1. Introduction
The development of industrial minerals is a critical driver for the structural transformation of developing economies. In Ethiopia, the mining sector has historically focused on precious metals, yet the vast potential of industrial minerals like diatomite remains largely underutilized.
Diatomite, a naturally occurring siliceous sedimentary rock, is composed of the fossilized skeletal remains of diatoms microscopic, single-celled aquatic algae. These frustules are primarily composed of amorphous silica (SiO₂·nH₂O), giving the material a unique suite of physical and chemical properties, including high surface area, exceptional porosity, chemical inertness, and low thermal conductivity
| [2] | Morgan, D. J. (2007). Industrial minerals and artisanal mining study (Ethiopia World Bank Energy Access Project): Summary of activities, findings and recommendations of industrial minerals sub-project (Report No. CR/06/181N). British Geological Survey.
https://nora.nerc.ac.uk/id/eprint/19660/ |
[2]
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The Ethiopian Rift System provides an optimal geological environment for the formation of massive diatomite deposits. The combination of intense Cenozoic volcanism and the presence of extensive lacustrine basins have facilitated the accumulation of high-purity diatomaceous earth. Volcanic activity in the rift has provided an abundant supply of dissolved silica through the deposition of ash and the influence of hydrothermal systems, while the closed basins created the stable water bodies necessary for diatom proliferation. Significant deposits have been identified in the Lakes Region of the Main Ethiopian Rift (MER), including Abiyata, Adami-Tulu, Gade Mota, and Chefe Jilla, as well as in the Afar Depression and the northern highlands at Lake Ashenge. Despite possessing an estimated 46.53 million tons of diatomite, of which 310,000 tons are considered high-grade, Ethiopia continues to import processed diatomite to meet the needs of its domestic industries (Ethiopian Ministry of Mines, 2007). The brewery sector, construction industry, and chemical manufacturers are the primary consumers, yet the local milling and refining capacity remains insufficient to meet modern industrial standards. This creates a significant opportunity for import substitution, a key pillar of Ethiopia's current economic reform agenda.
| [3] | Ethiopian Ministry of Mines. (2007). Industrial minerals and rocks of Ethiopia (Draft Report). Addis Ababa, Ethiopia. |
[3]
The 10-Year Development Plan (2021–2030) targets a rise in the mining sector's contribution to GDP from 2% to 14%, emphasizing the role of industrial minerals in providing raw materials for local manufacturing and enhancing export earnings
| [4] | Federal Democratic Republic of Ethiopia (FDRE). (2021). Ten-year development plan: A pathway to prosperity (2021–2030). Planning and Development Commission. Addis Ababa, Ethiopia. |
[4]
.
Beyond traditional uses, recent scientific advancements have opened new frontiers for diatomite utilization. These include its use in advanced 3D concrete printing to enhance carbon capture, the synthesis of hierarchical geopolymer foams for thermal insulation, and the development of modified adsorbents for the removal of fluoride and heavy metals from water. These value-addition opportunities represent a pathway toward a knowledge-based mineral economy that integrates industrial growth with environmental sustainability
| [5] | Senol, Z. M., & Simşek, S. (2020). Removal of Pb2+ ions from aqueous medium by using chitosan-diatomite composite: Equilibrium, kinetic and thermodynamic studies. Journal of the Turkish Chemical Society Section A: Chemistry, 7(1), 307–318. https://doi.org/10.18596/jotcsa.634590 |
| [6] | Teng, F., Xu, F., Yang, M., Yu, J., Zhang, D., & Weng, Y. (2025). Development of sustainable strain-hardening cementitious composites containing diatomite for 3D printing. Journal of Building Engineering, 103, 112170.
https://doi.org/10.1016/j.jobe.2025.112170 |
| [7] | Yu, J., Wang, Y., Xu, F., Zhang, D., & Weng, Y. (2025). 3D concrete printing of triply periodic minimum surfaces for enhanced carbon capture and storage. Advanced Functional Materials, 35(8), 2416026.
https://doi.org/10.1002/adfm.202416026 |
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1.1. Geological Setting
The formation and distribution of diatomite in Ethiopia are inextricably linked to the tectonic and volcanic evolution of the East African Rift System (EARS). The Main Ethiopian Rift (MER) is the northern segment of the EARS, characterized by a complex history of lithospheric thinning, extensional faulting, and voluminous magmatism that spans from the Oligocene to the Present
| [8] | Japan International Cooperation Agency (JICA). (2012). The study on Rift Valley Lakes Basin integrated resources management master plan in the Federal Democratic Republic of Ethiopia. Ministry of Water and Energy. |
[8]
.
