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To the Question of Structure Formation of Dispersed Systems in Cement Technology

Received: 10 July 2020     Accepted: 24 July 2020     Published: 10 August 2020
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Abstract

In the this publication, readers will find the results of the analytical and experimental research into the physical and chemical processes in the consecutive formation of structures at the major technological stages of the present-day production of portland cement. Dispersed systems of raw mixtures, which in different methods of production are formed at the stage of grinding, mixing and homogenization of raw materials, belong to different classification groups. In wet and combined methods is produced cement sludge - aqueous dispersed system, which belongs to the 2nd group: two-phase systems such as solid dispersed phase - liquid dispersion medium. In the dry method dispersed system is formed, which belongs to the 3rd group: three-phase systems such as solid dispersed phase - water-liquid and air-gas dispersion medium. The structural-mechanical and rheological properties of the coagulation structure of cement slurries, wich differ in the main raw material components, are shown. The study of deformation processes of aqueous dispersed systems showed that the nature of the development of deformations - rapid elastic ε0’, slow elastic ε2’ and plastic ε1’τ sludge samples belong to different structural - mechanical types. At the same time differences in quantitative values and a ratio of the specified types of deformation are noted. Readers will also find the particularities of the phase changes in the process of the crystallization structure formation at baking to maximum temperature 1450°С.

Published in World Journal of Applied Chemistry (Volume 5, Issue 3)
DOI 10.11648/j.wjac.20200503.11
Page(s) 41-46
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2020. Published by Science Publishing Group

Keywords

Cement, Technology, Structure, Water System, Baking, Phase Composition

References
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[3] Ghosh S. N. Adances in Cement Technology: Chemistry, Manufacture and Testing / Taylor & Francis, 2003. – 828 p.
[4] Nichiporenko S. P., Kruglitsky N. N., Panasevich А. А., Khilko V. V. Physico-chemical mechanics of dispersed minerals. Under the total. ed. Nichiporenko S. P.– Кyiv: Naukova dumka, 1974. – 246 p.
[5] Salnik V. G., Sviderskyy V. A., Chernyak L, P. Physico-chemical mechanics of dispersed structures in building porcelain technology – Kyiv: «Znannia», 2012. – 158 p.
[6] Dorogan N. O., Sviderskyy V. A., Chernyak L. P. White Potrland Cement – Kyiv: «Politechnika», 2018. – 204 p.
[7] Uryev N. B. Highly concentrated dispersed systems and materials – М.: Techpolitgrafcenter, 2018. – 407 p.
[8] Budnikov P. P., Ginstling A. M. Reactions in mixtures of solids. - М.: Stroyizdat, 1971.- 488 p.
[9] Richardson J., Taylor H. F. W. Cement Chemistry – London: ICE Publishing; 3 edition, 2020. – 600 р.
[10] Harsha Praneeth Pavani, Tezeswi Tadepalli, Ashish Kumar Agrawal. Thermal behaviour of PPC and OPC-53 when exposed to extreme temperatures – Advances in Cement Research, 2020. – 32: 8, pp. 358-370.
[11] Kurdowski W. Cement and Concrete Chemistry – Springer Netherlands, 2014. – 700 p.
[12] Ludwig H-M, Zhang W. Research review of cement clinker chemistry – Cement and Concrete Research, 2015. – Vol. 78.
[13] Hewlett P., Liska M. Lea’s Chemistry of Cement and Concrete – London: Butterworth-Heinemann; 5 edition, 2019. – 896 p.
[14] Gartner E., Sui T. Alternative cement clinkers - Cement and Concrete Research, 2018. – Vol. 114. - pp. 27-39.
[15] Valencia D. E. J., Baena O. J. R. Portland Cement Clinker Formation: High 18. Temperature Equilibria and Phase Composition Prediction. In: The Minerals, Metals & Materials Society (eds) TMS 2015 144th Annual Meeting & Exhibition, 2015. – Springer, Cham. – pp. 879-886.
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  • APA Style

    Chernyak Lev, Sviderskyy Valentin, Tokarchuk Volodymyr, Dorogan Natalia. (2020). To the Question of Structure Formation of Dispersed Systems in Cement Technology. World Journal of Applied Chemistry, 5(3), 41-46. https://doi.org/10.11648/j.wjac.20200503.11

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    ACS Style

    Chernyak Lev; Sviderskyy Valentin; Tokarchuk Volodymyr; Dorogan Natalia. To the Question of Structure Formation of Dispersed Systems in Cement Technology. World J. Appl. Chem. 2020, 5(3), 41-46. doi: 10.11648/j.wjac.20200503.11

