Studies on Chemical and Physical Properties of LiFeMPO<sub>4</sub> (M=Cu, La) by Polyol Route

Rasu Muruganantham; Marimuthu Sivakumar; Renganpillai Subadevi; Wei-Ren Liu

doi:doi:10.11648/j.wjac.20170201.12

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Studies on Chemical and Physical Properties of LiFeMPO₄ (M=Cu, La) by Polyol Route

Rasu Muruganantham, Marimuthu Sivakumar, Renganpillai Subadevi, Wei-Ren Liu

Published in World Journal of Applied Chemistry (Volume 2, Issue 1)

Received: 9 December 2016 Accepted: 23 December 2016 Published: 23 January 2017

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Abstract

Bare Lithium Iron Phosphate (LiFePO₄), Cu, La doped and Cu with La co-doped LiFePO₄ composite materials have been prepared via polyol technique without further post heat treatment. The prepared bare and composite materials’ crystalline structure has been indexed an orthorhombic phase olivine structure with space group of Pnma. The functional group vibrations and surface morphology of the prepared materials has been observed using Fourier transfer infrared spectroscopy (FT-IR) and scanning electron microscopy (SEM) with EDX analyses. Magnetization measurements revealed that saturation magnetizations (Ms) of the metal doped samples are gradually increased than that of the pure LiFePO₄. All the samples exhibit the spin-glass behaviour of magnetic materials.

Published in	World Journal of Applied Chemistry (Volume 2, Issue 1)
DOI	10.11648/j.wjac.20170201.12
Page(s)	7-12
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2017. Published by Science Publishing Group

Keywords

LiFePO₄, Cathode Materials, Polyol Process, Magnetic Measurements

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APA Style

Rasu Muruganantham, Marimuthu Sivakumar, Renganpillai Subadevi, Wei-Ren Liu. (2017). Studies on Chemical and Physical Properties of LiFeMPO4 (M=Cu, La) by Polyol Route. World Journal of Applied Chemistry, 2(1), 7-12. https://doi.org/10.11648/j.wjac.20170201.12

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ACS Style

Rasu Muruganantham; Marimuthu Sivakumar; Renganpillai Subadevi; Wei-Ren Liu. Studies on Chemical and Physical Properties of LiFeMPO4 (M=Cu, La) by Polyol Route. World J. Appl. Chem. 2017, 2(1), 7-12. doi: 10.11648/j.wjac.20170201.12

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AMA Style

Rasu Muruganantham, Marimuthu Sivakumar, Renganpillai Subadevi, Wei-Ren Liu. Studies on Chemical and Physical Properties of LiFeMPO4 (M=Cu, La) by Polyol Route. World J Appl Chem. 2017;2(1):7-12. doi: 10.11648/j.wjac.20170201.12

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@article{10.11648/j.wjac.20170201.12,
  author = {Rasu Muruganantham and Marimuthu Sivakumar and Renganpillai Subadevi and Wei-Ren Liu},
  title = {Studies on Chemical and Physical Properties of LiFeMPO4 (M=Cu, La) by Polyol Route},
  journal = {World Journal of Applied Chemistry},
  volume = {2},
  number = {1},
  pages = {7-12},
  doi = {10.11648/j.wjac.20170201.12},
  url = {https://doi.org/10.11648/j.wjac.20170201.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.wjac.20170201.12},
  abstract = {Bare Lithium Iron Phosphate (LiFePO4), Cu, La doped and Cu with La co-doped LiFePO4 composite materials have been prepared via polyol technique without further post heat treatment. The prepared bare and composite materials’ crystalline structure has been indexed an orthorhombic phase olivine structure with space group of Pnma. The functional group vibrations and surface morphology of the prepared materials has been observed using Fourier transfer infrared spectroscopy (FT-IR) and scanning electron microscopy (SEM) with EDX analyses. Magnetization measurements revealed that saturation magnetizations (Ms) of the metal doped samples are gradually increased than that of the pure LiFePO4. All the samples exhibit the spin-glass behaviour of magnetic materials.},
 year = {2017}
}

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TY  - JOUR
T1  - Studies on Chemical and Physical Properties of LiFeMPO4 (M=Cu, La) by Polyol Route
AU  - Rasu Muruganantham
AU  - Marimuthu Sivakumar
AU  - Renganpillai Subadevi
AU  - Wei-Ren Liu
Y1  - 2017/01/23
PY  - 2017
N1  - https://doi.org/10.11648/j.wjac.20170201.12
DO  - 10.11648/j.wjac.20170201.12
T2  - World Journal of Applied Chemistry
JF  - World Journal of Applied Chemistry
JO  - World Journal of Applied Chemistry
SP  - 7
EP  - 12
PB  - Science Publishing Group
SN  - 2637-5982
UR  - https://doi.org/10.11648/j.wjac.20170201.12
AB  - Bare Lithium Iron Phosphate (LiFePO4), Cu, La doped and Cu with La co-doped LiFePO4 composite materials have been prepared via polyol technique without further post heat treatment. The prepared bare and composite materials’ crystalline structure has been indexed an orthorhombic phase olivine structure with space group of Pnma. The functional group vibrations and surface morphology of the prepared materials has been observed using Fourier transfer infrared spectroscopy (FT-IR) and scanning electron microscopy (SEM) with EDX analyses. Magnetization measurements revealed that saturation magnetizations (Ms) of the metal doped samples are gradually increased than that of the pure LiFePO4. All the samples exhibit the spin-glass behaviour of magnetic materials.
VL  - 2
IS  - 1
ER  -