1.2. Tectonic Evolution and Basin Formation
The MER developed through a two-stage process that shaped the topography and sedimentary basins of the region. The early phase, occurring from the late Oligocene to the early Miocene, was characterized by the development of alternating and opposed half-grabens. By the late Miocene, these structures evolved into a more symmetrical rift system. The contemporary rift architecture is defined by a series of NE-SW trending marginal faults, which are intersected by the more recent NNE-SSW trending Wonji Fault Belt (WFB). The WFB represents the main spreading axis and is characterized by active faulting and Quaternary volcanism, which has been instrumental in the subsidence of the rift floor by as much as 2 km
| [9] | Benvenuti, M., Bonini, M., Moratti, P., & Sani, F. (2002). The Ziway–Shala lake basin (Main Ethiopian Rift, Ethiopia): A revised stratigraphic, pedological and geomorphological framework. Journal of African Earth Sciences, 35(2), 247–269.
https://doi.org/10.1016/S0899-5362(02)00115-6 |
[9]
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This extensional regime created numerous closed basins, many of which were occupied by expansive lakes during the Pleistocene and Holocene. The Ziway-Langano-Abiyata-Shala basin system in the central MER is a prime example of such a lacustrine environment
| [10] | Le Turdu, C., Tiercelin, J.-J., Gibert, E., Travi, Y., Lezzar, K. E., Richert, J.-P., Massault, M., Gasse, F., Bonnefille, R., Decobert, M., Gensous, B., Jeudy, V., Tamrat, E., Mohammed, M. U., Martens, K., Atnafu, B., Chernet, T., Williamson, D., & Taieb, M. (1999). The Ziway–Shala lake basin system, Main Ethiopian Rift: Influence of volcanism, tectonics, and climatic forcing on basin formation and sedimentation. Palaeogeography, Palaeoclimatology, Palaeoecology, 150(3-4), 135–177. https://doi.org/10.1016/S0031-0182(98)00216-2 |
[10]
. These lakes were sensitive to both tectonic shifts and climatic forcing, expanding during humid periods to provide vast, stable habitats for diatom communities
| [11] | Wondmagegn, T., Mengistou, S., & Barker, P. A. (2019). Testing of the applicability of European diatom indices in the tropical rift valley lake, Lake Hawassa, in Ethiopia. African Journal of Aquatic Science, 44(3), 209–217.
https://doi.org/10.2989/16085914.2019.1612590 |
[11]
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1.3. Volcanism and Silica Genesis
Silicic volcanism provided the essential chemical precursor for diatomite formation: dissolved silica. In the MER, volcanic activities ranging from fissure basaltic eruptions to rhyolitic caldera-forming events released significant quantities of volcanic ash and tephra. The weathering of these volcanic materials, alongside input from silica-rich hydrothermal springs, maintained high levels of dissolved orthosilicic acid in the lake waters. Geothermal studies in areas like the Shala and Aluto volcanic complexes indicate the presence of magmatic intrusions at depths below 7 km, which continue to drive hydrothermal activity in the rift floor. This continuous supply of silica, combined with nutrients derived from volcanic runoff, allowed for the rapid growth and accumulation of diatomaceous oozes that eventually lithified into diatomite
| [12] | Samrock, F., Grayver, A., Eysteinsson, H., & Saar, M. O. (2018). Magnetotelluric image of trans-crustal magmatic system and hydrothermal reservoir beneath the Tulu Moye geothermal prospect, Main Ethiopian Rift. Journal of Geophysical Research: Solid Earth, 123(3), 2035–2052.
https://doi.org/10.1002/2017JB014860 |
[12]
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1.4. Stratigraphic Context
Diatomite deposits in Ethiopia are typically found within Tertiary and Quaternary sedimentary sequences. They are often interbedded with or overlain by volcanic products, including pumice, unwelded tuffs, and ignimbrites.
| [3] | Ethiopian Ministry of Mines. (2007). Industrial minerals and rocks of Ethiopia (Draft Report). Addis Ababa, Ethiopia. |
[3]
For instance, in the Lake Abiyata area, the stratigraphy includes lacustrine sediments, pyroclastic ash, and the Bulbula and Shalo lacustrine deposits, which consist of gravel, sand, and mud.
| [8] | Japan International Cooperation Agency (JICA). (2012). The study on Rift Valley Lakes Basin integrated resources management master plan in the Federal Democratic Republic of Ethiopia. Ministry of Water and Energy. |
[8]
In the northern Ethiopian plateau, Lake Ashenge lies in a faulted graben of mid-Tertiary flood basalts, where diatomaceous earth is found in association with lacustrine clays and peat
| [13] | Giday, W., Hart, W. K., Renne, P. R., Sharp, W. D., Shackley, M. S., & Ambrose, S. H. (2019). Geological and geochronological context of the Lake Ashenge area, Northern Ethiopian Plateau. |
[13]
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Table 1.
General stratigraphy of the Main Ethiopian Rift and its relation to diatomite formation. | [8] | Japan International Cooperation Agency (JICA). (2012). The study on Rift Valley Lakes Basin integrated resources management master plan in the Federal Democratic Republic of Ethiopia. Ministry of Water and Energy. |
| [9] | Benvenuti, M., Bonini, M., Moratti, P., & Sani, F. (2002). The Ziway–Shala lake basin (Main Ethiopian Rift, Ethiopia): A revised stratigraphic, pedological and geomorphological framework. Journal of African Earth Sciences, 35(2), 247–269.
https://doi.org/10.1016/S0899-5362(02)00115-6 |
[8, 9] . Stratigraphic Unit | Age | Lithology | Relevance to Diatomite |
Pre-Rift Sequence | Oligocene-Miocene | Plateau basalts, rhyolites | Source of detrital silica |
Syn-Rift Sequence | Late Miocene-Pliocene | Ignimbrites, trachytes | Basin basement, tectonic control |
Main-Rift Sequence | Pleistocene-Holocene | Lacustrine sediments, ash | Primary diatomite host |
Wonji Fault Belt Units | Quaternary | Fissure basalts, pumice | Hydrothermal silica supply |
2. Materials and Methods
The characterization of Ethiopian diatomite resources involves a multi-disciplinary analytical approach designed to evaluate its industrial viability. Research conducted by the Ministry of Mines, the Mineral Industry Development Institute (MIDI), and various academic institutions has established a standard framework for sampling and testing these resources
| [4] | Federal Democratic Republic of Ethiopia (FDRE). (2021). Ten-year development plan: A pathway to prosperity (2021–2030). Planning and Development Commission. Addis Ababa, Ethiopia. |
[4]
.
