Simulated Sunlight Induced the Degradation of Rhodamine B Over Graphene Oxide-Based Ag3PO4@AgCl

Mahgoub Ibrahim Shinger; Ahmed Mahmoud Idris; Dong Dong Qin; Hind Baballa; Duoliang Shan; Xiaoquan Lu

doi:doi:10.11648/j.ijmsa.20150404.14

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Simulated Sunlight Induced the Degradation of Rhodamine B Over Graphene Oxide-Based Ag3PO4@AgCl

Mahgoub Ibrahim Shinger, Ahmed Mahmoud Idris, Dong Dong Qin, Hind Baballa, Duoliang Shan, Xiaoquan Lu

Published in International Journal of Materials Science and Applications (Volume 4, Issue 4)

Received: 21 May 2015 Accepted: 6 June 2015 Published: 30 June 2015

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Abstract

A facile, environmentally friendly and economical in-situ ion-exchange method was successfully fabricated graphene oxide-based Ag3PO4@AgCl photocatalyst to promote the photocatalytic activity of Ag3PO4@AgCl. The as synthesized GO-Ag3PO4@AgCl composite was characterized by Fourier transform infrared (FTIR), X-ray diffraction (XRD), UV-vis diffuse reflectance spectroscopy and photoluminescence (PL). The morphology and the structure of the synthesized photocatalyst were characterized by field-emission scanning electron microscopy (SEM) and transmitter electron microscopy (TEM). The elements detection and the chemical state of the sample were investigated by X-ray photoelectron spectroscopy (XPS) analysis. GO-Ag3PO4@AgCl exhibited higher photocatalytic activity over Ag3PO4@AgCl and Ag3PO4 for the degradation of Rhodamine B (RhB) under simulated sunlight, and the highest photocatalytic activity was obtained by GO-Ag3PO4@AgCl photocatalyst with Cl/P ratio of 0.5. The quenching study using different scavengers investigated that the photogenerated holes (h+) and superoxide radicals (•O2-) played a key role in the degradation of RhB. The kinetic study revealed that the degradation of RhB over GO-Ag3PO4@AgCl-0.5 under simulated sunlight followed the first-order kinetics.

Published in	International Journal of Materials Science and Applications (Volume 4, Issue 4)
DOI	10.11648/j.ijmsa.20150404.14
Page(s)	246-255
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2015. Published by Science Publishing Group

Keywords

GO, Ag3PO4, AgCl, RhB and Simulated Sunlight Irradiation

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APA Style

Mahgoub Ibrahim Shinger, Ahmed Mahmoud Idris, Dong Dong Qin, Hind Baballa, Duoliang Shan, et al. (2015). Simulated Sunlight Induced the Degradation of Rhodamine B Over Graphene Oxide-Based Ag3PO4@AgCl. International Journal of Materials Science and Applications, 4(4), 246-255. https://doi.org/10.11648/j.ijmsa.20150404.14

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ACS Style

Mahgoub Ibrahim Shinger; Ahmed Mahmoud Idris; Dong Dong Qin; Hind Baballa; Duoliang Shan, et al. Simulated Sunlight Induced the Degradation of Rhodamine B Over Graphene Oxide-Based Ag3PO4@AgCl. Int. J. Mater. Sci. Appl. 2015, 4(4), 246-255. doi: 10.11648/j.ijmsa.20150404.14

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AMA Style

Mahgoub Ibrahim Shinger, Ahmed Mahmoud Idris, Dong Dong Qin, Hind Baballa, Duoliang Shan, et al. Simulated Sunlight Induced the Degradation of Rhodamine B Over Graphene Oxide-Based Ag3PO4@AgCl. Int J Mater Sci Appl. 2015;4(4):246-255. doi: 10.11648/j.ijmsa.20150404.14

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@article{10.11648/j.ijmsa.20150404.14,
  author = {Mahgoub Ibrahim Shinger and Ahmed Mahmoud Idris and Dong Dong Qin and Hind Baballa and Duoliang Shan and Xiaoquan Lu},
  title = {Simulated Sunlight Induced the Degradation of Rhodamine B Over Graphene Oxide-Based Ag3PO4@AgCl},
  journal = {International Journal of Materials Science and Applications},
  volume = {4},
  number = {4},
  pages = {246-255},
  doi = {10.11648/j.ijmsa.20150404.14},
  url = {https://doi.org/10.11648/j.ijmsa.20150404.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijmsa.20150404.14},
  abstract = {A facile, environmentally friendly and economical in-situ ion-exchange method was successfully fabricated graphene oxide-based Ag3PO4@AgCl photocatalyst to promote the photocatalytic activity of Ag3PO4@AgCl. The as synthesized GO-Ag3PO4@AgCl composite was characterized by Fourier transform infrared (FTIR), X-ray diffraction (XRD), UV-vis diffuse reflectance spectroscopy and photoluminescence (PL). The morphology and the structure of the synthesized photocatalyst were characterized by field-emission scanning electron microscopy (SEM) and transmitter electron microscopy (TEM). The elements detection and the chemical state of the sample were investigated by X-ray photoelectron spectroscopy (XPS) analysis. GO-Ag3PO4@AgCl exhibited higher photocatalytic activity over Ag3PO4@AgCl and Ag3PO4 for the degradation of Rhodamine B (RhB) under simulated sunlight, and the highest photocatalytic activity was obtained by GO-Ag3PO4@AgCl photocatalyst with Cl/P ratio of 0.5. The quenching study using different scavengers investigated that the photogenerated holes (h+) and superoxide radicals (•O2-) played a key role in the degradation of RhB. The kinetic study revealed that the degradation of RhB over GO-Ag3PO4@AgCl-0.5 under simulated sunlight followed the first-order kinetics.},
 year = {2015}
}