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Author Information

Rasu Muruganantham

Energy and Opto-Electronic Materials Lab, Department of Chemical Engineering, Chung Yuan Christian University, Taoyuan City, Taiwan. ROC
Marimuthu Sivakumar

Energy Materials Lab, School of Physics, Science Block, Alagappa University, Karaikudi, Tamil Nadu, India
Renganpillai Subadevi

Energy Materials Lab, School of Physics, Science Block, Alagappa University, Karaikudi, Tamil Nadu, India
Wei-Ren Liu

Energy and Opto-Electronic Materials Lab, Department of Chemical Engineering, Chung Yuan Christian University, Taoyuan City, Taiwan. ROC

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Plain Text BibTeX RIS

APA Style

Rasu Muruganantham, Marimuthu Sivakumar, Renganpillai Subadevi, Wei-Ren Liu. (2017). Studies on Chemical and Physical Properties of LiFeMPO4 (M=Cu, La) by Polyol Route. World Journal of Applied Chemistry, 2(1), 7-12. https://doi.org/10.11648/j.wjac.20170201.12

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ACS Style

Rasu Muruganantham; Marimuthu Sivakumar; Renganpillai Subadevi; Wei-Ren Liu. Studies on Chemical and Physical Properties of LiFeMPO4 (M=Cu, La) by Polyol Route. World J. Appl. Chem. 2017, 2(1), 7-12. doi: 10.11648/j.wjac.20170201.12

Copy | Download

AMA Style

Rasu Muruganantham, Marimuthu Sivakumar, Renganpillai Subadevi, Wei-Ren Liu. Studies on Chemical and Physical Properties of LiFeMPO4 (M=Cu, La) by Polyol Route. World J Appl Chem. 2017;2(1):7-12. doi: 10.11648/j.wjac.20170201.12

Copy | Download

@article{10.11648/j.wjac.20170201.12,
  author = {Rasu Muruganantham and Marimuthu Sivakumar and Renganpillai Subadevi and Wei-Ren Liu},
  title = {Studies on Chemical and Physical Properties of LiFeMPO4 (M=Cu, La) by Polyol Route},
  journal = {World Journal of Applied Chemistry},
  volume = {2},
  number = {1},
  pages = {7-12},
  doi = {10.11648/j.wjac.20170201.12},
  url = {https://doi.org/10.11648/j.wjac.20170201.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.wjac.20170201.12},
  abstract = {Bare Lithium Iron Phosphate (LiFePO4), Cu, La doped and Cu with La co-doped LiFePO4 composite materials have been prepared via polyol technique without further post heat treatment. The prepared bare and composite materials’ crystalline structure has been indexed an orthorhombic phase olivine structure with space group of Pnma. The functional group vibrations and surface morphology of the prepared materials has been observed using Fourier transfer infrared spectroscopy (FT-IR) and scanning electron microscopy (SEM) with EDX analyses. Magnetization measurements revealed that saturation magnetizations (Ms) of the metal doped samples are gradually increased than that of the pure LiFePO4. All the samples exhibit the spin-glass behaviour of magnetic materials.},
 year = {2017}
}

Copy | Download

TY  - JOUR
T1  - Studies on Chemical and Physical Properties of LiFeMPO4 (M=Cu, La) by Polyol Route
AU  - Rasu Muruganantham
AU  - Marimuthu Sivakumar
AU  - Renganpillai Subadevi
AU  - Wei-Ren Liu
Y1  - 2017/01/23
PY  - 2017
N1  - https://doi.org/10.11648/j.wjac.20170201.12
DO  - 10.11648/j.wjac.20170201.12
T2  - World Journal of Applied Chemistry
JF  - World Journal of Applied Chemistry
JO  - World Journal of Applied Chemistry
SP  - 7
EP  - 12
PB  - Science Publishing Group
SN  - 2637-5982
UR  - https://doi.org/10.11648/j.wjac.20170201.12
AB  - Bare Lithium Iron Phosphate (LiFePO4), Cu, La doped and Cu with La co-doped LiFePO4 composite materials have been prepared via polyol technique without further post heat treatment. The prepared bare and composite materials’ crystalline structure has been indexed an orthorhombic phase olivine structure with space group of Pnma. The functional group vibrations and surface morphology of the prepared materials has been observed using Fourier transfer infrared spectroscopy (FT-IR) and scanning electron microscopy (SEM) with EDX analyses. Magnetization measurements revealed that saturation magnetizations (Ms) of the metal doped samples are gradually increased than that of the pure LiFePO4. All the samples exhibit the spin-glass behaviour of magnetic materials.
VL  - 2
IS  - 1
ER  -

Copy | Download