2.1. Sampling and Preparation
Diatomite samples are typically collected from outcrops, stream sections, and trial pits across major deposit areas like Abiyata and Adami-Tulu. Sampling strategies often follow standard guides such as ASTM D4700-91 to ensure representative data. Once collected, the raw material undergoes physical preparation: Samples are washed to remove soluble impurities and dried at temperatures around 393 K (120°C) to remove moisture. The dried material is ground using alumina ball mills for approximately one hour and sieved through apertures ranging from 45 µm to 63 µm to achieve the desired particle size for analysis
| [14] | Kebede, S., Kaneko, F., & Woldai, T. (2019). Geochemical and physical characterization of diatomite deposits in the Main Ethiopian Rift: Implications for industrial applications. Journal of African Earth Sciences, 158, 103551.
https://doi.org/10.1016/j.jafrearsci.2019.103551 |
| [15] | Kebede, S., Beshah, B., & Liyew, G. G. (2024). Effect of purification and milling parameters on the quality of Ethiopian diatomite for filtration and filler applications. International Journal of Mineral Processing and Extractive Metallurgy, 9(1), 12–28. https://doi.org/10.11648/j.ijmpem.20240901.12 |
[14, 15]
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2.2. Analytical Techniques
To determine the geochemical, mineralogical, and structural properties of the diatomite, several advanced techniques are employed: X-Ray Fluorescence (XRF): Used for the quantitative analysis of major element oxides (e.g., SiO₂, Al₂O₃, Fe₂O₃) and trace elements. X-Ray Diffraction (XRD): Critical for identifying the mineral phases, particularly the amorphous nature of the silica (Opal-A) and the presence of crystalline impurities like quartz or feldspar. Scanning Electron Microscopy (SEM): Provides high-resolution photomicrographs to assess the morphology, size, and preservation of diatom frustules, as well as the nature of the pore structure. Granulometry: Laser particle size analyzers are utilized to determine the particle size distribution, which is essential for assessing the material's suitability as a filter aid or filler
| [14] | Kebede, S., Kaneko, F., & Woldai, T. (2019). Geochemical and physical characterization of diatomite deposits in the Main Ethiopian Rift: Implications for industrial applications. Journal of African Earth Sciences, 158, 103551.
https://doi.org/10.1016/j.jafrearsci.2019.103551 |
[14]
.
2.3. Purification and Modification Methods
Research into value addition has explored specific refining processes: Thermochemical Purification: Raw diatomite is subjected to hot-acid leaching, typically using 6M sulfuric acid (H₂SO₄) at 360–368 K for durations of 24 to 48 hours. This process aims to remove metallic oxides that block the pores. Surface Functionalization: Techniques such as silanization using agents like 3-aminopropyltriethoxysilane (APTS) or n-octyltriethoxysilane (OTS) are applied to introduce hydrophobic or reactive groups to the diatomite surface for wastewater treatment or composite manufacturing
| [16] | Kebede, H., Gemta, A. B., Kassahun, G. B., Andoshe, D. M., & Tadele, K. (2024). Thermochemical purification and geochemical characterization of Ethiopian rift diatomite for industrial applications. ACS Omega, 9(1), 1047–1060.
https://doi.org/10.1021/acsomega.3c07381 |
| [17] | Zhang, Y., Zhao, J., Chu, J., Zhou, Y., Wei, Y., & Tian, Z. (2016). Surface functionalization of diatomite with 3-aminopropyltriethoxysilane and n-octyltriethoxysilane for enhanced wastewater treatment and composite manufacturing. Journal of Alloys and Compounds, 688, 1141–1151.
https://doi.org/10.1016/j.jallcom.2016.07.267 |
[16, 17]
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2.4. Geochemical Characterization
The geochemical profile of Ethiopian diatomite is the primary determinant of its industrial quality. Analysis across several deposits reveals a high-purity siliceous material with varying degrees of volcanic and detrital contamination.
2.4.1. Major Oxide Composition
The predominant constituent of Ethiopian diatomite is silica (SiO₂), which typically ranges from 76.4% to over 86% in its raw form (Ethiopian Ministry of Mines, 2007). The silica content is inversely related to the presence of impurities such as alumina (Al₂O₃), iron oxide (Fe₂O₃), and alkaline oxides (Na₂O, K₂O)
| [3] | Ethiopian Ministry of Mines. (2007). Industrial minerals and rocks of Ethiopia (Draft Report). Addis Ababa, Ethiopia. |
[3]
.
Table 2. Geochemical analysis (wt%) of major diatomite deposits in Ethiopia.
