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Synthesis of a Biobased Antioxidant Additive for Diesel Fuel

Received: 5 February 2014     Published: 10 March 2014
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Abstract

In this study, our objective is to synthesize a biobased antioxidant additive for Diesel fuel during the storage. Our choice was made particularly on the olive oil as raw material because of its oleic acid content which is more to 75%. The processes involved were epoxidation of oleic acid of the olive oil, opening of the oxirane ring, and esterification. The structures of the products were confirmed by FTIR. To test the effectiveness of our biobased antioxidant additive, we carried out Accelerated Oxidation Test – AOT on diesel without additive (blank) and diesel with additive with various concentrations: 2000,4000 and 6000 ppm. The oxidative degradation of diesel with or without antioxidants was investigated by UV-visible spectroscopy was used to monitor the changes using peroxide value. A remarkable stability of diesel with antioxidant additive comparing with the blank confirms the inhibition of the oxidation phoneme and thus of the good efficiency of antioxidant additive from the optimal concentration of 2000ppm.

Published in American Journal of Applied Chemistry (Volume 2, Issue 1)
DOI 10.11648/j.ajac.20140201.13
Page(s) 10-14
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2014. Published by Science Publishing Group

Keywords

Biobased Additive, Antioxidant, Diesel Fuel, Peroxide Value, Accelerated Oxidation Test

References
[1] N.Salih, J.Salimon and E. Yousif, "Synthetic biolubricant basestocks based on environmentally friendly raw materials", Journal of King Saud University – Science (2012) 24, 221–226.
[2] M.Senthil Kumar, A.Ramesh and B.Nagalingam, "Biomass and bio-energy" (2003) 25, 309.
[3] M.Eissen,J.Metzger,E.Schmidt,U. Schneidewind, "10 years after Rio - Concepts on the contribution of chemistry to a sustainable development, Angew". Chem. Int. Ed (2002) 41, 414-436.
[4] M.Genas, Rilsan (Polyamid 11), "Synthese and Eigenschaften, Angewandte Chemie", (1962)74,535-540.
[5] J.C. Guibet, "Carburants et moteurs: technologies, énergie, environnement" ,Volume 1 (1994).
[6] D.Chaithongdee,J.Chutmanop,P.Srinophakun, "Effect of Antioxidants and Additives on the Oxidation Stability of Jatropha Biodiesel". Kasetsart Journal – Natural Science (2010) 44, 243-50.
[7] M.L.A.Tavares, N.Queiroz,I.M.G .Santos, A. L.Souza,E. H. S.Cavalcanti, A. K. D. Barros, R.Rosenhaim, L. E. B.Soledade, A. G. Souza, "Sunflower Biodiesel. Use of P-DSC in the Evaluation of Antioxidant Efficiency". Journal of Thermal Analysis and Calorimetry (2011) 106(2), 575-9.
[8] L. R.Almeida, A. L.Silva, F. H. N.Souza, A. A. Hidalgo, M. L.Vega, H. N.Cunha, M. A. S. Rios, "Evaluation of Antioxidant Potentiality of Compounds Derived from Biomass for Application in Biodiesel from Soybean Oil", Química no Brasil, (2011).
[9] H. N. Fernando Souza, R.de Almeida Layane, C. L. Batista Francisco Samuel, Alexsandra de S. Rios Maria, "UV-Visible Spectroscopy Study of Oxidative Degradation of Sunflower Biodiesel",CSCanada Energy Science and Technology Vol. 2, (2011), pp. 56-61.
[10] J.Salimon, N.Salih, E.Yousif, "Chemically modified biolubricant basestocks from epoxidized oleic acid: Improved low temperature properties and oxidative stability",Journal of Saudi Chemical Society (2011) 15, 195–201.
[11] Tayde Saurabh., M.b.Patnaik, S.L. Bhagt, V.C. Renge, "Epoxidation of vegetable oils", International journal of advanced engineering technology, a review (2011) 0976-3945.
[12] Z.S.Petrovic, A. Zlatanic , C.C. Lava , S. Sinadinovicfise , "Epoxidation of soya bean oil in toluene with peroxoacetic acid and peroxoformic acids-kinetics and side reactions". European Journal of Lipid Science and Technology (2002). 104(5):293-299.
[13] S.F.Snezana, J.Milovan, S.P.Zoran. "Kinetics of in situ Epoxidation of Soybean Oil in Bulk Catalyzed by Ion Exchange Resin" JAOCS, Vol1, (2001). 78, no. 7
[14] N. Salih, J. Salimon, E.Youcef, "Synthesis of oleic acid based esters as potential basestock for biolubricant production". Turkish J. Eng. Env. Sci. (2011) 35, 115 – 123.
Cite This Article
  • APA Style

