| Peer-Reviewed

Determination of Isotopic Composition and Concentration of Uranium and Boron by Thermal Ionization Mass Spectrometric Isotopic Dilution Technique

Received: 13 March 2014     Accepted: 10 April 2014     Published: 20 April 2014
Views:       Downloads:
Abstract

In this study, the determination of isotopic composition and concentration of uranium and boron by mass spectrometric isotopic dilution have been performed .The isotopic composition was measured using thermal ionization mass spectrometer methodology employing U-233 and B-10 as spike isotope standards. The accuracy and reproducibility of the isotopic ratio and concentration measurements were evaluated

Published in American Journal of Applied Chemistry (Volume 2, Issue 2)
DOI 10.11648/j.ajac.20140202.11
Page(s) 27-32
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2014. Published by Science Publishing Group

Keywords

Mass Spectrometry, Boron Isotopes, Uranium Isotopes, Isotope Dilution Technique

References
[1] Y. J. Park, H. Y. Pyo, K. Song, B. C. Song, K. Y. Jee and W. H. Kim, Bull. Korean Chem. Soc., 27 (10) (2006) 1609-1612.
[2] T. U. Probost, Fresenius Z. Anal. Chem. 364 (1999) 391.
[3] P. W. May, K. N. Fox, N. A. Younes, C. M. Beardmore, Diamond and Related Materials 6 (1997) 450.
[4] C. J. Park, Bull. Korean Chem. Soc. 23 (2002) 1541-1544.
[5] A. Lamberty, V. Holland, A. Verbruggen, F. Hendrickx and P. Debievre, Fresenius Z. Anal. Chem. 332 (1988) 645-647.
[6] R. M. Rao, A. R. Parab, K. S. Bhushan and S. K. Aggarwal, Microchim Acta 169 (2010) 227-231.
[7] G. Menard, I. Vlastelic, D. A. Ionov, E. F. Rose-Koga, J. Piro and C. Pin, Chemical Geology 354 (2013) 139-149.
[8] W. Arden and N. H. Gale, Anal. chem. 46 (1974) 687-691.
[9] M. Haldimann, M. Baduraux, A. Eastgate, P. Froidevaux, S. O'Donova, D. Von Gunten and O. Zoller, J. Anal. At. Spectrom 16 (2001) 1364-1369.
[10] A. G. Adriaens, J. D. Fassett, W. R. Kelly, D. S. Simons and F. C. Adams, Anal. Chem. 64 (1992) 2945-2950.
[11] D. Vopalka and J. Cabical, Int. J. Mass Spec. and Ion Physics 48 (1983) 401-404.
[12] V. J. Heinonen and R. J. Korhonen, J. Radioal. Chem. 64, No. 1-2 (1981) 65-72.
[13] L. Koch, Radio Chim. Acta. 12 (1969) 16.
[14] J. Krtil, F. Sus and J. Mensl, J. Radioanal. Chem. 28 (1975) 109-118.
[15] F. Sus and J. Krtil, J. Radioanal. Chem. 15 (1979) 143-151.
[16] E. J. Spitzer and J. R. Sites, "Isotopic mass spectrometry of the elements'' USAEC, Rept., ORNL-3528.
[17] M. W. Lerner "The Analysis of Elemental Boron", TID-25910 (1970).
[18] R. O. Inlow and J. M. scarborough, Anal. Chem. 48 (1976) 1357.
[19] A. Henrion, Fres. J. Anal.Chem. 350 (1994) 657-658.
[20] J.Tolgyessy, T. Braun and M. Kyrs,"Isotope Dilution Analysis" pergamon press, Oxford (1972)
[21] W. Beyrich and E. Drosselmyer, “The Interlaboratory Experiment” IDA-72 on M.S.I.D.A.," kfk-1905/1 and Kfk-1905/11 (July 1975).
[22] H. O. Finely and E. E. Luang, USAEC Rept., NBL-170 (1961) "Mass Spectrometric Determination of Boron Isotopic Abundance in the Near Normal Range
Cite This Article
  • APA Style

    Hilal Shahab Wahab, Khalil Ibraheem Hussain. (2014). Determination of Isotopic Composition and Concentration of Uranium and Boron by Thermal Ionization Mass Spectrometric Isotopic Dilution Technique. American Journal of Applied Chemistry, 2(2), 27-32. https://doi.org/10.11648/j.ajac.20140202.11

    Copy | Download

    ACS Style

    Hilal Shahab Wahab; Khalil Ibraheem Hussain. Determination of Isotopic Composition and Concentration of Uranium and Boron by Thermal Ionization Mass Spectrometric Isotopic Dilution Technique. Am. J. Appl. Chem. 2014, 2(2), 27-32. doi: 10.11648/j.ajac.20140202.11

    Copy | Download

    AMA Style

    Hilal Shahab Wahab, Khalil Ibraheem Hussain. Determination of Isotopic Composition and Concentration of Uranium and Boron by Thermal Ionization Mass Spectrometric Isotopic Dilution Technique. Am J Appl Chem. 2014;2(2):27-32. doi: 10.11648/j.ajac.20140202.11

    Copy | Download

  • @article{10.11648/j.ajac.20140202.11,
      author = {Hilal Shahab Wahab and Khalil Ibraheem Hussain},
      title = {Determination of Isotopic Composition and Concentration of Uranium and Boron by Thermal Ionization Mass Spectrometric Isotopic Dilution Technique},
      journal = {American Journal of Applied Chemistry},
      volume = {2},
      number = {2},
      pages = {27-32},
      doi = {10.11648/j.ajac.20140202.11},
      url = {https://doi.org/10.11648/j.ajac.20140202.11},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20140202.11},
      abstract = {In this study, the determination of isotopic composition and concentration of uranium and boron by mass spectrometric isotopic dilution have been performed .The isotopic composition was measured using thermal ionization mass spectrometer methodology employing U-233 and B-10 as spike isotope standards. The accuracy and reproducibility of the isotopic ratio and concentration measurements were evaluated},
     year = {2014}
    }
    

    Copy | Download

  • TY  - JOUR
    T1  - Determination of Isotopic Composition and Concentration of Uranium and Boron by Thermal Ionization Mass Spectrometric Isotopic Dilution Technique
    AU  - Hilal Shahab Wahab
    AU  - Khalil Ibraheem Hussain
    Y1  - 2014/04/20
    PY  - 2014
    N1  - https://doi.org/10.11648/j.ajac.20140202.11
    DO  - 10.11648/j.ajac.20140202.11
    T2  - American Journal of Applied Chemistry
    JF  - American Journal of Applied Chemistry
    JO  - American Journal of Applied Chemistry
    SP  - 27
    EP  - 32
    PB  - Science Publishing Group
    SN  - 2330-8745
    UR  - https://doi.org/10.11648/j.ajac.20140202.11
    AB  - In this study, the determination of isotopic composition and concentration of uranium and boron by mass spectrometric isotopic dilution have been performed .The isotopic composition was measured using thermal ionization mass spectrometer methodology employing U-233 and B-10 as spike isotope standards. The accuracy and reproducibility of the isotopic ratio and concentration measurements were evaluated
    VL  - 2
    IS  - 2
    ER  - 

    Copy | Download

Author Information
  • Department of chemistry, College of Science, Al-Nahrain University, Al-Jadriya, Baghdad, Iraq

  • Department of chemistry, College of Education - Ibn Al-Haitham, University of Baghdad, Al-Aadhamiya, Baghdad, Iraq

  • Sections