Effects of the Ba Impregnation on Pt Electrode on NO Electrochemical Reduction Mechanism

Xi Wang

doi:doi:10.11648/j.ijeee.20190402.11

| Peer-Reviewed

Effects of the Ba Impregnation on Pt Electrode on NO Electrochemical Reduction Mechanism

Xi Wang

Published in International Journal of Economy, Energy and Environment (Volume 4, Issue 2)

Received: 5 June 2019 Published: 19 July 2019

Views: Downloads:

Download PDF

Share This Article

Twitter
Linked In
Facebook

Abstract

The study investigated the electrochemical reduction performances of NO and O₂ on Pt symmetric electrode with Ba adsorption layer. The temperature varied from 350°C to 550°C. The experimental Ba (NO₃)₂ solution was impregnated in the Pt electrode. For the NO performance, the polarization curves and CV tests showed that the Pt-BaO electrode showed higher electrochemical performance than Pt electrode. EIS results revealed that the Pt-BaO electrode exhibited higher activity than the Pt electrode. It was due to the decreased polarization resistance in the low-frequency region that dominated the electrochemical impedance spectra. The increase of temperature strengthened the effect of adsorption layer on NO electrochemical performance. The EIS results were fitted well with the equivalent circuit model indicating that the improved mechanism with the Ba adsorption layer may be related with the NO oxidation to NO₂ on the Pt surface, the formation of Ba (NO₃)₂ in the adsorption layer and the reduction of the reaction path from the direct Ba (NO₃)₂ decomposition.

Published in	International Journal of Economy, Energy and Environment (Volume 4, Issue 2)
DOI	10.11648/j.ijeee.20190402.11
Page(s)	24-32
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2019. Published by Science Publishing Group

Keywords

Symmetric Electrode, Electrochemical Performance, Electrochemical Impedance Spectra, Equivalent Circuit Model

