The history of the formation and development of the theory of chain reactions is briefly presented. In specific examples the mechanisms of branched chain processes, conditions inhibiting and accelerating chain reactions, criteria characterizing the chain nature of chemical processes are described. The modern state in the development of the theory of chain reactions is analyzed. The mechanisms describing regularities of formation of molecular products of the chain processes occurring in different systems with the use of different initiators at different conditions are discussed. A summary of the radical-chain character of the radiation sewing of elastomers /non stitched rubbers/ at high pressures (2 GPa) and at temperatures above 300°K is provided and the ionic character of this process at low temperatures (77°K) has been studied. Mechanisms of photolythic and radiolytic processes transformations of any organic pollutants and natural toxins in oxygen-free and oxygen-containing aqueous solutions are proposed. Significant decomposition of natural toxins is observed under influence of ionizing radiation of 60Co source. The short description of the revealed chain processes proceeding in gaseous, liquid, amorphous and solid phases is provided. These studies are an essential contribution to researches in the field of studying of chain chemical processes.
| Published in | Journal of Energy, Environmental & Chemical Engineering (Volume 2, Issue 4) |
| DOI | 10.11648/j.jeece.20170204.12 |
| Page(s) | 67-75 |
| Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
| Copyright |
Copyright © The Author(s), 2018. Published by Science Publishing Group |
Theory of Chain Reactions, Active Centers, Initiation of Chain Reactions, Photolytic and Radiolytic Conversion, Gas-Phase Mixtures, Water Solutions
| [1] | Luis B, Elbe G. Burning, flames and explosions in gases. State Publishing House of Foreign Liter. Moscow, 1948, 438 p. |
| [2] | Zeldovich Y. B., Barenblatt G. I., Librovich V. B., Mihvizladze G. M. Mathematical theory of combustion and explosion. M.: Nauka, 1980. 478 p. |
| [3] | Moshkin P. A. Oxidation of hydrocarbons in the liquid phase. Moscow: Publishing House of the Academy of Sciences. 1959. pp. 255-267. |
| [4] | Emanuel N. M., Zaikov G. E., Kritsman V. A. Chain reactions. Historical aspect. Moscow: Nauka, 1989, 335 p. |
| [5] | Semenov N. N. On some problems of chemical kinetics and reactivity: Free radicals and chain reactions. Moscow: Publishing House of the Academy of Sciences. 1958. 686 p. |
| [6] | Denisova L. N., Denisov E. T., Metelitsa D. I. Oxidation of phenol and naphthols with molecular oxygen // News of AS of SSSR. Ser. Chem., 1969, No. 8, pp. 1657-1663. |
| [7] | Talroze V. L On the theory of radiation-chemical initiation of chain reactions. Chemistry of high energies. 1974. Vol. 8, No. 6, pp. 519-527. |
| [8] | Dzantiev B. G., Ermakov A. N., Shitomirsky B. M., Popov V. M. Kinetik and mechanism of thermoradiation on the water vapour and its mixture with acceptors. Radiation Physical Chemistry, 1985, V. 26, N: 5, pp. 559-562. |
| [9] | Klinshpont E. R., Kiryukhin V. P., Milinchuk V. K. Radiation chemical processes in polymers at high pressures. M.: NIITECHIM. 1982. 49 p. |
| [10] | Kurbanov M. A., Iskenderova Z. I., Dzantiev B. G., Mamedov Kh. F. Chain transformations in the radiolysis of gas-phase mixtures of CO2-H2. Chemistry № 1, 1986, pp. 135-136. |
| [11] | Mamedov Kh. F. Effective processes of decomposition of xenobiotics and natural toxins. Radiolytic and photolytic decomposition of xenobiotics and mycotoxins. LAP LAMBERT Academic Publishing, Heinrich-Bocking Str. 6-8, Saarbrucken, Germany, 2014, 419 p. |
| [12] | Safaric I, Strausz O. P. The reactions of hydrogen atom with organosulfur compounds. Rew. Chem. Int., 1985. V. 6. pp. 143-173. |
| [13] | Mamedov Kh. F. Radiolysis and photolysis of water solutions of phenol. European Researcher. 2014, V. 78. N: 7-1. pp. 1216-1236. |
| [14] | Mamedov Kh. F. Radiolytic transformation of natural toxins in contaminated plant products and aqueous solutions. Sci. J. "Science Rise". 2014. N: 4/2 (4). pp. 116-121. |
| [15] | Tiwari B., Brennan C., Curran T., Gallagher E., Cullen P., O’Donnell C. Application of ozone in grain processing. J. Cereal Sci., 2010, 51: 248-255. |
| [16] | Duarte S., Pena A., Lino C. A review on ochratoxin A occurrence and effects of processing of cereal and cereal derived food products. Food Microbiol., 2010, 27: 187-198. |
| [17] | He J., Zhou T., Young J., Boland G., Scott P. Chemical and biological transformations for detoxifications of trichothecene mycotoxins in human and animal food chains: a review. Trends Food Sci. Technol., 2010, 21: 67-76. |
| [18] | Pikaev A. Modern Radiation Chemistry: Radiolysis gases and liquids. Moscow: Nauka, 1986, pp. 91-125. |