Deposit Location | SiO₂ | Al₂O₃ | Fe₂O₃ | Na₂O | K₂O | CaO | MgO | LOI |
Adami Tulu | 86.70 | 3.36 | 2.20 | 1.63 | 0.84 | 0.14 | 0.22 | 3.66 |
Gada Mota | 85.50 | 3.68 | 2.40 | 1.18 | 0.73 | 1.11 | 0.36 | 3.78 |
Chefe Jilla | 84.50 | 3.14 | 1.50 | 1.64 | 0.78 | 1.89 | 0.72 | 4.68 |
Abiyata (Avg) | 76.40 | 3.47 | 1.10 | 1.52 | 1.11 | 0.67 | 0.10 | 13.7 |
Adami Tulu has the highest silica (SiO₂) content at 86.70%, indicating a relatively pure diatomite deposit. Its low levels of other oxides and moderate loss on ignition (LOI) suggest limited clay mineral impurities and organic content. Gada Mota also shows high silica (85.50%) with slightly elevated alumina (Al₂O₃) and iron oxide (Fe₂O₃), hinting at minor clay and iron impurities. Its calcium oxide (CaO) and LOI are moderate, pointing to some carbonate and volatile content. Chefe Jilla features lower silica (84.50%) and the highest calcium oxide (1.89%) and magnesia (MgO) among the first three, suggesting greater carbonate mineral impurities. Its higher LOI also indicates more bound water or organic matter. Abiyata (Avg) stands out with significantly lower silica (76.40%) and a very high LOI (13.7%), strongly implying a substantial content of clay minerals, organic material, or water. This makes it the least pure of the deposits listed.
2.4.2. Comparative Geochemical Properties of Ethiopian vs. Global Diatomite
Table 3. Comparative Geochemical Properties of Ethiopian vs. Global Diatomite.
Region/Deposit | SiO2 Content (%) | Porosity (%) | Typical Application |
Ethiopian Rift (Adami-Tulu) | 76.4 – 86.7 | 70 – 85 | High-end filtration, Paint, Pharmaceuticals |
USA (California/Nevada) | 85.0 – 90.0 | 75 – 90 | Industrial Filter Aids (Global Standard) |
China (Jilin Province) | 65.0 – 82.0 | 60 – 80 | Construction, Absorbents, Fillers |
Denmark (Moler) | 70.0 – 75.0 | 50 – 65 | Insulation Bricks, Chemical Carriers |
The strategic imperative for domestic processing is underscored by the exceptional geochemical profile of the Ethiopian Rift deposits, which meet or exceed the benchmarks of established global commercial grades. While traditional market leaders like the USA (Celite) and China dominate the high-end filtration sector, geochemical assays of the Adami-Tulu and Abiyata deposits reveal amorphous silica (SiO
2) content reaching up to 86%, coupled with a specific gravity and total porosity that align with premium filter-aid standards. This high SiO
2 purity, characterized by a dominant Opal-A phase, ensures low levels of detrimental impurities like Al
2O
3 and Fe
2O
3, which are often higher in lower-tier global deposits. By leveraging these "world-class" material properties, Ethiopia can transition from a net importer of processed filter media to a competitive regional exporter, directly addressing the trade imbalance identified by the Ethiopian Revenues and Customs Authority
| [12] | Samrock, F., Grayver, A., Eysteinsson, H., & Saar, M. O. (2018). Magnetotelluric image of trans-crustal magmatic system and hydrothermal reservoir beneath the Tulu Moye geothermal prospect, Main Ethiopian Rift. Journal of Geophysical Research: Solid Earth, 123(3), 2035–2052.
https://doi.org/10.1002/2017JB014860 |
| [15] | Kebede, S., Beshah, B., & Liyew, G. G. (2024). Effect of purification and milling parameters on the quality of Ethiopian diatomite for filtration and filler applications. International Journal of Mineral Processing and Extractive Metallurgy, 9(1), 12–28. https://doi.org/10.11648/j.ijmpem.20240901.12 |
| [18] | A. Przybek, M. Łach, M. Hebdowska-Krupa, K. Miernik, and J. Mikuła, "Research of the physical and chemical properties of diatomite as a carrier of phase change materials for use in advanced building materials," Frontiers in Materials, vol. 11, Art. no. 1507779, 2024.
https://doi.org/10.3389/fmats.2024.1507779 |
[12, 15, 18]
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2.4.3. Trace Elements and Impurities
While major oxides define the bulk chemistry, trace constituents like TiO₂ (0.17% - 0.28%), MnO (0.02% - 0.05%), and P₂O₅ (0.34% - 0.62%) are consistently low. The Loss on Ignition (LOI) values, particularly in the Abiyata deposit (13.7% average), are attributed to the presence of structural water, organic matter, and carbonates. High LOI can be problematic for certain high-temperature applications but is typically reduced during calcination processes
| [14] | Kebede, S., Kaneko, F., & Woldai, T. (2019). Geochemical and physical characterization of diatomite deposits in the Main Ethiopian Rift: Implications for industrial applications. Journal of African Earth Sciences, 158, 103551.
https://doi.org/10.1016/j.jafrearsci.2019.103551 |
[14]
.
