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Inter-Laboratory Study for the Asbestos Detection in Bulk Materials: First Italian Scheme

Received: 2 May 2018     Accepted: 29 May 2018     Published: 19 June 2018
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Abstract

Italian Health Ministry established by regulation the minimum requirements for laboratories intending to perform asbestos analysis and the organization of a quality control scheme to which the laboratories must refer. Three proficiency testing schemes for asbestos detection in bulk materials using polarized light microscopy (PLM), X-ray diffraction (XRD) and Fourier Transform Infrared Spectroscopy (FTIR) were developed according to the regulation of Health Ministry. The schemes were organized in rounds. In each round the laboratory received one batch of 4 samples. The participant laboratories were 475. The performance of laboratory as satisfactory, unsatisfactory or awaiting classification. The samples of the rounds were real world materials from abatement project and might contain any of the asbestos types. Ceiling-tile containing vitreous fibers caused the highest frequency of false positive; 87% of errors incurred in FTIR and 60% in XRD. Vinyl-floor tiles caused most false negative; 100% of errors incurred in PLM in the second pilot program, 13% in FTIR and 10% in XRD. One of the main factors causing variability of results turned out to be related to the skill of the analysts. Training and experience of the analysts help to get a reliable and reproducible asbestos analysis.

Published in International Journal of Science and Qualitative Analysis (Volume 4, Issue 3)
DOI 10.11648/j.ijsqa.20180403.15
Page(s) 93-99
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2018. Published by Science Publishing Group

Keywords

Asbestos Containing Materials, Quality Control Scheme, PLM, XRD, FTIR

References
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[2] McCaughey W. T. E. (1958). Primary tumors of the pleura. J. Path. Bact. 76, 517-529.
[3] Bader M. E.; Bader R. A., Tierstein A. S., J. Sclikoff (1965). Pulmonary function in asbestosis: serial tests in a long term prospective study. Ann. NY Acad. Sci. 132, 391-405.
[4] Wagner J. C. (1965) Epidemiology of diffuse mesothelial tumors. Ann. NY Acad. Sci. 132, 575-578.
[5] Rom W. N. (1998) Asbestos-related Disease. In: Environmental & Occupational Medicine, 3rd edition, (Lippincott-Raven Publishers) Philadelphia, pp. 349-375.
[6] Kalnas, J. (2000) Diagnosis and risk of asbestos-related diseases in an era of decreasing exposure. In: Peters & Peters, editors, Asbestos Disease Control, vol. 21, (LEXIS Publishing) 339-381.
[7] International Agency for research on Cancer (IARC) (2017) Agents classified by the monographs.. Lyon, France. vol 1-117.
[8] Health and Safety Executive (HSE) (2012) Asbestos: The survey guide. HSE Books ISBN 978 0 7176 6502.
[9] Kwon J., K. Jangt, E. Hwang, Ki-Woong Kim (2017) Development of the KOSHA Proficiency testing scheme on asbestos analysis in Korea. Safety and Health at Work. 8, 318-321.
[10] American industrial Hygiene Association (AIHA) (cited May 2018). Available from https://www.aihapat.org/Programs/BAPAT/Pages/default.aspx
[11] Health and Safety Laboratory (HSL) ((cited May 2018). Available from https://www.hsl.gov.uk/proficiency-testing-schemes
[12] Italian Ministry of Health, DM 14 May 1996: Normative e metodologie tecniche per gli interventi di bonifica, ivi compresi quelli per rendere innocuo l’amianto, previsti dall’art. 5, comma 1, lettera f), della legge 27 marzo 1992, n. 257, recante norme relative alla cessazione dell’impiego dell’amianto. Gazzetta Ufficiale della Repubblica Italiana n. 251, 25 October 1996.
[13] Verein Deutscher Ingenieure (VDI), (2001) Determination of asbestos in technical products. Infrared spectroscopy method. VDI 3866 Part 2. October.
[14] McCrone W. C. (1996) Detection and identification of asbestos by microscopical dispersion staining. Environ Health Perspective 9, 57-61.
[15] Ganotes J. T., H. T. Tan (1980). Asbestos identification by dispersion staining microscopy. American Industrial Hygiene Association Journal 41(1), 70-3.
[16] Crane D.T. (1992). Polarized light microscopy of asbestos. Method number ID 191. Salt Lake City, UT: Occupational Safety & Health Administration.
Cite This Article
  • APA Style

    Antonella Campopiano, Angelo Olori, Biagio Maria Bruni, Luciano Benini, Mauro Campanella, et al. (2018). Inter-Laboratory Study for the Asbestos Detection in Bulk Materials: First Italian Scheme. International Journal of Science and Qualitative Analysis, 4(3), 93-99. https://doi.org/10.11648/j.ijsqa.20180403.15

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    ACS Style

    Antonella Campopiano; Angelo Olori; Biagio Maria Bruni; Luciano Benini; Mauro Campanella, et al. Inter-Laboratory Study for the Asbestos Detection in Bulk Materials: First Italian Scheme. Int. J. Sci. Qual. Anal. 2018, 4(3), 93-99. doi: 10.11648/j.ijsqa.20180403.15

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    AMA Style

    Antonella Campopiano, Angelo Olori, Biagio Maria Bruni, Luciano Benini, Mauro Campanella, et al. Inter-Laboratory Study for the Asbestos Detection in Bulk Materials: First Italian Scheme. Int J Sci Qual Anal. 2018;4(3):93-99. doi: 10.11648/j.ijsqa.20180403.15