| [19] | Mogilevich M., Pliss E. Oxidation and oxidative polymerization of unsaturated compounds. Moscow: Khimiya, 1990, pp. 188-230. |
| [20] | Roginskiy V. Phenolic antioxidants. Moscow: Nauka, 1988, pp. 17-191. |
| [21] | Neta P., Grodkowski J. Rate constants for reaction of phenoxyl radicals in solution. J. Phys. Chem. Ref. Data, 2005, 34: 109-199. |
APA Style
Khagani Farzulla Mammadov. (2018). Development the Theory of Chain Reactions and Analysis of Relatively Recently Studied Chain Processes. Journal of Energy, Environmental & Chemical Engineering, 2(4), 67-75. https://doi.org/10.11648/j.jeece.20170204.12
ACS Style
Khagani Farzulla Mammadov. Development the Theory of Chain Reactions and Analysis of Relatively Recently Studied Chain Processes. J. Energy Environ. Chem. Eng. 2018, 2(4), 67-75. doi: 10.11648/j.jeece.20170204.12
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Download@article{10.11648/j.jeece.20170204.12,
author = {Khagani Farzulla Mammadov},
title = {Development the Theory of Chain Reactions and Analysis of Relatively Recently Studied Chain Processes},
journal = {Journal of Energy, Environmental & Chemical Engineering},
volume = {2},
number = {4},
pages = {67-75},
doi = {10.11648/j.jeece.20170204.12},
url = {https://doi.org/10.11648/j.jeece.20170204.12},
eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.jeece.20170204.12},
abstract = {The history of the formation and development of the theory of chain reactions is briefly presented. In specific examples the mechanisms of branched chain processes, conditions inhibiting and accelerating chain reactions, criteria characterizing the chain nature of chemical processes are described. The modern state in the development of the theory of chain reactions is analyzed. The mechanisms describing regularities of formation of molecular products of the chain processes occurring in different systems with the use of different initiators at different conditions are discussed. A summary of the radical-chain character of the radiation sewing of elastomers /non stitched rubbers/ at high pressures (2 GPa) and at temperatures above 300°K is provided and the ionic character of this process at low temperatures (77°K) has been studied. Mechanisms of photolythic and radiolytic processes transformations of any organic pollutants and natural toxins in oxygen-free and oxygen-containing aqueous solutions are proposed. Significant decomposition of natural toxins is observed under influence of ionizing radiation of 60Co source. The short description of the revealed chain processes proceeding in gaseous, liquid, amorphous and solid phases is provided. These studies are an essential contribution to researches in the field of studying of chain chemical processes.},
year = {2018}
}
TY - JOUR T1 - Development the Theory of Chain Reactions and Analysis of Relatively Recently Studied Chain Processes AU - Khagani Farzulla Mammadov Y1 - 2018/01/19 PY - 2018 N1 - https://doi.org/10.11648/j.jeece.20170204.12 DO - 10.11648/j.jeece.20170204.12 T2 - Journal of Energy, Environmental & Chemical Engineering JF - Journal of Energy, Environmental & Chemical Engineering JO - Journal of Energy, Environmental & Chemical Engineering SP - 67 EP - 75 PB - Science Publishing Group SN - 2637-434X UR - https://doi.org/10.11648/j.jeece.20170204.12 AB - The history of the formation and development of the theory of chain reactions is briefly presented. In specific examples the mechanisms of branched chain processes, conditions inhibiting and accelerating chain reactions, criteria characterizing the chain nature of chemical processes are described. The modern state in the development of the theory of chain reactions is analyzed. The mechanisms describing regularities of formation of molecular products of the chain processes occurring in different systems with the use of different initiators at different conditions are discussed. A summary of the radical-chain character of the radiation sewing of elastomers /non stitched rubbers/ at high pressures (2 GPa) and at temperatures above 300°K is provided and the ionic character of this process at low temperatures (77°K) has been studied. Mechanisms of photolythic and radiolytic processes transformations of any organic pollutants and natural toxins in oxygen-free and oxygen-containing aqueous solutions are proposed. Significant decomposition of natural toxins is observed under influence of ionizing radiation of 60Co source. The short description of the revealed chain processes proceeding in gaseous, liquid, amorphous and solid phases is provided. These studies are an essential contribution to researches in the field of studying of chain chemical processes. VL - 2 IS - 4 ER -
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