2.5. Mineralogical Analysis
XRD data confirms that the amorphous phase, Opal-A, is the primary mineral constituent of Ethiopian. This amorphous state is critical for its reactivity in chemical applications and its high porosity. However, the presence of crystalline phases is common, including: Quartz and Feldspar: The most prevalent crystalline impurities, likely derived from air-fall ash or terrestrial runoff. Clay Minerals: Minor amounts of illite, halloysite, and montmorillonite have been detected in various sections. Zeolites and Others: Traces of mordenite, wairakite, and clinoptilolite suggest localized post-depositional alteration or hydrothermal influence
| [14] | Kebede, S., Kaneko, F., & Woldai, T. (2019). Geochemical and physical characterization of diatomite deposits in the Main Ethiopian Rift: Implications for industrial applications. Journal of African Earth Sciences, 158, 103551.
https://doi.org/10.1016/j.jafrearsci.2019.103551 |
| [15] | Kebede, S., Beshah, B., & Liyew, G. G. (2024). Effect of purification and milling parameters on the quality of Ethiopian diatomite for filtration and filler applications. International Journal of Mineral Processing and Extractive Metallurgy, 9(1), 12–28. https://doi.org/10.11648/j.ijmpem.20240901.12 |
[14, 15]
.
2.6. Physical and Structural Properties
The industrial value of diatomite is largely dictated by its unique physical structure, which is a direct consequence of its biogenic origin and geochemical purity
| [3] | Ethiopian Ministry of Mines. (2007). Industrial minerals and rocks of Ethiopia (Draft Report). Addis Ababa, Ethiopia. |
[3]
.
Table 4. Technical and physical properties of Ethiopian diatomites.
Physical Parameter | Abiyata | Adami Tulu | Chefe Jilla |
Porosity (%) | 85.6 | 73.4 | 76.7 |
Bulk Density (g/cm³) | 0.42 | 0.42 | 0.32 |
Shaking Density (g/l) | 169 | 162 | 163 |
Jolting Density (g/l) | 260 | 258 | 268 |
The material possesses exceptional porosity and low bulk density, making it an ideal candidate for filtration and lightweight insulation. SEM investigations reveal that the diatom frustules in these deposits are well-preserved, exhibiting hierarchical pore structures that include both interconnected mesopores and macropores. Micropaleontological studies identify a dominance of pennate diatom forms elongated and bilaterally symmetrical valves which contribute to the material's high specific surface area.
2.7. Industrial and Economic Applications
The unique properties of Ethiopian diatomite make it a versatile raw material for a wide range of established and emerging industries. Its high silica content and structural integrity are utilized across sectors as diverse as food processing, construction, and environmental engineering. Brewery Applications: Major Ethiopian breweries, including Dashen, BGI Ethiopia, St. George, and Habesha, utilize diatomite for beer filtration. During the clarification process, diatomite removes yeast cells and high-molecular-weight proteins, ensuring the clarity and biological stability of the final product. Waste Management: The byproduct of this process, known as diatomaceous earth sludge (DES) or brewery spent diatomaceous earth (BSDE), presents its own opportunities. Research has shown that DES can be reused as a modifier for asphalt binders, improving the rutting resistance and stiffness of pavements. Diatomite's low thermal conductivity and lightweight nature are highly valued in the construction materials sector.
| [18] | A. Przybek, M. Łach, M. Hebdowska-Krupa, K. Miernik, and J. Mikuła, "Research of the physical and chemical properties of diatomite as a carrier of phase change materials for use in advanced building materials," Frontiers in Materials, vol. 11, Art. no. 1507779, 2024.
https://doi.org/10.3389/fmats.2024.1507779 |
[18]
Insulating Bricks and Tiles: It is used in the production of lightweight, heat-resistant bricks and thermal insulation for industrial furnaces and energy-efficient buildings. Cement and Pozzolans: Diatomite acts as a pozzolanic additive in cement and concrete formulations. Replacing a portion of Portland cement with diatomite can improve sulfate resistance and reduce the dry unit weight of the concrete, which is beneficial for high-rise or seismic-resistant structures
| [19] | Li, J., Zhang, W., Li, C., & Monteiro, P. J. M. (2019). Green concrete containing diatomaceous earth and limestone: Workability, mechanical properties, and life-cycle assessment. Journal of Cleaner Production, 223, 672–679.
https://doi.org/10.1016/j.jclepro.2019.03.077 |
[19]
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Agriculture and Chemical Carriers: The high absorptive capacity of diatomite (up to several times its own weight) makes it an effective carrier for liquid and solid chemicals. Agrochemical Carriers: Diatomite is used as a carrier for pesticides and fertilizers, allowing for a more controlled release of active ingredients and preventing their leaching into groundwater Soil Amendment: In agriculture, diatomite is applied to improve soil structure, increase aeration, and enhance the water-holding capacity of sandy or degraded soils. Trials using brewery-spent diatomite have shown it to be a safe organic fertilizer that can enhance cereal yields such as teff and wheat. Chemical and Industrial Fillers: Due to its inertness, brightness, and high surface area, diatomite is common filler in various manufacturing processes: Paints and Plastics: It serves as a functional filler to control gloss, improve durability, and enhance the mechanical properties of polymers. Abrasives and Polishing: The skeletal remains are hard yet fragile, making diatomite a gentle abrasive used in toothpaste and specialized metal polishes
| [14] | Kebede, S., Kaneko, F., & Woldai, T. (2019). Geochemical and physical characterization of diatomite deposits in the Main Ethiopian Rift: Implications for industrial applications. Journal of African Earth Sciences, 158, 103551.