    Chikh Sabrina, Pemanos Yelda Bakoz, Zourane Tinhinane, Hamada Boudjema. (2014). Synthesis of a Biobased Antioxidant Additive for Diesel Fuel. American Journal of Applied Chemistry, 2(1), 10-14. https://doi.org/10.11648/j.ajac.20140201.13

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    ACS Style

    Chikh Sabrina; Pemanos Yelda Bakoz; Zourane Tinhinane; Hamada Boudjema. Synthesis of a Biobased Antioxidant Additive for Diesel Fuel. Am. J. Appl. Chem. 2014, 2(1), 10-14. doi: 10.11648/j.ajac.20140201.13

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    AMA Style

    Chikh Sabrina, Pemanos Yelda Bakoz, Zourane Tinhinane, Hamada Boudjema. Synthesis of a Biobased Antioxidant Additive for Diesel Fuel. Am J Appl Chem. 2014;2(1):10-14. doi: 10.11648/j.ajac.20140201.13

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  • @article{10.11648/j.ajac.20140201.13,
      author = {Chikh Sabrina and Pemanos Yelda Bakoz and Zourane Tinhinane and Hamada Boudjema},
      title = {Synthesis of a Biobased Antioxidant Additive for Diesel Fuel},
      journal = {American Journal of Applied Chemistry},
      volume = {2},
      number = {1},
      pages = {10-14},
      doi = {10.11648/j.ajac.20140201.13},
      url = {https://doi.org/10.11648/j.ajac.20140201.13},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20140201.13},
      abstract = {In this study, our objective is to synthesize a biobased antioxidant additive for Diesel fuel during the storage. Our choice was made particularly on the olive oil as raw material because of its oleic acid content which is more to 75%. The processes involved were epoxidation of oleic acid of the olive oil, opening of the oxirane ring, and esterification. The structures of the products were confirmed by FTIR. To test the effectiveness of our biobased antioxidant additive, we carried out Accelerated Oxidation Test – AOT on diesel without additive (blank) and diesel with additive with various concentrations: 2000,4000 and 6000 ppm. The oxidative degradation of diesel with or without antioxidants was investigated by UV-visible spectroscopy was used to monitor the changes using peroxide value. A remarkable stability of diesel with antioxidant additive comparing with the blank confirms the inhibition of the oxidation phoneme and thus of the good efficiency of antioxidant additive from the optimal concentration of 2000ppm.},
     year = {2014}
    }
    

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  • TY  - JOUR
    T1  - Synthesis of a Biobased Antioxidant Additive for Diesel Fuel
    AU  - Chikh Sabrina
    AU  - Pemanos Yelda Bakoz
    AU  - Zourane Tinhinane
    AU  - Hamada Boudjema
    Y1  - 2014/03/10
    PY  - 2014
    N1  - https://doi.org/10.11648/j.ajac.20140201.13
    DO  - 10.11648/j.ajac.20140201.13
    T2  - American Journal of Applied Chemistry
    JF  - American Journal of Applied Chemistry
    JO  - American Journal of Applied Chemistry
    SP  - 10
    EP  - 14
    PB  - Science Publishing Group
    SN  - 2330-8745
    UR  - https://doi.org/10.11648/j.ajac.20140201.13
    AB  - In this study, our objective is to synthesize a biobased antioxidant additive for Diesel fuel during the storage. Our choice was made particularly on the olive oil as raw material because of its oleic acid content which is more to 75%. The processes involved were epoxidation of oleic acid of the olive oil, opening of the oxirane ring, and esterification. The structures of the products were confirmed by FTIR. To test the effectiveness of our biobased antioxidant additive, we carried out Accelerated Oxidation Test – AOT on diesel without additive (blank) and diesel with additive with various concentrations: 2000,4000 and 6000 ppm. The oxidative degradation of diesel with or without antioxidants was investigated by UV-visible spectroscopy was used to monitor the changes using peroxide value. A remarkable stability of diesel with antioxidant additive comparing with the blank confirms the inhibition of the oxidation phoneme and thus of the good efficiency of antioxidant additive from the optimal concentration of 2000ppm.
    VL  - 2
    IS  - 1
    ER  - 

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Author Information
  • Laboratory of Petrochemical synthesis, Faculty of Hydrocarbons and Chemistry, University M’hamed Bouguara-Boumerdes, Algeria

  • Depatment of Chemistry, College of Science, University of ZaKho, Kurdistan Rigion, Iraq

  • Laboratory of Petrochemical synthesis, Faculty of Hydrocarbons and Chemistry, University M’hamed Bouguara-Boumerdes, Algeria

  • Laboratory of Petrochemical synthesis, Faculty of Hydrocarbons and Chemistry, University M’hamed Bouguara-Boumerdes, Algeria

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