References

[1]	J. C. Summers, S. V. Houtte, D. Psaras. Simultaneous control of particulate and NO emissions from diesel engines [J]. Applied Catalysis B: Environment, 1996, 10: 139-156.
[2]	M. T. Lerdau, J. W. Munger, J. D. Jacob, “The NO_{2_{flus conundrum [J],” Science, 2000, 289: 2291-2293.}}
[3]	Z. M. He, K. B. Andersen, L. Keel, F. B. Nygaard, M. Menon, K. K. Hansen. Processing and characterization of porous electrochemical cells for flue gas purification [J]. Ionics, 2009, 15: 427-431.
[4]	T. J. Huang, C. Y. Wu, S. H. Hsu, C. C. Wu. Complete emissions control for highly fuel-efficient automobiles via a simulated stack of electrochemical-catalytic cells [J]. Energy & Environmental Science, 2011, 4: 4061-4067.
[5]	T. J. Huang, C. Y. Wu, C. C. Wu. Lean-burn NOx emission control via simulated stack of solid oxide fuel cells with Cu-added (LaSr)MnO_{3_{cathodes [J]. Chemical Engineering Journal, 2011, 172 (2-3): 665-670.}}
[6]	M. Awano, Y. Fujishiro, K. Hamamoto. Advances in nano-structured electrochemical reactors for NOx treatment in the presence of oxygen [J]. International Journal of Applied Ceramic Technology, 2004, 1 (3): 277-286.
[7]	K. K. Hansen. Solid state electrochemical DeNOx-An overview [J]. Applied Catalysis B: Environmental, 2010, 100 (3-4): 427-432.
[8]	T. J. Huang, C. Y. Wu, D. Y. Chiang, C. C. Yu. Ambient temperature NOx emission control for lean-burn engines by electro-catalytic tubes [J]. Applied Catalysis A: General, 2012, 445-446: 153-158.
[9]	T. J. Huang, C. L. Chou. Feasibility of simultaneous NO reduction and electricity generation in SOFCs with V_{2_{O_{5_{or Cu added LSCF-GDC cathodes [J]. Electrochemistry Communications, 2009, 11 (2): 477-480.}}}}
[10]	R. M. L. Werchmeister, K. K. Hansen. Electrochemical reduction of oxygen and nitric oxide at low temperature on Ce_1-xPr_xO_2-δ cathodes [J]. Electrochimica Acta, 2013, 114: 474-477.
[11]	T. J. Huang, C. Y. Wu, Y. H. Lin. Electrochemical enhancement of nitric oxide removal from simulated lean-burn engine exhaust via solid oxide fuel cells [J]. Environmental Science & Technology, 2011, 45: 5683-5688.
[12]	K. K. Hansen, E. M. Skou, H. Christensen. Perovskites as cathodes for nitric oxide reduction [J]. Journal of The Electrochemical Society, 2000, 147 (5): 2007-2012.
[13]	C. G. Schmidt, D. Ippolito, J. J. Bentzen, K. B. Andersen, A. Kaiser, K. K Hansen. Fabrication and characterization of multi-layer ceramics for electrochemical flue gas purification [J]. Journal of The Electrochemical Society, 2013, 160 (9): E113-E119.
[14]	A. de Lucas-Consuegra, A. Caravaca, M. J. Martín de Vidales, F. Dorado, S. Balomenou, D. Tsiplakides, P. Vernoux, J. L. Valverde. An electrochemically assisted NOxstorage/reduction catalyst operating under fixed lean burn conditions [J]. Catalysis Communications, 2009, 11 (4), 247-251.
[15]	J. Shao, K. K. Hansen. Optimization of an electrochemical cell with an adsorption layer for NOx removal [J]. Journal of Solid State Electrochemistry, 2012, 16 (10): 3331-3340.
[16]	R. M. L. Werchmeister, K. K. Hansen, M. Mogensen. Electrochemical removal of NOx with porous cell stacks[J]. Materials Research Bulletin, 2010, 45: 1554-1561.
[17]	S. Bredikhin, K. Maeda, M. Awano. Electrochemical cell with two layers cathode for NO decomposition [J]. Ionics, 2001, 7 (1-2): 109-115.
[18]	S. Bredikhin, K. Maeda, M. Awano. NO decomposition by an electrochemical cell with mixed oxide working electrode [J]. Solid State Ionics, 2001, 144 (1-2): 1-9.
[19]	S. Bredikhin, K. Maeda, M. Awano. Low current density electrochemical cell for NO decomposition [J]. Solid State Ionics, 2002, 152-153: 727-733.
[20]	K. Hamamoto, Y. Fujishiro, M. Awano. Low-temperature NOx decomposition using an electrochemical reactor [J]. Journal of The Electrochemical Society, 2008, 155 (8): E109-E111.
[21]	X. Li, P. Vernoux. A new NOx storage-reduction electrochemical catalyst [J]. Applied Catalysis B: Environmental, 2005, 61 (3-4): 267-273.
[22]	W. Y. Hernandez, A. Hadjar, A. Giroir-Fendler, P. Andy, A. Princivalle, M. Klotz, A. Marouf, C. Guizard, C. Tardivat, C. Viazzi, P. Vernoux. Electrochemically-assisted NOx storage-reduction catalysts [J]. Catalysis Today, 2015, 241: 143-150.
[23]	C. G. Vayenas, S. Bebelis, S. Ladas. Dependence of catalytic rates on catalyst work function [J]. Nature, 1990, 343: 625-627.
[24]	A. A. Nikola. NEMCA-From discovery to technology [J]. Catalysis Today, 2009, 146: 308-311.
[25]	M. L. Traulsen, K. K. Hansen. Improvement of LSM15-CGO10 electrodes for electrochemical removal of NOx by KNO3 and MnOx impregnation [J]. Journal of The Electrochemical Society, 2011, 158 (12): P147-P161.
[26]	M. L. Traulsen, F. Bræstrup, K. K. Hansen. NOx conversion on porous LSF15-CGO10 cell stacks with KNO3 or K2O impregnation [J]. Journal of Solid State Electrochemistry, 2012, 16: 2651-2660.
[27]	M. L. Traulsen, K. B. Andersen, K. K. Hansen. NOx conversion on LSM15-CGO10 cell stacks with BaO impregnation [J]. Journal of Materials Chemistry, 2012, 22: 11792-11800.
[28]	J. Shao, K. K, Hansen. Electrochemical NOx reduction on an LSM/CGO symmetric cell modified by NOx adsorbents [J]. Journal of Materials Chemistry A, 2013, 1: 7137-7146.
[29]	J. Shao, K. K, Hansen. Enhancement of NOx removal performance for (La_0.85Sr_0.15) _0.99MnO₃/Ce_0.9Gd_0.1O_1.95 electrochemical cells by NOx storage/reduction adsorption layers [J]. Electrochimica Acta, 2013, 90: 482-491.
[30]	J. Shao. NOx reduction using an electrochemical cell with NOx adsorbents [D]. Denmark: Technical University of Denmark, 2013.
[31]	J. E. Bauerle. Study of solid electrolyte polarization by a complex admittance method [J]. Journal of Physics and Chemistry of Solids, 1969, 30 (12): 2657-2670.
[32]	R. M. L. Werchmeister, K. K. Hansen, M. Mogensen. Chracterization of (La_1-xSr_x) _sMnO₃ and doped ceria composite electrodes in NOx-containing atmosphere with impedance spectroscopy [J]. Journal of The Electrochemical Society, 2010, 157 (5): P35-P42.
[33]	M. J. Jorgensen, M. Mogensen. Impedance of solid oxide fuel cell LSM/YSZ composite cathodes [J]. Journal of The Electrochemical Society, 2001, 148 (5): A433-A442.

