Fluoride Determination in Pickling Solution of Stainless Steel by Ion Selective Electrode

Yusuf Yildiz; Angela Jan; Sapan Patel

doi:doi:10.11648/j.wjac.20180301.14

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Fluoride Determination in Pickling Solution of Stainless Steel by Ion Selective Electrode

Yusuf Yildiz, Angela Jan, Sapan Patel

Published in World Journal of Applied Chemistry (Volume 3, Issue 1)

Received: 23 February 2018 Accepted: 11 March 2018 Published: 9 April 2018

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Abstract

The Fluoride Ion Selective Electrode is an ion-selective sensor and will quickly and accurately measure fluoride ion activity rather than concentration in aqueous solutions. Fluoride ion activity depends on the solution total ionic strength and pH, and on fluoride complexing species. Adding an appropriate buffer provides a nearly uniform ionic strength background, adjust pH, and breaks up complexes so that, in effect, the electrode measures concentration. Pickling removes a thin surface layer from the stainless, using an acid solution, which is usually a hydrofluoric acid (HF) and nitric acid (HNO₃), also called mixed acid. In this study, fluoride ion strength has been measured of pickling waste water from stainless steel by ion selective electrode. The results met the specification.

Published in	World Journal of Applied Chemistry (Volume 3, Issue 1)
DOI	10.11648/j.wjac.20180301.14
Page(s)	28-31
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2018. Published by Science Publishing Group

Keywords

Pickling Stainless Steel Solution, Fluoride, Ion Selective Electrode

References

[1]	Bohler Welding Nordic AB. Pickling Handbook. Surface Treatment of Stainless Steel.
[2]	Technical Specification for the Fluoride Ion-Selective Electrode (ELIT 82221).
[3]	Y. Yildiz; Determination of Fluoride in tri-calcium phosphate (TCP) by Ion-Selective Electrode. International Journal of Development Research, Vol. 5, issue: 10, pp: 5704-5706, October, 2015.
[4]	Orion Research, Boston, MA.
[5]	Skoog/West/Holber, Analytical Chemistry an Introduction, Sixth Edition. Saunders Golden Sunburst Series. 1993, USA.
[6]	Prem N. Vijan and Baverly Aider, Determination of fluoride in vegetable by ion-selective electrode. American laboratory, December 1984.
[7]	Dionex, Application Note 209. Determination of Fluoride in Acidulated Phosphate Topical Solutions using reagent-Free Ion Chromatography.
[8]	Method for Determining the Concentration of Fluoride (F-) in Aqueous Solutions. NICO 2000. ELIT Brand Electrochemical Sensors.
[9]	Edens G. and Yildiz Y. Standard method for Determination of Fluoride in ARDE Pickling sample. Complete Analysis Laboratories, June 18, 2010. New Jersey, USA.
[10]	Fluoride Combination Ion Selective Electrode, Accument. Cat No: 13-620-528& 13-620-529 Published: 03/94.
[11]	Standard Methods for the Examination of Water &Wastewater, 21st Edition 2005. 4500-F-C Ion-Selective Electrode Method p: 4-84.
[12]	J. R. Sherman, Standard Method for Determination of Fluoride. Arde, Inc. New Jersey. 9-18- 2006.

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APA Style

Yusuf Yildiz, Angela Jan, Sapan Patel. (2018). Fluoride Determination in Pickling Solution of Stainless Steel by Ion Selective Electrode. World Journal of Applied Chemistry, 3(1), 28-31. https://doi.org/10.11648/j.wjac.20180301.14

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ACS Style

Yusuf Yildiz; Angela Jan; Sapan Patel. Fluoride Determination in Pickling Solution of Stainless Steel by Ion Selective Electrode. World J. Appl. Chem. 2018, 3(1), 28-31. doi: 10.11648/j.wjac.20180301.14

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AMA Style

Yusuf Yildiz, Angela Jan, Sapan Patel. Fluoride Determination in Pickling Solution of Stainless Steel by Ion Selective Electrode. World J Appl Chem. 2018;3(1):28-31. doi: 10.11648/j.wjac.20180301.14

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@article{10.11648/j.wjac.20180301.14,
  author = {Yusuf Yildiz and Angela Jan and Sapan Patel},
  title = {Fluoride Determination in Pickling Solution of Stainless Steel by Ion Selective Electrode},
  journal = {World Journal of Applied Chemistry},
  volume = {3},
  number = {1},
  pages = {28-31},
  doi = {10.11648/j.wjac.20180301.14},
  url = {https://doi.org/10.11648/j.wjac.20180301.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.wjac.20180301.14},
  abstract = {The Fluoride Ion Selective Electrode is an ion-selective sensor and will quickly and accurately measure fluoride ion activity rather than concentration in aqueous solutions. Fluoride ion activity depends on the solution total ionic strength and pH, and on fluoride complexing species. Adding an appropriate buffer provides a nearly uniform ionic strength background, adjust pH, and breaks up complexes so that, in effect, the electrode measures concentration. Pickling removes a thin surface layer from the stainless, using an acid solution, which is usually a hydrofluoric acid (HF) and nitric acid (HNO3), also called mixed acid. In this study, fluoride ion strength has been measured of pickling waste water from stainless steel by ion selective electrode. The results met the specification.},
 year = {2018}
}