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TY  - JOUR
T1  - Simulated Sunlight Induced the Degradation of Rhodamine B Over Graphene Oxide-Based Ag3PO4@AgCl
AU  - Mahgoub Ibrahim Shinger
AU  - Ahmed Mahmoud Idris
AU  - Dong Dong Qin
AU  - Hind Baballa
AU  - Duoliang Shan
AU  - Xiaoquan Lu
Y1  - 2015/06/30
PY  - 2015
N1  - https://doi.org/10.11648/j.ijmsa.20150404.14
DO  - 10.11648/j.ijmsa.20150404.14
T2  - International Journal of Materials Science and Applications
JF  - International Journal of Materials Science and Applications
JO  - International Journal of Materials Science and Applications
SP  - 246
EP  - 255
PB  - Science Publishing Group
SN  - 2327-2643
UR  - https://doi.org/10.11648/j.ijmsa.20150404.14
AB  - A facile, environmentally friendly and economical in-situ ion-exchange method was successfully fabricated graphene oxide-based Ag3PO4@AgCl photocatalyst to promote the photocatalytic activity of Ag3PO4@AgCl. The as synthesized GO-Ag3PO4@AgCl composite was characterized by Fourier transform infrared (FTIR), X-ray diffraction (XRD), UV-vis diffuse reflectance spectroscopy and photoluminescence (PL). The morphology and the structure of the synthesized photocatalyst were characterized by field-emission scanning electron microscopy (SEM) and transmitter electron microscopy (TEM). The elements detection and the chemical state of the sample were investigated by X-ray photoelectron spectroscopy (XPS) analysis. GO-Ag3PO4@AgCl exhibited higher photocatalytic activity over Ag3PO4@AgCl and Ag3PO4 for the degradation of Rhodamine B (RhB) under simulated sunlight, and the highest photocatalytic activity was obtained by GO-Ag3PO4@AgCl photocatalyst with Cl/P ratio of 0.5. The quenching study using different scavengers investigated that the photogenerated holes (h+) and superoxide radicals (•O2-) played a key role in the degradation of RhB. The kinetic study revealed that the degradation of RhB over GO-Ag3PO4@AgCl-0.5 under simulated sunlight followed the first-order kinetics.
VL  - 4
IS  - 4
ER  -

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Author Information

Mahgoub Ibrahim Shinger

Key Laboratory of Bioelectrochemistry & Environmental Analysis of Gansu Province, College of Chemistry & Chemical Engineering, Northwest Normal University, Lanzhou, China
Ahmed Mahmoud Idris

Key Laboratory of Bioelectrochemistry & Environmental Analysis of Gansu Province, College of Chemistry & Chemical Engineering, Northwest Normal University, Lanzhou, China
Dong Dong Qin

Key Laboratory of Bioelectrochemistry & Environmental Analysis of Gansu Province, College of Chemistry & Chemical Engineering, Northwest Normal University, Lanzhou, China
Hind Baballa

Key Laboratory of Bioelectrochemistry & Environmental Analysis of Gansu Province, College of Chemistry & Chemical Engineering, Northwest Normal University, Lanzhou, China
Duoliang Shan

Key Laboratory of Bioelectrochemistry & Environmental Analysis of Gansu Province, College of Chemistry & Chemical Engineering, Northwest Normal University, Lanzhou, China
Xiaoquan Lu

Key Laboratory of Bioelectrochemistry & Environmental Analysis of Gansu Province, College of Chemistry & Chemical Engineering, Northwest Normal University, Lanzhou, China

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APA Style

Mahgoub Ibrahim Shinger, Ahmed Mahmoud Idris, Dong Dong Qin, Hind Baballa, Duoliang Shan, et al. (2015). Simulated Sunlight Induced the Degradation of Rhodamine B Over Graphene Oxide-Based Ag3PO4@AgCl. International Journal of Materials Science and Applications, 4(4), 246-255. https://doi.org/10.11648/j.ijmsa.20150404.14