Cite This Article

Plain Text BibTeX RIS

APA Style

Xi Wang. (2019). Effects of the Ba Impregnation on Pt Electrode on NO Electrochemical Reduction Mechanism. International Journal of Economy, Energy and Environment, 4(2), 24-32. https://doi.org/10.11648/j.ijeee.20190402.11

Copy | Download

ACS Style

Xi Wang. Effects of the Ba Impregnation on Pt Electrode on NO Electrochemical Reduction Mechanism. Int. J. Econ. Energy Environ. 2019, 4(2), 24-32. doi: 10.11648/j.ijeee.20190402.11

Copy | Download

AMA Style

Xi Wang. Effects of the Ba Impregnation on Pt Electrode on NO Electrochemical Reduction Mechanism. Int J Econ Energy Environ. 2019;4(2):24-32. doi: 10.11648/j.ijeee.20190402.11

Copy | Download

@article{10.11648/j.ijeee.20190402.11,
  author = {Xi Wang},
  title = {Effects of the Ba Impregnation on Pt Electrode on NO Electrochemical Reduction Mechanism},
  journal = {International Journal of Economy, Energy and Environment},
  volume = {4},
  number = {2},
  pages = {24-32},
  doi = {10.11648/j.ijeee.20190402.11},
  url = {https://doi.org/10.11648/j.ijeee.20190402.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijeee.20190402.11},
  abstract = {The study investigated the electrochemical reduction performances of NO and O2 on Pt symmetric electrode with Ba adsorption layer. The temperature varied from 350°C to 550°C. The experimental Ba (NO3)2 solution was impregnated in the Pt electrode. For the NO performance, the polarization curves and CV tests showed that the Pt-BaO electrode showed higher electrochemical performance than Pt electrode. EIS results revealed that the Pt-BaO electrode exhibited higher activity than the Pt electrode. It was due to the decreased polarization resistance in the low-frequency region that dominated the electrochemical impedance spectra. The increase of temperature strengthened the effect of adsorption layer on NO electrochemical performance. The EIS results were fitted well with the equivalent circuit model indicating that the improved mechanism with the Ba adsorption layer may be related with the NO oxidation to NO2 on the Pt surface, the formation of Ba (NO3)2 in the adsorption layer and the reduction of the reaction path from the direct Ba (NO3)2 decomposition.},
 year = {2019}
}

Copy | Download

TY  - JOUR
T1  - Effects of the Ba Impregnation on Pt Electrode on NO Electrochemical Reduction Mechanism
AU  - Xi Wang
Y1  - 2019/07/19
PY  - 2019
N1  - https://doi.org/10.11648/j.ijeee.20190402.11
DO  - 10.11648/j.ijeee.20190402.11
T2  - International Journal of Economy, Energy and Environment
JF  - International Journal of Economy, Energy and Environment
JO  - International Journal of Economy, Energy and Environment
SP  - 24
EP  - 32
PB  - Science Publishing Group
SN  - 2575-5021
UR  - https://doi.org/10.11648/j.ijeee.20190402.11
AB  - The study investigated the electrochemical reduction performances of NO and O2 on Pt symmetric electrode with Ba adsorption layer. The temperature varied from 350°C to 550°C. The experimental Ba (NO3)2 solution was impregnated in the Pt electrode. For the NO performance, the polarization curves and CV tests showed that the Pt-BaO electrode showed higher electrochemical performance than Pt electrode. EIS results revealed that the Pt-BaO electrode exhibited higher activity than the Pt electrode. It was due to the decreased polarization resistance in the low-frequency region that dominated the electrochemical impedance spectra. The increase of temperature strengthened the effect of adsorption layer on NO electrochemical performance. The EIS results were fitted well with the equivalent circuit model indicating that the improved mechanism with the Ba adsorption layer may be related with the NO oxidation to NO2 on the Pt surface, the formation of Ba (NO3)2 in the adsorption layer and the reduction of the reaction path from the direct Ba (NO3)2 decomposition.
VL  - 4
IS  - 2
ER  -