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    AMA Style

    Chernyak Lev, Sviderskyy Valentin, Tokarchuk Volodymyr, Dorogan Natalia. To the Question of Structure Formation of Dispersed Systems in Cement Technology. World J Appl Chem. 2020;5(3):41-46. doi: 10.11648/j.wjac.20200503.11

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  • @article{10.11648/j.wjac.20200503.11,
      author = {Chernyak Lev and Sviderskyy Valentin and Tokarchuk Volodymyr and Dorogan Natalia},
      title = {To the Question of Structure Formation of Dispersed Systems in Cement Technology},
      journal = {World Journal of Applied Chemistry},
      volume = {5},
      number = {3},
      pages = {41-46},
      doi = {10.11648/j.wjac.20200503.11},
      url = {https://doi.org/10.11648/j.wjac.20200503.11},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.wjac.20200503.11},
      abstract = {In the this publication, readers will find the results of the analytical and experimental research into the physical and chemical processes in the consecutive formation of structures at the major technological stages of the present-day production of portland cement. Dispersed systems of raw mixtures, which in different methods of production are formed at the stage of grinding, mixing and homogenization of raw materials, belong to different classification groups. In wet and combined methods is produced cement sludge - aqueous dispersed system, which belongs to the 2nd group: two-phase systems such as solid dispersed phase - liquid dispersion medium. In the dry method dispersed system is formed, which belongs to the 3rd group: three-phase systems such as solid dispersed phase - water-liquid and air-gas dispersion medium. The structural-mechanical and rheological properties of the coagulation structure of cement slurries, wich differ in the main raw material components, are shown. The study of deformation processes of aqueous dispersed systems showed that the nature of the development of deformations - rapid elastic ε0’, slow elastic ε2’ and plastic ε1’τ sludge samples belong to different structural - mechanical types. At the same time differences in quantitative values and a ratio of the specified types of deformation are noted. Readers will also find the particularities of the phase changes in the process of the crystallization structure formation at baking to maximum temperature 1450°С.},
     year = {2020}
    }
    

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    T1  - To the Question of Structure Formation of Dispersed Systems in Cement Technology
    AU  - Chernyak Lev
    AU  - Sviderskyy Valentin
    AU  - Tokarchuk Volodymyr
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    DO  - 10.11648/j.wjac.20200503.11
    T2  - World Journal of Applied Chemistry
    JF  - World Journal of Applied Chemistry
    JO  - World Journal of Applied Chemistry
    SP  - 41
    EP  - 46
    PB  - Science Publishing Group
    SN  - 2637-5982
    UR  - https://doi.org/10.11648/j.wjac.20200503.11
    AB  - In the this publication, readers will find the results of the analytical and experimental research into the physical and chemical processes in the consecutive formation of structures at the major technological stages of the present-day production of portland cement. Dispersed systems of raw mixtures, which in different methods of production are formed at the stage of grinding, mixing and homogenization of raw materials, belong to different classification groups. In wet and combined methods is produced cement sludge - aqueous dispersed system, which belongs to the 2nd group: two-phase systems such as solid dispersed phase - liquid dispersion medium. In the dry method dispersed system is formed, which belongs to the 3rd group: three-phase systems such as solid dispersed phase - water-liquid and air-gas dispersion medium. The structural-mechanical and rheological properties of the coagulation structure of cement slurries, wich differ in the main raw material components, are shown. The study of deformation processes of aqueous dispersed systems showed that the nature of the development of deformations - rapid elastic ε0’, slow elastic ε2’ and plastic ε1’τ sludge samples belong to different structural - mechanical types. At the same time differences in quantitative values and a ratio of the specified types of deformation are noted. Readers will also find the particularities of the phase changes in the process of the crystallization structure formation at baking to maximum temperature 1450°С.
    VL  - 5
    IS  - 3
    ER  - 

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Author Information
  • Department of Chemical Technology of Composite Material, National Technical University of Ukraine "Igor Sikorsky Kyiv Polytechnic Institute", Кyiv, Ukraine

  • Department of Chemical Technology of Composite Material, National Technical University of Ukraine "Igor Sikorsky Kyiv Polytechnic Institute", Кyiv, Ukraine

  • Department of Chemical Technology of Composite Material, National Technical University of Ukraine "Igor Sikorsky Kyiv Polytechnic Institute", Кyiv, Ukraine

  • Department of Chemical Technology of Composite Material, National Technical University of Ukraine "Igor Sikorsky Kyiv Polytechnic Institute", Кyiv, Ukraine

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