Cadmium Sulphide (CdS) thin films have been deposited on glass substrates at room temperature by using Chemical bath deposition method. The bath composition included cadmium chloride hemidihydrate [CdCl2.2½H2O], thiourea [SC (NH2)2] and Ammonia (NH3) solution. The effects of the pH value on the optical properties of the films have been investigated. The as-deposited films have been characterized by the UV-VIS Spectrophotometer. The spectrum showed that absorbance was high in the UV and low in the VIS-NIR region. The optimum percentage transmittance and reflectance are 84.7% and 20.3% respectively within the same region. The band gap values of the films range from 2.4 to 2.6 eV. The optical properties of the films within the UV- VIS-NIR regions indicate that the films can find application in solar thermal technology, particularly in antireflection coating.
Published in | International Journal of Materials Science and Applications (Volume 4, Issue 2) |
DOI | 10.11648/j.ijmsa.20150402.21 |
Page(s) | 138-142 |
Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
Copyright |
Copyright © The Author(s), 2015. Published by Science Publishing Group |
CBD, Cadmium Sulphide, pH, Optical Properties
[1] | Kobayashi M., Kitamura K., Umeya H., Jia A. W., Yoshikawa A., Shimotomai M., Kato Y., Takahashi K., J. Vac. Sci. Technol B 18 (2000) 1684. |
[2] | Selma M. H., Al-Jawad Ali M., Mousa Wessal A. T., Um-Salam Science Journal, 6/1 (2009) 041. |
[3] | Contreras M., Romero M., To B., Hasoon F., Noufi R., Ward S., Ramanathan K., Thin Solid Films 403/404 (2002) 204. |
[4] | Mirsagatove, S. A.; Shamirzaev, S. K.; Makhmudov, M.; Muzapharova, S. A. , J. Korean Phys.Soc. 34(1999) S420-S421. |
[5] | Davis A., Vaccaro K., Dauplaise H., Waters W., Lorenzo J., J. Electrochem. Soc. 146 (1999) 1046. |
[6] | Dhumure S.S and Lokhande C.D, Indian J pure & Appl phys, 31(1993)512. |
[7] | Lincot D. and Gary H., Proceedings of the International Symposium The Electrochemical Society, (2006) |
[8] | Antonio L. and Steven H, (2003), Handbook of Photovoltaic Science and Engineering John Wiley and Sons |
[9] | Fouassier C.,(1994), Luminescence in Encyclopedia of Inorganic Chemistry, John Wiley & Sons |
[10] | Dhawale D.S., Dubal D.P., Phadatare M.R., Patil J.S., Lokhande C.D., Journal of Materials Science, 46 , (2011) 5009–5015. |
[11] | Park J. W., Ahn B. T., Im H. B. and Kim C. S., J. Electrochem. Soc 139 (1992) 3351–3356. |
[12] | Shah N. M., Ray J .R., Desai M. S., Panchal C. J., Journal 0f Optoelectronics and Advanced Materials, 12/10 (2010) 2052 -2056. |
[13] | Mahmoud S.A., Ibrahim A.A., Riad A.S., Thin Solid Films 372 (2000) 144. |
[14] | Nam-Hoon K., Seung-Han R., Hyo-Sup N., Woo-Sun L., Materials Science in Semiconductor Processing 15/2, (2012) 125-130. |
[15] | Tsai C., Chuu D., Chen G., and S. Yang. J. Appl. Phys. 79 (1996)9105. |
[16] | Shah N. M., AIP Conf. Proc., (2013) 1536, 445-4414. |
[17] | Hoffmann P.h., Horn K., Bradshaw A.M., Johson R.L., Fuchs D., Cardona M., Phys. Rev. B47 (1993)1639. |
[18] | Yadav A. A., Masumdar E. U., Journal of Alloys and Compounds, 509 /17 (2011) 5394-5399. |
[19] | Mahdi M .A, Hassan Z .N., Hassan S. S., Mohd J. J., Bakhori S K., Thin Solid Film 520, (2012) 3477 – 3484. |
[20] | Metin, H., Sat F., Erat S., and Ari M. Journal of Optoelectronics and Advanced Materials. 10/10, (2008) 2622-2630. |
[21] | Dharmadasa I.M and Haigh J. Journal of the Electrochemical Society. 153 (2006) G74-G52. |
[22] | Das V.D., Sathyanarayanan J., and Damodare L. Surf.Coat.Technol. 94/95, (1997) 669-671. |
[23] | Kale S.S., Mane R.S., Lokhande C.D., Nandi K.C., and Han S.H. Materials Science and Engineering B-Solid State Materials for Advanced Technology. 133/1-3 (2006) 222-225. |
[24] | Bhattacharjee R. Assam University Journal of Science & Technology. 5(2010) 153-155. |
[25] | Be Xuan H., Ha Van T., Khuc Quang., Phung Quoc B. VNU Journal of Science, Mathematics -Physics 24 (2008) 119-123. |
[26] | Suresh S. and Koteeswari P., International Journal of Chem Tech Research, 6/7(2014) 3748-3752. |