https://doi.org/10.1016/j.jafrearsci.2019.103551 |
| [20] | Dessalew, G., Beyene, A., Nebiyu, A., & Ruelle, M. L. (2017). Use of industrial diatomite wastes from beer production to improve soil fertility and cereal yields. Journal of Cleaner Production, 157, 22–29.
https://doi.org/10.1016/j.jclepro.2017.04.093 |
[14, 20]
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2.8. Value Addition Opportunities
The transition from exporting raw diatomite to producing high-value engineered products is a strategic imperative for Ethiopia's industrial minerals sector. Recent research has identified several cutting-edge applications that leverage the unique hierarchical structure of diatomite. Advanced 3D Concrete Printing and Carbon Capture.
A transformative application of diatomite has emerged in the field of 3D concrete printing (3DCP). Researchers have developed sustainable concrete mixes that incorporate diatomaceous earth to achieve superior environmental and mechanical performance. Carbon Sequestration: The sponge-like hierarchical porosity of diatomite (ranging from 2 to 100 nm) provides numerous active sites to trap CO₂. When used in 3D-printed Triply Periodic Minimal Surface (TPMS) structures which maximize surface-area-to-volume ratios these mixes can capture 142% more CO₂ than traditional concrete. Structural Integrity: Unlike many porous additives that weaken concrete, the pozzolanic reaction between diatomite silica and calcium hydroxide creates additional calcium silicate hydrate (C-S-H) gel, increasing compressive strength over time (peaking at over 30 MPa).
| [19] | Li, J., Zhang, W., Li, C., & Monteiro, P. J. M. (2019). Green concrete containing diatomaceous earth and limestone: Workability, mechanical properties, and life-cycle assessment. Journal of Cleaner Production, 223, 672–679.
https://doi.org/10.1016/j.jclepro.2019.03.077 |
[19]
Diatomite is also being utilized as a natural carrier for Phase Change Materials (PCMs) in geopolymer foams for energy-efficient construction. Thermal Efficiency: Encapsulating PCMs like paraffin within the porous structure of diatomite ensures stability and environmental compatibility. These composites can increase the specific heat capacity of building materials by nearly 50%, allowing for effective thermal energy storage and regulation. Sound Absorption: The interconnected pore network of diatomite-loaded foams significantly improves sound absorption properties, making them ideal for high-performance acoustic insulation. 3D Printing Filaments and Polymer Composites In the polymer industry, diatomite is being investigated as a renewable filler for 3D printing filaments, such as those based on polylactic acid (PLA). Cost and Performance: Replacing 10 wt% of PLA with diatomite can reduce filament costs by 5% to 10% with only minor mechanical setbacks. Furthermore, post-processing techniques like cold hydrostatic extrusion can nearly double the compressive strength of these composites by mitigating crack initiation through pore closure. Functional Agents: The high surface area of diatomite protruding from printed objects provides a platform for immobilizing chemical sensors, as well as antibacterial and antiviral agents
| [21] | Aggarwal, S., Singh, P., & Kumar, A. (2019). Development of diatomaceous earth-filled poly (lactic acid) composites for 3D printing filaments. Journal of Applied Polymer Science, 136(12), 47221. https://doi.org/10.1002/app.47221 |
[21]
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Modified diatomite presents a low-cost, eco-friendly solution for Ethiopia's water quality challenges: Fluoride Removal: Diatomite modified with aluminum hydroxide has shown exceptional results in removing fluoride from drinking water in the Rift Valley, reaching removal efficiencies of 89.4%.
| [22] | Wang, S., He, J., Chen, Z., Jiang, Q., Li, S., & Wang, J. (2020). Aluminum-modified diatomite for fluoride removal from groundwater in the Ethiopian Rift Valley. Journal of Hazardous Materials, 384, 121350.
https://doi.org/10.1016/j.jhazmat.2019.121350 |
[22]
Heavy Metal Sequestration: Surface functionalization with silane coupling agents (e.g., APTS, KH-570) allows for the creation of composites capable of the time- and cost-efficient removal of heavy metals like lead and cadmium, as well as volatile organic compounds like formaldehyde
| [23] | Zhang, Y., Zhao, J., & Liu, Z. (2016). Surface functionalization of diatomite with silane coupling agents for heavy metal ion sequestration. Microporous and Mesoporous Materials, 225, 100–108. https://doi.org/10.1016/j.micromeso.2015.12.003 |
[23]
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2.9. Strategic Economic Applications
Ethiopia's diatomite resources are a central component of its strategy for industrialization and self-reliance. The economic rationale for developing these resources is built upon import substitution, job creation, and export diversification.
Import Substitution and Trade Balance
Despite possessing massive reserves, Ethiopia is a net importer of processed diatomite. Data from the Ethiopian Revenues and Customs Authority highlights a persistent reliance on foreign supply to support domestic industries like brewing and paint manufacturing
| [3] | Ethiopian Ministry of Mines. (2007). Industrial minerals and rocks of Ethiopia (Draft Report). Addis Ababa, Ethiopia. |
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Table 5. Diatomite supply and import trends in Ethiopia (2014–2023).