Copy | Download

Author Information

Xi Wang

Jiangsu Investment Management Co., Ltd., Nanjing, China

Download PDF

Sections

Plain Text BibTeX RIS

APA Style

Xi Wang. (2019). Effects of the Ba Impregnation on Pt Electrode on NO Electrochemical Reduction Mechanism. International Journal of Economy, Energy and Environment, 4(2), 24-32. https://doi.org/10.11648/j.ijeee.20190402.11

Copy | Download

ACS Style

Xi Wang. Effects of the Ba Impregnation on Pt Electrode on NO Electrochemical Reduction Mechanism. Int. J. Econ. Energy Environ. 2019, 4(2), 24-32. doi: 10.11648/j.ijeee.20190402.11

Copy | Download

AMA Style

Xi Wang. Effects of the Ba Impregnation on Pt Electrode on NO Electrochemical Reduction Mechanism. Int J Econ Energy Environ. 2019;4(2):24-32. doi: 10.11648/j.ijeee.20190402.11

Copy | Download

@article{10.11648/j.ijeee.20190402.11,
  author = {Xi Wang},
  title = {Effects of the Ba Impregnation on Pt Electrode on NO Electrochemical Reduction Mechanism},
  journal = {International Journal of Economy, Energy and Environment},
  volume = {4},
  number = {2},
  pages = {24-32},
  doi = {10.11648/j.ijeee.20190402.11},
  url = {https://doi.org/10.11648/j.ijeee.20190402.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijeee.20190402.11},
  abstract = {The study investigated the electrochemical reduction performances of NO and O2 on Pt symmetric electrode with Ba adsorption layer. The temperature varied from 350°C to 550°C. The experimental Ba (NO3)2 solution was impregnated in the Pt electrode. For the NO performance, the polarization curves and CV tests showed that the Pt-BaO electrode showed higher electrochemical performance than Pt electrode. EIS results revealed that the Pt-BaO electrode exhibited higher activity than the Pt electrode. It was due to the decreased polarization resistance in the low-frequency region that dominated the electrochemical impedance spectra. The increase of temperature strengthened the effect of adsorption layer on NO electrochemical performance. The EIS results were fitted well with the equivalent circuit model indicating that the improved mechanism with the Ba adsorption layer may be related with the NO oxidation to NO2 on the Pt surface, the formation of Ba (NO3)2 in the adsorption layer and the reduction of the reaction path from the direct Ba (NO3)2 decomposition.},
 year = {2019}
}

Copy | Download

TY  - JOUR
T1  - Effects of the Ba Impregnation on Pt Electrode on NO Electrochemical Reduction Mechanism
AU  - Xi Wang
Y1  - 2019/07/19
PY  - 2019
N1  - https://doi.org/10.11648/j.ijeee.20190402.11
DO  - 10.11648/j.ijeee.20190402.11
T2  - International Journal of Economy, Energy and Environment
JF  - International Journal of Economy, Energy and Environment
JO  - International Journal of Economy, Energy and Environment
SP  - 24
EP  - 32
PB  - Science Publishing Group
SN  - 2575-5021
UR  - https://doi.org/10.11648/j.ijeee.20190402.11
AB  - The study investigated the electrochemical reduction performances of NO and O2 on Pt symmetric electrode with Ba adsorption layer. The temperature varied from 350°C to 550°C. The experimental Ba (NO3)2 solution was impregnated in the Pt electrode. For the NO performance, the polarization curves and CV tests showed that the Pt-BaO electrode showed higher electrochemical performance than Pt electrode. EIS results revealed that the Pt-BaO electrode exhibited higher activity than the Pt electrode. It was due to the decreased polarization resistance in the low-frequency region that dominated the electrochemical impedance spectra. The increase of temperature strengthened the effect of adsorption layer on NO electrochemical performance. The EIS results were fitted well with the equivalent circuit model indicating that the improved mechanism with the Ba adsorption layer may be related with the NO oxidation to NO2 on the Pt surface, the formation of Ba (NO3)2 in the adsorption layer and the reduction of the reaction path from the direct Ba (NO3)2 decomposition.
VL  - 4
IS  - 2
ER  -

Copy | Download