Selective Separation of Organic Electrolytes by Neutralization Dialysis with Grafted Polyethylene Films

Yuji Kimura; Kazunori Yamada

doi:doi:10.11648/j.ijmsa.20180703.14

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Selective Separation of Organic Electrolytes by Neutralization Dialysis with Grafted Polyethylene Films

Yuji Kimura, Kazunori Yamada

Published in International Journal of Materials Science and Applications (Volume 7, Issue 3)

Received: 14 November 2017 Accepted: 30 November 2017 Published: 26 April 2018

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Abstract

The selective separation of organic electrolytes by neutralization dialysis was investigated with two kinds of grafted polyethylene (PE) films prepared through the photografting of 2-(dimethylamino) ethyl methacrylate (DMAEMA) onto the PE films and the subsequent quaternization and through the photografting of glycidyl methacrylate (GMA) and the subsequent sulfonation. The permeation flux of benzoic acid (BA) for the quarternized DMAEMA-grafted PE (PE-g-QPDMAEMA) films increased with an increase in the degree of quaternization, and the BA permeability had the maximum at the initial pH value of the permeate solution of 12.0. On the other hand, the sulfonation offered the phenylalaninol (Phl) permeability of the GMA-grafted PE (PE-g-PGMA) films. The selective separation for the binary BA/Phl or 2,5-dichlorobenzoic acid/Phl systems was successfully achieved by use of a pH difference between the feed and permeate solutions through the PE-g-QPDMAEMA and sulfonated PE-g-PGMA (PE-g-SPGMA) films. The maximum selective separation was obtained under the conditions that the initial pH values of the permeate solutions through the PE-g-QPDMAEMA and PE-g-SPGMA films were adjusted to 12.0 and 2.0, respectively. This procedure will be applied to separation and concentration of organic electrolytes and water purification.

Published in	International Journal of Materials Science and Applications (Volume 7, Issue 3)
DOI	10.11648/j.ijmsa.20180703.14
Page(s)	95-105
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2018. Published by Science Publishing Group

Keywords

Polyethylene, Photografting, 2-(dimethylamino) ethyl Methacrylate, Glycidyl Methacrylate, Neutralization Dialysis, Selective Separation

References

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Yuji Kimura, Kazunori Yamada. (2018). Selective Separation of Organic Electrolytes by Neutralization Dialysis with Grafted Polyethylene Films. International Journal of Materials Science and Applications, 7(3), 95-105. https://doi.org/10.11648/j.ijmsa.20180703.14

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ACS Style

Yuji Kimura; Kazunori Yamada. Selective Separation of Organic Electrolytes by Neutralization Dialysis with Grafted Polyethylene Films. Int. J. Mater. Sci. Appl. 2018, 7(3), 95-105. doi: 10.11648/j.ijmsa.20180703.14

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AMA Style

Yuji Kimura, Kazunori Yamada. Selective Separation of Organic Electrolytes by Neutralization Dialysis with Grafted Polyethylene Films. Int J Mater Sci Appl. 2018;7(3):95-105. doi: 10.11648/j.ijmsa.20180703.14