[27] | Awodugba A.O., and Adedokun O., The Pacific Journal of Science and Technology 12/ 2. (2011) 335 |
[28] | Khallaf H., Isaiah O. O., Guangyu C and Lee C., Thin Solid Films 516 (2008) 7306–7312. |
[29] | Gray, D.E., American Institute of Physics Handbook. 3rd Edition. (1982) McGraw-Hill: New York, NY. |
[30] | Nair, P.K., M.T.S. Nair, A. Fermaardex, and M. Ocampo. J. Phys. D Appl. Phys. 22, (1989) 829. |
[31] | Lozada-Morales, R., Rubin-Falfan M., Zela-Angel O., and Ramirez-Bon R., J.Phys. Chm. Solid. 59/9 (1998) 1393. |
APA Style
Rita Anionye Daniel-Umeri. (2015). Effect of pH on the Optical Properties of Cadmium Sulphide (CdS) Thin Film Deposited Using Chemical Bath Method. International Journal of Materials Science and Applications, 4(2), 138-142. https://doi.org/10.11648/j.ijmsa.20150402.21
ACS Style
Rita Anionye Daniel-Umeri. Effect of pH on the Optical Properties of Cadmium Sulphide (CdS) Thin Film Deposited Using Chemical Bath Method. Int. J. Mater. Sci. Appl. 2015, 4(2), 138-142. doi: 10.11648/j.ijmsa.20150402.21
AMA Style
Rita Anionye Daniel-Umeri. Effect of pH on the Optical Properties of Cadmium Sulphide (CdS) Thin Film Deposited Using Chemical Bath Method. Int J Mater Sci Appl. 2015;4(2):138-142. doi: 10.11648/j.ijmsa.20150402.21
@article{10.11648/j.ijmsa.20150402.21, author = {Rita Anionye Daniel-Umeri}, title = {Effect of pH on the Optical Properties of Cadmium Sulphide (CdS) Thin Film Deposited Using Chemical Bath Method}, journal = {International Journal of Materials Science and Applications}, volume = {4}, number = {2}, pages = {138-142}, doi = {10.11648/j.ijmsa.20150402.21}, url = {https://doi.org/10.11648/j.ijmsa.20150402.21}, eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijmsa.20150402.21}, abstract = {Cadmium Sulphide (CdS) thin films have been deposited on glass substrates at room temperature by using Chemical bath deposition method. The bath composition included cadmium chloride hemidihydrate [CdCl2.2½H2O], thiourea [SC (NH2)2] and Ammonia (NH3) solution. The effects of the pH value on the optical properties of the films have been investigated. The as-deposited films have been characterized by the UV-VIS Spectrophotometer. The spectrum showed that absorbance was high in the UV and low in the VIS-NIR region. The optimum percentage transmittance and reflectance are 84.7% and 20.3% respectively within the same region. The band gap values of the films range from 2.4 to 2.6 eV. The optical properties of the films within the UV- VIS-NIR regions indicate that the films can find application in solar thermal technology, particularly in antireflection coating.}, year = {2015} }
TY - JOUR T1 - Effect of pH on the Optical Properties of Cadmium Sulphide (CdS) Thin Film Deposited Using Chemical Bath Method AU - Rita Anionye Daniel-Umeri Y1 - 2015/04/18 PY - 2015 N1 - https://doi.org/10.11648/j.ijmsa.20150402.21 DO - 10.11648/j.ijmsa.20150402.21 T2 - International Journal of Materials Science and Applications JF - International Journal of Materials Science and Applications JO - International Journal of Materials Science and Applications SP - 138 EP - 142 PB - Science Publishing Group SN - 2327-2643 UR - https://doi.org/10.11648/j.ijmsa.20150402.21 AB - Cadmium Sulphide (CdS) thin films have been deposited on glass substrates at room temperature by using Chemical bath deposition method. The bath composition included cadmium chloride hemidihydrate [CdCl2.2½H2O], thiourea [SC (NH2)2] and Ammonia (NH3) solution. The effects of the pH value on the optical properties of the films have been investigated. The as-deposited films have been characterized by the UV-VIS Spectrophotometer. The spectrum showed that absorbance was high in the UV and low in the VIS-NIR region. The optimum percentage transmittance and reflectance are 84.7% and 20.3% respectively within the same region. The band gap values of the films range from 2.4 to 2.6 eV. The optical properties of the films within the UV- VIS-NIR regions indicate that the films can find application in solar thermal technology, particularly in antireflection coating. VL - 4 IS - 2 ER -