diallo
    AU  - Daouda Ndoye
    Y1  - 2022/03/15
    PY  - 2022
    N1  - https://doi.org/10.11648/j.ajac.20221002.11
    DO  - 10.11648/j.ajac.20221002.11
    T2  - American Journal of Applied Chemistry
    JF  - American Journal of Applied Chemistry
    JO  - American Journal of Applied Chemistry
    SP  - 38
    EP  - 42
    PB  - Science Publishing Group
    SN  - 2330-8745
    UR  - https://doi.org/10.11648/j.ajac.20221002.11
    AB  - Two new ladder n-dibutyltin(IV) compounds with general formulae [n-Bu2Sn]4(μ3-O)2(μ2-OH)2(OSO2R)2 with R=4-HO-C6H4-(1) and CH3-(2) have been synthetized and characterized by elemental analysis, FT-IR, 1H NMR and Mass spectroscopies techniques as well as single crystal X-ray diffraction study. The complex 1 crystallizes in the triclinic space group P1 with a=12.808 (8), b=15.391 (9), c=15.803 (10) Å, α=87.910 (5), β=66.650 (6), γ=80.283 (5)°, V=2817.6 (3) Å3 and Z=1. The crystal structure reveal them to be tetranuclear tin (IV) ladder-like structure containing two deprotonated ligands an three-rung-staircase Sn4O4 core. The structure is a centro-symmetric dimer of an oxoditin (IV) unit having a central four-member ring. In this complex, the central tin (IV) atoms are pentacoordinated, where the sulfonate base acts as monodentate ligands. Supramolecular architecture is formed by extensive hydrogen-bonding interactions, O-H…O.
    VL  - 10
    IS  - 2
    ER  - 

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Author Information
  • Inorganic and Analytical Chemistry Laboratory, Department of Chemistry, Faculty of Science and Technology, Cheikh Anta Diop University, Dakar, Senegal

  • Inorganic and Analytical Chemistry Laboratory, Department of Chemistry, Faculty of Science and Technology, Cheikh Anta Diop University, Dakar, Senegal

  • Inorganic and Analytical Chemistry Laboratory, Department of Chemistry, Faculty of Science and Technology, Cheikh Anta Diop University, Dakar, Senegal

  • Inorganic and Analytical Chemistry Laboratory, Department of Chemistry, Faculty of Science and Technology, Cheikh Anta Diop University, Dakar, Senegal

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