| Peer-Reviewed

Synthesis and Investigation of Polyester and Poly Amide Azo Dyes (I)

Received: 17 December 2014     Accepted: 25 December 2014     Published: 20 January 2015
Views:       Downloads:
Abstract

The preparation of monomer dyes was carried out by formation of diazinium salt of amine compound to coupled with Ρ- toluidine, aniline to form azo dyes with function (hydroxy and amino) groups. the polymerized was carried out with different diacid chloride or modified with acroyl chloride to polymerize with methylmethacrylate (MMA) by two method solution and interfacial poly condensation methods, the prepared mono azodye, poly(ester) and poly(amide) azopolymers were characterized, by infrared spectroscopy, elemental analysis, 1H NMR, thermodynamic (TGA), thermo gravimetric (DSC) analysis and TGA. The molecular weights were measured by GPC. The synthesized polymers showed a good film forming properties.

Published in American Journal of Applied Chemistry (Volume 3, Issue 1)
DOI 10.11648/j.ajac.20150301.12
Page(s) 6-13
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2015. Published by Science Publishing Group

Keywords

Azo Polymers, Polyesters and Polyamides

References
[1] Ho M S,Barrett C, Paterson J,E steghamation M , Natansohn A and Rochon P, Macromolecules, 199629,4613.
[2] Yin S, Xu H, shi W ,Gao y, Song Y and Wing J, Polymer, 2005,46,7670.
[3] Nabeshima Y, Shishido A, Kanazawa A, Shiono T, Ikeda t and Hiyama T, Chem Mater1997, 9, 1480.
[4] Hallas G and Towns A D, Dyes pigments, 1997, 33,319.
[5] Towns A D, Dyes pigments, 1999, 42, 3.
[6] T. Mandel., and Y. Inber., Chem. Phys. Lett. 2004, 165, 387.
[7] Hasanain A S. A Majeed, Alaa Yassin Al-Ahmad and Kawkab Ali Hussain, The Preparation, Characterization and the Study of the Linear Optical Properties of a New Azo Compound, Journal of Basrah Researches ((Sciences)) 2011,Vol.37.No. 2,.
[8] E. Saion, Susilawati, A.Doyan,S. Zainal, Z. Azmi, A. Zulkfi, A.R.MohdZaki,K.Z.H. Dahlan and T.Karni, "Changes in the Optical Band Gap and ν Absorption Edge of Gamma-Irradiated Polymer Blends “,J. Appl. Sci." , 2005, 5, 10, 1825-1829.
[9] Gardziella,A. Pilao, L.A., and Know, A., Phenolic Resins: chemistry, Applications,standardization, safety and Ecology, 2000,New York: springer.
[10] Giles C H , A Laboratory Course in Dyeing , 3rd ed ( Socity of Dyers and Colorist , Bradford ) 1974
[11] W, Jie-xiong et al. Application of Polymeric Dyes in Textile Fields, Application of Polymeric Dyes in Textile Fields, The Proceedings of the 3rd International Conference on Functional Molecules
Cite This Article
  • APA Style

    Rehab Abdeen, H. O. BadrEldin. (2015). Synthesis and Investigation of Polyester and Poly Amide Azo Dyes (I). American Journal of Applied Chemistry, 3(1), 6-13. https://doi.org/10.11648/j.ajac.20150301.12

    Copy | Download

    ACS Style

    Rehab Abdeen; H. O. BadrEldin. Synthesis and Investigation of Polyester and Poly Amide Azo Dyes (I). Am. J. Appl. Chem. 2015, 3(1), 6-13. doi: 10.11648/j.ajac.20150301.12

    Copy | Download

    AMA Style

    Rehab Abdeen, H. O. BadrEldin. Synthesis and Investigation of Polyester and Poly Amide Azo Dyes (I). Am J Appl Chem. 2015;3(1):6-13. doi: 10.11648/j.ajac.20150301.12

    Copy | Download

  • @article{10.11648/j.ajac.20150301.12,
      author = {Rehab Abdeen and H. O. BadrEldin},
      title = {Synthesis and Investigation of Polyester and Poly Amide Azo Dyes (I)},
      journal = {American Journal of Applied Chemistry},
      volume = {3},
      number = {1},
      pages = {6-13},
      doi = {10.11648/j.ajac.20150301.12},
      url = {https://doi.org/10.11648/j.ajac.20150301.12},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20150301.12},
      abstract = {The preparation of monomer dyes was carried out by formation of diazinium salt of amine compound to coupled with Ρ- toluidine, aniline to form azo dyes with function (hydroxy and amino) groups. the polymerized was carried out with different diacid chloride or modified with acroyl chloride to polymerize with methylmethacrylate (MMA) by two method solution and interfacial poly condensation methods, the prepared mono azodye, poly(ester) and poly(amide) azopolymers were characterized, by infrared spectroscopy, elemental analysis, 1H NMR, thermodynamic (TGA), thermo gravimetric (DSC) analysis and TGA. The molecular weights were measured by GPC. The synthesized polymers showed a good film forming properties.},
     year = {2015}
    }
    

    Copy | Download

  • TY  - JOUR
    T1  - Synthesis and Investigation of Polyester and Poly Amide Azo Dyes (I)
    AU  - Rehab Abdeen
    AU  - H. O. BadrEldin
    Y1  - 2015/01/20
    PY  - 2015
    N1  - https://doi.org/10.11648/j.ajac.20150301.12
    DO  - 10.11648/j.ajac.20150301.12
    T2  - American Journal of Applied Chemistry
    JF  - American Journal of Applied Chemistry
    JO  - American Journal of Applied Chemistry
    SP  - 6
    EP  - 13
    PB  - Science Publishing Group
    SN  - 2330-8745
    UR  - https://doi.org/10.11648/j.ajac.20150301.12
    AB  - The preparation of monomer dyes was carried out by formation of diazinium salt of amine compound to coupled with Ρ- toluidine, aniline to form azo dyes with function (hydroxy and amino) groups. the polymerized was carried out with different diacid chloride or modified with acroyl chloride to polymerize with methylmethacrylate (MMA) by two method solution and interfacial poly condensation methods, the prepared mono azodye, poly(ester) and poly(amide) azopolymers were characterized, by infrared spectroscopy, elemental analysis, 1H NMR, thermodynamic (TGA), thermo gravimetric (DSC) analysis and TGA. The molecular weights were measured by GPC. The synthesized polymers showed a good film forming properties.
    VL  - 3
    IS  - 1
    ER  - 

    Copy | Download

Author Information
  • Health science program, Biology Department, Faculty of Science, King Khalid University, Women center Al-Samer, Abha, KSA

  • Health science program, Biology Department, Faculty of Science, King Khalid University, Women center Al-Samer, Abha, KSA

  • Sections