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  • @article{10.11648/j.ijsqa.20180403.15,
      author = {Antonella Campopiano and Angelo Olori and Biagio Maria Bruni and Luciano Benini and Mauro Campanella and Fulvio Cavariani and Adriano Fava and Patrizia Garofani and Luigi Leone and Claudio Martinelli and Mariano Alessi},
      title = {Inter-Laboratory Study for the Asbestos Detection in Bulk Materials: First Italian Scheme},
      journal = {International Journal of Science and Qualitative Analysis},
      volume = {4},
      number = {3},
      pages = {93-99},
      doi = {10.11648/j.ijsqa.20180403.15},
      url = {https://doi.org/10.11648/j.ijsqa.20180403.15},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijsqa.20180403.15},
      abstract = {Italian Health Ministry established by regulation the minimum requirements for laboratories intending to perform asbestos analysis and the organization of a quality control scheme to which the laboratories must refer. Three proficiency testing schemes for asbestos detection in bulk materials using polarized light microscopy (PLM), X-ray diffraction (XRD) and Fourier Transform Infrared Spectroscopy (FTIR) were developed according to the regulation of Health Ministry. The schemes were organized in rounds. In each round the laboratory received one batch of 4 samples. The participant laboratories were 475. The performance of laboratory as satisfactory, unsatisfactory or awaiting classification. The samples of the rounds were real world materials from abatement project and might contain any of the asbestos types. Ceiling-tile containing vitreous fibers caused the highest frequency of false positive; 87% of errors incurred in FTIR and 60% in XRD. Vinyl-floor tiles caused most false negative; 100% of errors incurred in PLM in the second pilot program, 13% in FTIR and 10% in XRD. One of the main factors causing variability of results turned out to be related to the skill of the analysts. Training and experience of the analysts help to get a reliable and reproducible asbestos analysis.},
     year = {2018}
    }
    

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  • TY  - JOUR
    T1  - Inter-Laboratory Study for the Asbestos Detection in Bulk Materials: First Italian Scheme
    AU  - Antonella Campopiano
    AU  - Angelo Olori
    AU  - Biagio Maria Bruni
    AU  - Luciano Benini
    AU  - Mauro Campanella
    AU  - Fulvio Cavariani
    AU  - Adriano Fava
    AU  - Patrizia Garofani
    AU  - Luigi Leone
    AU  - Claudio Martinelli
    AU  - Mariano Alessi
    Y1  - 2018/06/19
    PY  - 2018
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    DO  - 10.11648/j.ijsqa.20180403.15
    T2  - International Journal of Science and Qualitative Analysis
    JF  - International Journal of Science and Qualitative Analysis
    JO  - International Journal of Science and Qualitative Analysis
    SP  - 93
    EP  - 99
    PB  - Science Publishing Group
    SN  - 2469-8164
    UR  - https://doi.org/10.11648/j.ijsqa.20180403.15
    AB  - Italian Health Ministry established by regulation the minimum requirements for laboratories intending to perform asbestos analysis and the organization of a quality control scheme to which the laboratories must refer. Three proficiency testing schemes for asbestos detection in bulk materials using polarized light microscopy (PLM), X-ray diffraction (XRD) and Fourier Transform Infrared Spectroscopy (FTIR) were developed according to the regulation of Health Ministry. The schemes were organized in rounds. In each round the laboratory received one batch of 4 samples. The participant laboratories were 475. The performance of laboratory as satisfactory, unsatisfactory or awaiting classification. The samples of the rounds were real world materials from abatement project and might contain any of the asbestos types. Ceiling-tile containing vitreous fibers caused the highest frequency of false positive; 87% of errors incurred in FTIR and 60% in XRD. Vinyl-floor tiles caused most false negative; 100% of errors incurred in PLM in the second pilot program, 13% in FTIR and 10% in XRD. One of the main factors causing variability of results turned out to be related to the skill of the analysts. Training and experience of the analysts help to get a reliable and reproducible asbestos analysis.
    VL  - 4
    IS  - 3
    ER  - 

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Author Information
  • Department of Medicine, Epidemiology, Occupational and Environmental Hygiene, National Institute for Insurance against Accidents at Work (INAIL), Monte Porzio Catone, Rome, Italy

  • Department of Medicine, Epidemiology, Occupational and Environmental Hygiene, National Institute for Insurance against Accidents at Work (INAIL), Monte Porzio Catone, Rome, Italy

  • Department of Technology and Health, National Health Institute (ISS), Rome, Italy

  • Asbestos Regional Center of Marche, ARPAM Pesaro, Italy

  • Asbestos Regional Center of Abruzzo, ARTA Teramo, Italy

  • Asbestos Regional Center of Lazio, ASL Viterbo, Italy

  • Asbestos Regional Center of Emilia Romagna, ARPA Reggio Emilia, Italy

  • Asbestos Regional Center of Umbria, AUSL 2 Assisi, Italy

  • Asbestos Regional Center of Basilicata, ARPAB Potenza, Italy

  • Asbestos Regional Center of Veneto, ARPA Verona, Italy

  • General Direction of Health Prevention, Italian Ministry of Health, Rome, Italy

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