Year | Imported Quantity (Tons) | Imported Value (1000 USD) | Domestic Production (Tons) | Total Consumption (Tons) |
2014 | 295 | 287 | 4,600 | 4,895 |
2016 | 387 | 298 | 5,000 | 5,387 |
2018 | 517 | 470 | 5,000 | 5,517 |
2020 | 210 | 191 | 5,000 | 5,210 |
2022 | 259 | 255 | 5200 | 5455 |
2023 | 58 | 83 | 5410 | 5493 |
The average annual expenditure on diatomite imports from 2014 to 2023 was approximately 300,700$. Establishing local milling and thermochemical purification facilities would not only save this foreign currency but also insulate domestic industries from global supply chain disruptions and exchange rate volatility.
In alignment with global market dynamics, Ethiopia’s current production of approximately 5,400 tons while showing steady growth remains a marginal fraction of a worldwide market projected to reach USD 3.16 billion by 2034. Globally, the industry is dominated by the United States (32%), Denmark (17%), and China (10%), which leverage advanced calcination technologies to meet the 54% of global demand concentrated in the high-grade filtration sector. The discrepancy between Ethiopia's massive high-grade reserves (estimated at over 40 million tons) and its persistent net importer status highlights a strategic opportunity to capture the 5.3% annual global growth rate, particularly as demand surges in Asia-Pacific and North America for sustainable water treatment and eco-friendly construction additives. By transitioning from raw extraction to domestic value-added processing (calcination), Ethiopia can shift from a dependency on foreign supply to becoming a competitive regional supplier, transforming a trade deficit into a strategic industrial advantage
| [3] | Ethiopian Ministry of Mines. (2007). Industrial minerals and rocks of Ethiopia (Draft Report). Addis Ababa, Ethiopia. |
[3]
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Strategic Development Goals
The mining sector is a priority under Ethiopia's 10-Year Perspective Development Plan (2021–2030) and the Homegrown Economic Reform program. GDP Contribution: The government aims to increase the mining sector's contribution to GDP from the current 2% to 14% by 2030.
| [24] | Federal Democratic Republic of Ethiopia (FDRE), "Ethiopia 2030: An African beacon of prosperity: Ten-year perspective development plan (2021–2030)," Planning and Development Commission, Addis Ababa, 2021. |
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Export Earnings: Mining is projected to account for 37% of export earnings by 2030. High-grade diatomite from the central rift is seen as a commodity with significant regional export potential to markets like India and the East African Community.
| [25] | HornReview, "Ethiopia’s mining boom: Projections for 2030 and regional export dynamics," The Horn Review, Jan. 2025. |
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Employment: The sector is expected to expand its workforce significantly, providing skilled and semi-skilled employment for millions of citizens.
| [24] | Federal Democratic Republic of Ethiopia (FDRE), "Ethiopia 2030: An African beacon of prosperity: Ten-year perspective development plan (2021–2030)," Planning and Development Commission, Addis Ababa, 2021. |
[24]
To realize this potential, the Ethiopian government has implemented a series of reforms designed to attract private investment: Legal Protections: The Mining Proclamation No. 678/2010 provides security of tenure and allows for the deduction of exploration and development costs.
| [26] | Federal Democratic Republic of Ethiopia (FDRE), "Mining Proclamation No. 678/2010," Negarit Gazeta, Addis Ababa, 2010. |
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Financial Incentives: Investors benefit from a competitive income tax rate (35%), a duty-free import regime for capital goods, and lower royalty rates compared to precious metals. Geoscience Data: The Ministry of Mines is focused on generating and disseminating high-quality geological data to reduce exploration risk for potential developers
| [24] | Federal Democratic Republic of Ethiopia (FDRE), "Ethiopia 2030: An African beacon of prosperity: Ten-year perspective development plan (2021–2030)," Planning and Development Commission, Addis Ababa, 2021. |
[24]
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Environmental and Sustainability Considerations
The exploitation of diatomite resources within the Main Ethiopian Rift (MER) necessitates a robust geodynamic and environmental framework to safeguard the region’s unique lacustrine ecosystems. Primary deposits, notably those in the Abiyata and Adami-Tulu sectors, are situated in high-sensitivity zones within or adjacent to the Abiyata-Shala Lakes National Park (ASLNP). Hydrological modeling indicates extreme sensitivity to anthropogenic stressors; industrial water abstraction primarily for soda ash extraction and potential diatomite beneficiation has exacerbated lacustrine regression, with Lake Abiyata’s surface area contracting by approximately 50% over the last five decades
| [8] | Japan International Cooperation Agency (JICA). (2012). The study on Rift Valley Lakes Basin integrated resources management master plan in the Federal Democratic Republic of Ethiopia. Ministry of Water and Energy. |
[8]
. This hydrological instability triggers a trophic cascade: fluctuations in salinity and depth threaten the specialized habitats of migratory avifauna, specifically the lesser flamingo (Phoeniconaias minor) and great white pelican (Pelecanus onocrotalus), and have precipitated a collapse in indigenous fisheries. To mitigate these impacts, industrial operations must implement closed-loop water recycling systems to eliminate raw water withdrawal and adopt progressive backfilling during the extraction phase to prevent groundwater contamination and surface runoff. Furthermore, the application of geosynthetic clay liners (GCLs) in processing waste-ponds is essential to prevent the leaching of alkaline effluents into the rift’s fragile groundwater system, thereby ensuring that mineral extraction aligns with sustainable hydrogeological management
| [27] | Federal Democratic Republic of Ethiopia (FDRE). (2002). Environmental Impact Assessment Proclamation: Proclamation No. 299/2002. Federal Negarit Gazeta. |
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Regulatory and Policy Landscape: The Ethiopian government has established a comprehensive regulatory framework to manage the environmental impacts of mining: Environmental Impact Assessments (EIA): Under Proclamation No. 299/2002 and the Mining Operations Proclamation, any small- or large-scale project that alters the environment must obtain an approved EIA before receiving a license.