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ACS Style

Mahgoub Ibrahim Shinger; Ahmed Mahmoud Idris; Dong Dong Qin; Hind Baballa; Duoliang Shan, et al. Simulated Sunlight Induced the Degradation of Rhodamine B Over Graphene Oxide-Based Ag3PO4@AgCl. Int. J. Mater. Sci. Appl. 2015, 4(4), 246-255. doi: 10.11648/j.ijmsa.20150404.14

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AMA Style

Mahgoub Ibrahim Shinger, Ahmed Mahmoud Idris, Dong Dong Qin, Hind Baballa, Duoliang Shan, et al. Simulated Sunlight Induced the Degradation of Rhodamine B Over Graphene Oxide-Based Ag3PO4@AgCl. Int J Mater Sci Appl. 2015;4(4):246-255. doi: 10.11648/j.ijmsa.20150404.14

Copy | Download

@article{10.11648/j.ijmsa.20150404.14,
  author = {Mahgoub Ibrahim Shinger and Ahmed Mahmoud Idris and Dong Dong Qin and Hind Baballa and Duoliang Shan and Xiaoquan Lu},
  title = {Simulated Sunlight Induced the Degradation of Rhodamine B Over Graphene Oxide-Based Ag3PO4@AgCl},
  journal = {International Journal of Materials Science and Applications},
  volume = {4},
  number = {4},
  pages = {246-255},
  doi = {10.11648/j.ijmsa.20150404.14},
  url = {https://doi.org/10.11648/j.ijmsa.20150404.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijmsa.20150404.14},
  abstract = {A facile, environmentally friendly and economical in-situ ion-exchange method was successfully fabricated graphene oxide-based Ag3PO4@AgCl photocatalyst to promote the photocatalytic activity of Ag3PO4@AgCl. The as synthesized GO-Ag3PO4@AgCl composite was characterized by Fourier transform infrared (FTIR), X-ray diffraction (XRD), UV-vis diffuse reflectance spectroscopy and photoluminescence (PL). The morphology and the structure of the synthesized photocatalyst were characterized by field-emission scanning electron microscopy (SEM) and transmitter electron microscopy (TEM). The elements detection and the chemical state of the sample were investigated by X-ray photoelectron spectroscopy (XPS) analysis. GO-Ag3PO4@AgCl exhibited higher photocatalytic activity over Ag3PO4@AgCl and Ag3PO4 for the degradation of Rhodamine B (RhB) under simulated sunlight, and the highest photocatalytic activity was obtained by GO-Ag3PO4@AgCl photocatalyst with Cl/P ratio of 0.5. The quenching study using different scavengers investigated that the photogenerated holes (h+) and superoxide radicals (•O2-) played a key role in the degradation of RhB. The kinetic study revealed that the degradation of RhB over GO-Ag3PO4@AgCl-0.5 under simulated sunlight followed the first-order kinetics.},
 year = {2015}
}

Copy | Download

TY  - JOUR
T1  - Simulated Sunlight Induced the Degradation of Rhodamine B Over Graphene Oxide-Based Ag3PO4@AgCl
AU  - Mahgoub Ibrahim Shinger
AU  - Ahmed Mahmoud Idris
AU  - Dong Dong Qin
AU  - Hind Baballa
AU  - Duoliang Shan
AU  - Xiaoquan Lu
Y1  - 2015/06/30
PY  - 2015
N1  - https://doi.org/10.11648/j.ijmsa.20150404.14
DO  - 10.11648/j.ijmsa.20150404.14
T2  - International Journal of Materials Science and Applications
JF  - International Journal of Materials Science and Applications
JO  - International Journal of Materials Science and Applications
SP  - 246
EP  - 255
PB  - Science Publishing Group
SN  - 2327-2643
UR  - https://doi.org/10.11648/j.ijmsa.20150404.14
AB  - A facile, environmentally friendly and economical in-situ ion-exchange method was successfully fabricated graphene oxide-based Ag3PO4@AgCl photocatalyst to promote the photocatalytic activity of Ag3PO4@AgCl. The as synthesized GO-Ag3PO4@AgCl composite was characterized by Fourier transform infrared (FTIR), X-ray diffraction (XRD), UV-vis diffuse reflectance spectroscopy and photoluminescence (PL). The morphology and the structure of the synthesized photocatalyst were characterized by field-emission scanning electron microscopy (SEM) and transmitter electron microscopy (TEM). The elements detection and the chemical state of the sample were investigated by X-ray photoelectron spectroscopy (XPS) analysis. GO-Ag3PO4@AgCl exhibited higher photocatalytic activity over Ag3PO4@AgCl and Ag3PO4 for the degradation of Rhodamine B (RhB) under simulated sunlight, and the highest photocatalytic activity was obtained by GO-Ag3PO4@AgCl photocatalyst with Cl/P ratio of 0.5. The quenching study using different scavengers investigated that the photogenerated holes (h+) and superoxide radicals (•O2-) played a key role in the degradation of RhB. The kinetic study revealed that the degradation of RhB over GO-Ag3PO4@AgCl-0.5 under simulated sunlight followed the first-order kinetics.
VL  - 4
IS  - 4
ER  -

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