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Synthesis and Characterization of Lanthanide Complexes of N6 – Macrocyclic Schiff Base

Received: 24 September 2013     Published: 30 October 2013
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Abstract

A new macrocyclic Schiff base complexes were prepared in the presence of lanthanide metal ion[La(III), Ce(III) and Gd(III)] by the reaction of 2,6 – diamino pyridine, benzoyl aceton and metal ion as template effect in the molar ratio of 2: 2: 1 respectively. The lanthanide metal complexes were characterized and investigated by using; 1HNMR, FTIR, UV/Visible spectroscopy, Elemental analysis (C.H.N.), Magnetic susceptibility and Molar conductivity measurements. The lanthanide metal ions coordinated to six nitrogen atoms of the ligand and three chloride ions to complete geometry of nine coordination complexes.

Published in American Journal of Applied Chemistry (Volume 1, Issue 4)
DOI 10.11648/j.ajac.20130104.11
Page(s) 49-52
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This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2013. Published by Science Publishing Group

Keywords

Macrocyclic, Schiff Bases, Lanthanide Complexes, Template Synthesis

References
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    KHALIL KHALAF ABID. (2013). Synthesis and Characterization of Lanthanide Complexes of N6 – Macrocyclic Schiff Base. American Journal of Applied Chemistry, 1(4), 49-52. https://doi.org/10.11648/j.ajac.20130104.11

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    ACS Style

    KHALIL KHALAF ABID. Synthesis and Characterization of Lanthanide Complexes of N6 – Macrocyclic Schiff Base. Am. J. Appl. Chem. 2013, 1(4), 49-52. doi: 10.11648/j.ajac.20130104.11

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    AMA Style

    KHALIL KHALAF ABID. Synthesis and Characterization of Lanthanide Complexes of N6 – Macrocyclic Schiff Base. Am J Appl Chem. 2013;1(4):49-52. doi: 10.11648/j.ajac.20130104.11

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  • @article{10.11648/j.ajac.20130104.11,
      author = {KHALIL KHALAF ABID},
      title = {Synthesis and Characterization of Lanthanide Complexes of N6 – Macrocyclic Schiff Base},
      journal = {American Journal of Applied Chemistry},
      volume = {1},
      number = {4},
      pages = {49-52},
      doi = {10.11648/j.ajac.20130104.11},
      url = {https://doi.org/10.11648/j.ajac.20130104.11},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20130104.11},
      abstract = {A new macrocyclic Schiff base complexes were prepared in the presence of lanthanide metal ion[La(III), Ce(III) and Gd(III)] by the reaction of 2,6 – diamino pyridine,  benzoyl aceton and metal ion as template effect in the molar ratio of  2: 2: 1 respectively. The lanthanide metal complexes were characterized and investigated by using; 1HNMR, FTIR, UV/Visible spectroscopy, Elemental analysis (C.H.N.), Magnetic susceptibility and Molar conductivity measurements. The lanthanide metal ions coordinated to six nitrogen atoms of the ligand and three chloride ions to complete geometry of nine coordination complexes.},
     year = {2013}
    }
    

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    T1  - Synthesis and Characterization of Lanthanide Complexes of N6 – Macrocyclic Schiff Base
    AU  - KHALIL KHALAF ABID
    Y1  - 2013/10/30
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    N1  - https://doi.org/10.11648/j.ajac.20130104.11
    DO  - 10.11648/j.ajac.20130104.11
    T2  - American Journal of Applied Chemistry
    JF  - American Journal of Applied Chemistry
    JO  - American Journal of Applied Chemistry
    SP  - 49
    EP  - 52
    PB  - Science Publishing Group
    SN  - 2330-8745
    UR  - https://doi.org/10.11648/j.ajac.20130104.11
    AB  - A new macrocyclic Schiff base complexes were prepared in the presence of lanthanide metal ion[La(III), Ce(III) and Gd(III)] by the reaction of 2,6 – diamino pyridine,  benzoyl aceton and metal ion as template effect in the molar ratio of  2: 2: 1 respectively. The lanthanide metal complexes were characterized and investigated by using; 1HNMR, FTIR, UV/Visible spectroscopy, Elemental analysis (C.H.N.), Magnetic susceptibility and Molar conductivity measurements. The lanthanide metal ions coordinated to six nitrogen atoms of the ligand and three chloride ions to complete geometry of nine coordination complexes.
    VL  - 1
    IS  - 4
    ER  - 

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Author Information
  • Department of Chemistry, College of Science, Al – Mustanseriyah University, 10053 Baghdad Iraq

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