| [28] | De Haan, J., Dales, K., & McQuilken, J. (2020). Mapping artisanal and small-scale mining to the Sustainable Development Goals. University of Delaware; Pact.
https://doi.org/10.2139/ssrn.3532756 |
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Artisanal and Small-Scale Mining (ASM): While ASM is a critical livelihood source; its informal nature often bypasses formal environmental oversight. This has resulted in localized land degradation, deforestation, and the siltation of watercourses. Current policy aims to formalize the ASM sector, providing miners with technical support and "Simple Environmental Information Sheets" to encourage responsible practices
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To ensure that diatomite development aligns with the "African Beacon of Prosperity" vision, several sustainable practices are recommended: Selective Surface Mining: Mining operations should minimize the total surface area exposed at any one time to reduce habitat disruption. Progressive Reclamation: Disturbed areas should be reclaimed and revegetated with native species. Diatomaceous earth makes an excellent growing medium, facilitating the restoration of forested or grassland ecosystems within 10 years of site closure. Advanced Pollution Control: Modern processing facilities must implement dust control (e.g., baghouses) and water treatment systems (e.g., siltation ponds) to ensure that emissions and runoff comply with national standards
| [28] | De Haan, J., Dales, K., & McQuilken, J. (2020). Mapping artisanal and small-scale mining to the Sustainable Development Goals. University of Delaware; Pact.
https://doi.org/10.2139/ssrn.3532756 |
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3. Conclusion
The characterization of diatomite resources in the Ethiopian Rift System reveals a clear paradox: Ethiopia possesses world-class deposits of a versatile industrial mineral, yet it remains a minor player in the global market and a net importer for its own domestic needs. This situation is driven by a lack of integrated industrial infrastructure and the historical prioritization of metallic minerals. From a geochemical perspective, the Ethiopian deposits are of moderate to high quality. The raw SiO₂ content of 84% - 86% in the Lakes Region is highly competitive, and the successful application of hot-acid leaching to reach 96% purity demonstrates that these resources can be upgraded for high-end pharmaceutical and catalyst applications. The dominance of pennate diatom species and the high porosity of the material further confirm its suitability as a premium filter aid.
The potential for value addition is perhaps the most compelling argument for a revitalized diatomite industry. The integration of diatomite into 3D concrete printing not only addresses Ethiopia's infrastructure needs but also positions the country as an innovator in carbon sequestration technology. Furthermore, the reuse of brewery waste as a soil conditioner or asphalt modifier illustrates the potential for circular economy practices that reduce the environmental footprint of existing industries.
However, the strategic expansion of this sector faces significant hurdles. The most immediate challenge is the location of major deposits in ecologically sensitive zones. The ongoing desiccation of Lake Abiyata serves as a stark reminder of the consequences of unsustainable resource extraction. Any future diatomite mining must be governed by a rigorous "Triple Bottom Line" approach balancing economic gain with social welfare and environmental protection This requires not only stricter enforcement of EIA regulations but also the adoption of cleaner, water-efficient processing technologies. Economically, the path forward requires bridging the gap between mining and manufacturing. The 10-Year Development Plan provides the vision, but implementation will depend on attracting foreign direct investment (FDI) and fostering partnerships between academia and the private sector. By simplifying export procedures and incentivizing local value addition, Ethiopia can transform its diatomite from a dormant resource into a strategic economic pillar. This comprehensive review has established that the diatomite resources of the Ethiopian Rift System possess significant industrial potential and geochemical merit. With over 46 million tons of reserves characterized by high silica purity and exceptional physical properties, these deposits are well-suited for a broad range of applications, from traditional beer filtration and thermal insulation to cutting-edge carbon sequestration and geopolymer synthesis.
The strategic importance of these resources lies in their ability to drive Ethiopia's import substitution agenda and contribute to the ambitious 14% GDP target for the mining sector by 2030. However, the successful development of the diatomite industry will require a shift from the extraction of raw materials to the production of high-value, refined industrial products.
To achieve this, it is recommended that the Ethiopian government and industrial stakeholders: Prioritize the establishment of domestic milling and thermochemical purification facilities to meet the quality standards of the brewery and pharmaceutical sectors. Promote the adoption of 3D concrete printing and sustainable building technologies that utilize diatomite to address national infrastructure and climate goals. Implement a rigorous environmental management framework for the Lakes Region that includes progressive reclamation, water conservation, and the formalization of artisanal mining practices. Enhance international collaborations to access the technologies and markets necessary for high-value diatomite exports. By integrating geological abundance with technological innovation and sustainable management, Ethiopia can effectively leverage its diatomite resources to foster long-term industrial growth and environmental stewardship.