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@article{10.11648/j.ijmsa.20180703.14,
  author = {Yuji Kimura and Kazunori Yamada},
  title = {Selective Separation of Organic Electrolytes by Neutralization Dialysis with Grafted Polyethylene Films},
  journal = {International Journal of Materials Science and Applications},
  volume = {7},
  number = {3},
  pages = {95-105},
  doi = {10.11648/j.ijmsa.20180703.14},
  url = {https://doi.org/10.11648/j.ijmsa.20180703.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijmsa.20180703.14},
  abstract = {The selective separation of organic electrolytes by neutralization dialysis was investigated with two kinds of grafted polyethylene (PE) films prepared through the photografting of 2-(dimethylamino) ethyl methacrylate (DMAEMA) onto the PE films and the subsequent quaternization and through the photografting of glycidyl methacrylate (GMA) and the subsequent sulfonation. The permeation flux of benzoic acid (BA) for the quarternized DMAEMA-grafted PE (PE-g-QPDMAEMA) films increased with an increase in the degree of quaternization, and the BA permeability had the maximum at the initial pH value of the permeate solution of 12.0. On the other hand, the sulfonation offered the phenylalaninol (Phl) permeability of the GMA-grafted PE (PE-g-PGMA) films. The selective separation for the binary BA/Phl or 2,5-dichlorobenzoic acid/Phl systems was successfully achieved by use of a pH difference between the feed and permeate solutions through the PE-g-QPDMAEMA and sulfonated PE-g-PGMA (PE-g-SPGMA) films. The maximum selective separation was obtained under the conditions that the initial pH values of the permeate solutions through the PE-g-QPDMAEMA and PE-g-SPGMA films were adjusted to 12.0 and 2.0, respectively. This procedure will be applied to separation and concentration of organic electrolytes and water purification.},
 year = {2018}
}

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TY  - JOUR
T1  - Selective Separation of Organic Electrolytes by Neutralization Dialysis with Grafted Polyethylene Films
AU  - Yuji Kimura
AU  - Kazunori Yamada
Y1  - 2018/04/26
PY  - 2018
N1  - https://doi.org/10.11648/j.ijmsa.20180703.14
DO  - 10.11648/j.ijmsa.20180703.14
T2  - International Journal of Materials Science and Applications
JF  - International Journal of Materials Science and Applications
JO  - International Journal of Materials Science and Applications
SP  - 95
EP  - 105
PB  - Science Publishing Group
SN  - 2327-2643
UR  - https://doi.org/10.11648/j.ijmsa.20180703.14
AB  - The selective separation of organic electrolytes by neutralization dialysis was investigated with two kinds of grafted polyethylene (PE) films prepared through the photografting of 2-(dimethylamino) ethyl methacrylate (DMAEMA) onto the PE films and the subsequent quaternization and through the photografting of glycidyl methacrylate (GMA) and the subsequent sulfonation. The permeation flux of benzoic acid (BA) for the quarternized DMAEMA-grafted PE (PE-g-QPDMAEMA) films increased with an increase in the degree of quaternization, and the BA permeability had the maximum at the initial pH value of the permeate solution of 12.0. On the other hand, the sulfonation offered the phenylalaninol (Phl) permeability of the GMA-grafted PE (PE-g-PGMA) films. The selective separation for the binary BA/Phl or 2,5-dichlorobenzoic acid/Phl systems was successfully achieved by use of a pH difference between the feed and permeate solutions through the PE-g-QPDMAEMA and sulfonated PE-g-PGMA (PE-g-SPGMA) films. The maximum selective separation was obtained under the conditions that the initial pH values of the permeate solutions through the PE-g-QPDMAEMA and PE-g-SPGMA films were adjusted to 12.0 and 2.0, respectively. This procedure will be applied to separation and concentration of organic electrolytes and water purification.
VL  - 7
IS  - 3
ER  -

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Author Information

Yuji Kimura

Department of Applied Molecular Chemistry, Nihon University, Narashino, Japan
Kazunori Yamada

Department of Applied Molecular Chemistry, Nihon University, Narashino, Japan

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Yuji Kimura, Kazunori Yamada. (2018). Selective Separation of Organic Electrolytes by Neutralization Dialysis with Grafted Polyethylene Films. International Journal of Materials Science and Applications, 7(3), 95-105. https://doi.org/10.11648/j.ijmsa.20180703.14

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ACS Style

Yuji Kimura; Kazunori Yamada. Selective Separation of Organic Electrolytes by Neutralization Dialysis with Grafted Polyethylene Films. Int. J. Mater. Sci. Appl. 2018, 7(3), 95-105. doi: 10.11648/j.ijmsa.20180703.14

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AMA Style

Yuji Kimura, Kazunori Yamada. Selective Separation of Organic Electrolytes by Neutralization Dialysis with Grafted Polyethylene Films. Int J Mater Sci Appl. 2018;7(3):95-105. doi: 10.11648/j.ijmsa.20180703.14