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TY  - JOUR
T1  - Fluoride Determination in Pickling Solution of Stainless Steel by Ion Selective Electrode
AU  - Yusuf Yildiz
AU  - Angela Jan
AU  - Sapan Patel
Y1  - 2018/04/09
PY  - 2018
N1  - https://doi.org/10.11648/j.wjac.20180301.14
DO  - 10.11648/j.wjac.20180301.14
T2  - World Journal of Applied Chemistry
JF  - World Journal of Applied Chemistry
JO  - World Journal of Applied Chemistry
SP  - 28
EP  - 31
PB  - Science Publishing Group
SN  - 2637-5982
UR  - https://doi.org/10.11648/j.wjac.20180301.14
AB  - The Fluoride Ion Selective Electrode is an ion-selective sensor and will quickly and accurately measure fluoride ion activity rather than concentration in aqueous solutions. Fluoride ion activity depends on the solution total ionic strength and pH, and on fluoride complexing species. Adding an appropriate buffer provides a nearly uniform ionic strength background, adjust pH, and breaks up complexes so that, in effect, the electrode measures concentration. Pickling removes a thin surface layer from the stainless, using an acid solution, which is usually a hydrofluoric acid (HF) and nitric acid (HNO3), also called mixed acid. In this study, fluoride ion strength has been measured of pickling waste water from stainless steel by ion selective electrode. The results met the specification.
VL  - 3
IS  - 1
ER  -

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Author Information

Yusuf Yildiz

Analytical Chemistry Research Department, Complete Analysis Laboratories, New Jersey, USA
Angela Jan

Analytical Chemistry Department, Whitehouse Labs/AMRI, New Jersey, USA
Sapan Patel

Whiting School of Engineering, John Hopkins University, Baltimore, USA

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APA Style

Yusuf Yildiz, Angela Jan, Sapan Patel. (2018). Fluoride Determination in Pickling Solution of Stainless Steel by Ion Selective Electrode. World Journal of Applied Chemistry, 3(1), 28-31. https://doi.org/10.11648/j.wjac.20180301.14

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ACS Style

Yusuf Yildiz; Angela Jan; Sapan Patel. Fluoride Determination in Pickling Solution of Stainless Steel by Ion Selective Electrode. World J. Appl. Chem. 2018, 3(1), 28-31. doi: 10.11648/j.wjac.20180301.14

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AMA Style

Yusuf Yildiz, Angela Jan, Sapan Patel. Fluoride Determination in Pickling Solution of Stainless Steel by Ion Selective Electrode. World J Appl Chem. 2018;3(1):28-31. doi: 10.11648/j.wjac.20180301.14

Copy | Download

@article{10.11648/j.wjac.20180301.14,
  author = {Yusuf Yildiz and Angela Jan and Sapan Patel},
  title = {Fluoride Determination in Pickling Solution of Stainless Steel by Ion Selective Electrode},
  journal = {World Journal of Applied Chemistry},
  volume = {3},
  number = {1},
  pages = {28-31},
  doi = {10.11648/j.wjac.20180301.14},
  url = {https://doi.org/10.11648/j.wjac.20180301.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.wjac.20180301.14},
  abstract = {The Fluoride Ion Selective Electrode is an ion-selective sensor and will quickly and accurately measure fluoride ion activity rather than concentration in aqueous solutions. Fluoride ion activity depends on the solution total ionic strength and pH, and on fluoride complexing species. Adding an appropriate buffer provides a nearly uniform ionic strength background, adjust pH, and breaks up complexes so that, in effect, the electrode measures concentration. Pickling removes a thin surface layer from the stainless, using an acid solution, which is usually a hydrofluoric acid (HF) and nitric acid (HNO3), also called mixed acid. In this study, fluoride ion strength has been measured of pickling waste water from stainless steel by ion selective electrode. The results met the specification.},
 year = {2018}
}

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TY  - JOUR
T1  - Fluoride Determination in Pickling Solution of Stainless Steel by Ion Selective Electrode
AU  - Yusuf Yildiz
AU  - Angela Jan
AU  - Sapan Patel
Y1  - 2018/04/09
PY  - 2018
N1  - https://doi.org/10.11648/j.wjac.20180301.14
DO  - 10.11648/j.wjac.20180301.14
T2  - World Journal of Applied Chemistry
JF  - World Journal of Applied Chemistry
JO  - World Journal of Applied Chemistry
SP  - 28
EP  - 31
PB  - Science Publishing Group
SN  - 2637-5982
UR  - https://doi.org/10.11648/j.wjac.20180301.14
AB  - The Fluoride Ion Selective Electrode is an ion-selective sensor and will quickly and accurately measure fluoride ion activity rather than concentration in aqueous solutions. Fluoride ion activity depends on the solution total ionic strength and pH, and on fluoride complexing species. Adding an appropriate buffer provides a nearly uniform ionic strength background, adjust pH, and breaks up complexes so that, in effect, the electrode measures concentration. Pickling removes a thin surface layer from the stainless, using an acid solution, which is usually a hydrofluoric acid (HF) and nitric acid (HNO3), also called mixed acid. In this study, fluoride ion strength has been measured of pickling waste water from stainless steel by ion selective electrode. The results met the specification.
VL  - 3
IS  - 1
ER  -

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