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@article{10.11648/j.ijmsa.20180703.14,
  author = {Yuji Kimura and Kazunori Yamada},
  title = {Selective Separation of Organic Electrolytes by Neutralization Dialysis with Grafted Polyethylene Films},
  journal = {International Journal of Materials Science and Applications},
  volume = {7},
  number = {3},
  pages = {95-105},
  doi = {10.11648/j.ijmsa.20180703.14},
  url = {https://doi.org/10.11648/j.ijmsa.20180703.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijmsa.20180703.14},
  abstract = {The selective separation of organic electrolytes by neutralization dialysis was investigated with two kinds of grafted polyethylene (PE) films prepared through the photografting of 2-(dimethylamino) ethyl methacrylate (DMAEMA) onto the PE films and the subsequent quaternization and through the photografting of glycidyl methacrylate (GMA) and the subsequent sulfonation. The permeation flux of benzoic acid (BA) for the quarternized DMAEMA-grafted PE (PE-g-QPDMAEMA) films increased with an increase in the degree of quaternization, and the BA permeability had the maximum at the initial pH value of the permeate solution of 12.0. On the other hand, the sulfonation offered the phenylalaninol (Phl) permeability of the GMA-grafted PE (PE-g-PGMA) films. The selective separation for the binary BA/Phl or 2,5-dichlorobenzoic acid/Phl systems was successfully achieved by use of a pH difference between the feed and permeate solutions through the PE-g-QPDMAEMA and sulfonated PE-g-PGMA (PE-g-SPGMA) films. The maximum selective separation was obtained under the conditions that the initial pH values of the permeate solutions through the PE-g-QPDMAEMA and PE-g-SPGMA films were adjusted to 12.0 and 2.0, respectively. This procedure will be applied to separation and concentration of organic electrolytes and water purification.},
 year = {2018}
}

Copy | Download

TY  - JOUR
T1  - Selective Separation of Organic Electrolytes by Neutralization Dialysis with Grafted Polyethylene Films
AU  - Yuji Kimura
AU  - Kazunori Yamada
Y1  - 2018/04/26
PY  - 2018
N1  - https://doi.org/10.11648/j.ijmsa.20180703.14
DO  - 10.11648/j.ijmsa.20180703.14
T2  - International Journal of Materials Science and Applications
JF  - International Journal of Materials Science and Applications
JO  - International Journal of Materials Science and Applications
SP  - 95
EP  - 105
PB  - Science Publishing Group
SN  - 2327-2643
UR  - https://doi.org/10.11648/j.ijmsa.20180703.14
AB  - The selective separation of organic electrolytes by neutralization dialysis was investigated with two kinds of grafted polyethylene (PE) films prepared through the photografting of 2-(dimethylamino) ethyl methacrylate (DMAEMA) onto the PE films and the subsequent quaternization and through the photografting of glycidyl methacrylate (GMA) and the subsequent sulfonation. The permeation flux of benzoic acid (BA) for the quarternized DMAEMA-grafted PE (PE-g-QPDMAEMA) films increased with an increase in the degree of quaternization, and the BA permeability had the maximum at the initial pH value of the permeate solution of 12.0. On the other hand, the sulfonation offered the phenylalaninol (Phl) permeability of the GMA-grafted PE (PE-g-PGMA) films. The selective separation for the binary BA/Phl or 2,5-dichlorobenzoic acid/Phl systems was successfully achieved by use of a pH difference between the feed and permeate solutions through the PE-g-QPDMAEMA and sulfonated PE-g-PGMA (PE-g-SPGMA) films. The maximum selective separation was obtained under the conditions that the initial pH values of the permeate solutions through the PE-g-QPDMAEMA and PE-g-SPGMA films were adjusted to 12.0 and 2.0, respectively. This procedure will be applied to separation and concentration of organic electrolytes and water purification.
VL  - 7
IS  - 3
ER  -

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