Research Article | | Peer-Reviewed

Development of Acid-Modified Clay for the Treatment of Simulated Textile Dye Effluents

Published in Frontiers (Volume 6, Issue 4)
Received: 25 July 2026     Accepted: 24 August 2026     Published: 11 November 2026
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Abstract

The physiochemical properties of Natural Bentonite Clay (NBC) were modified in this work to increase its adsorption performance. The NBC was mined from Fika town in Yobe State and thereafter subjected to beneficiation to obtain various particle sizes. The modified NBC and Activated Bentonite Clay (ABC) were characterized using Fourier transform infrared (FTIR) spectroscopy for the determination of the effect of acid attack and the adsorbate Braunner-Emmet-Teller (BET) method for surface area determination was conducted on the clay sample before and after modification procedure. The surface areas of the adsorbents before and after modification were found to be 126.50 m2/g and 160.40 m2/g for NBC and ABC respectively. The raw and the modified samples had an adsorption capacity of 12.55 and 74.98 mg/g which were used to purify the simulated textile wastewater to investigate their adsorptive performance. The equilibrium data were fitted in Langmuir, Freundlich and Temkin adsorption isotherm models with the aid of origin 9 software using two statistical parameters- the correlation coefficient R and Sum of Square Errors SSE. Results showed the experimental data was best fitted in the Langmuir isotherm model where R values of ABC was consistently higher for dye 1-dye 4 than that of NBC. The SSE of ABC was also found to be consistently lower for all dye adsorption than that of NBC.

Published in Frontiers (Volume 6, Issue 4)
DOI 10.11648/j.frontiers.20260604.17
Page(s) 206-218
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2026. Published by Science Publishing Group

Keywords

Adsorption, Bentonite Clay, Adsorption Parameters, Dye Concentration, Particle Size

References
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[3] Ali, M., Asim, T., Khan, A., Low-cost adsorbents for the removal of organic pollutants from wastewater, J. Environ. Manage. 113, 170-183 (2012).
[4] Anirudhan, T. S., Ramachandran, M., Adsorptive removal of basic dyes from aqueous solutions by surfactant modified bentonite clay (organoclay): kinetic and competitive adsorption isotherm. Process Safety and Environmental Protection, 95, 215-225 (2015).
[5] Bayode, A. A., Removal of Cationic and Anionic Dyes from Aqueous Solution by MicrowaveAssisted Hybrid Clay Material. Redeemer’s University, Ede, Osun State (2016).
[6] Doulia, D., Leodopoulos, C., Gimouhopoulos, K., Rigas, F., Journal of Colloid and Interface Science Adsorption of humic acid on acid-activated Greek bentonite. Journal of Colloid And Interface Science, 340(2), 131-141 (2009).
[7] Fabryanty, R., Valencia, C., Soetaredjo, F. E., Putro, J. N., Santoso, S. P., Kurniawan, A., Ismadji, S., Removal of crystal violet dye by adsorption using bentonite-alginate composite. Journal of Environmental Chemical Engineering, 5(6), 5677-5687 (2017).
[8] Fu, F., Gao, Z., Gao, L., Li, D., Effective Adsorption of Anionic Dye, Alizarin Red S, from Aqueous Solutions on Activated Clay Modified by Iron Oxide. *Industrial and Engineering Chemistry Research*, 50, 9712-9717 (2011).
[9] Gupta, V. K., Application of low-cost adsorbents for dye removal—a review. *Journal of Environmental Management*, 90(8), 2313-2342 (2009).
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[14] Nejib A., Joelle D., Abdellah E., Amane J., Malika T. A., Textile dye adsorption onto raw clay: influence of clay surface properties and dyeing additives. *Journal of Colloid Science and Biotechnology*, 3: 98-110 (2014).
[15] Ngulube T., Ray J., Masindi V., Maity A., An update on synthetic dyes adsorption onto clay based minerals: A state-of-art review. *Journal of Environmental Management*, 191, 35-57 (2017).
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Cite This Article
  • APA Style

    Paul, A. A., Agbeke, I. O. R., Olufemi, A. B., Sulaiman, Z., Usman, A. (2026). Development of Acid-Modified Clay for the Treatment of Simulated Textile Dye Effluents. Frontiers, 6(4), 206-218. https://doi.org/10.11648/j.frontiers.20260604.17

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    ACS Style

    Paul, A. A.; Agbeke, I. O. R.; Olufemi, A. B.; Sulaiman, Z.; Usman, A. Development of Acid-Modified Clay for the Treatment of Simulated Textile Dye Effluents. Frontiers. 2026, 6(4), 206-218. doi: 10.11648/j.frontiers.20260604.17

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    AMA Style

    Paul AA, Agbeke IOR, Olufemi AB, Sulaiman Z, Usman A. Development of Acid-Modified Clay for the Treatment of Simulated Textile Dye Effluents. Frontiers. 2026;6(4):206-218. doi: 10.11648/j.frontiers.20260604.17

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  • @article{10.11648/j.frontiers.20260604.17,
      author = {Adelana Adedamola Paul and Iyun Ogunkemi Risikat Agbeke and Aderemi Benjamin Olufemi and Zakariyau Sulaiman and Ahmed Usman},
      title = {Development of Acid-Modified Clay for the Treatment of Simulated Textile Dye Effluents},
      journal = {Frontiers},
      volume = {6},
      number = {4},
      pages = {206-218},
      doi = {10.11648/j.frontiers.20260604.17},
      url = {https://doi.org/10.11648/j.frontiers.20260604.17},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.frontiers.20260604.17},
      abstract = {The physiochemical properties of Natural Bentonite Clay (NBC) were modified in this work to increase its adsorption performance. The NBC was mined from Fika town in Yobe State and thereafter subjected to beneficiation to obtain various particle sizes. The modified NBC and Activated Bentonite Clay (ABC) were characterized using Fourier transform infrared (FTIR) spectroscopy for the determination of the effect of acid attack and the adsorbate Braunner-Emmet-Teller (BET) method for surface area determination was conducted on the clay sample before and after modification procedure. The surface areas of the adsorbents before and after modification were found to be 126.50 m2/g and 160.40 m2/g for NBC and ABC respectively. The raw and the modified samples had an adsorption capacity of 12.55 and 74.98 mg/g which were used to purify the simulated textile wastewater to investigate their adsorptive performance. The equilibrium data were fitted in Langmuir, Freundlich and Temkin adsorption isotherm models with the aid of origin 9 software using two statistical parameters- the correlation coefficient R and Sum of Square Errors SSE. Results showed the experimental data was best fitted in the Langmuir isotherm model where R values of ABC was consistently higher for dye 1-dye 4 than that of NBC. The SSE of ABC was also found to be consistently lower for all dye adsorption than that of NBC.},
     year = {2026}
    }
    

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  • TY  - JOUR
    T1  - Development of Acid-Modified Clay for the Treatment of Simulated Textile Dye Effluents
    AU  - Adelana Adedamola Paul
    AU  - Iyun Ogunkemi Risikat Agbeke
    AU  - Aderemi Benjamin Olufemi
    AU  - Zakariyau Sulaiman
    AU  - Ahmed Usman
    Y1  - 2026/11/11
    PY  - 2026
    N1  - https://doi.org/10.11648/j.frontiers.20260604.17
    DO  - 10.11648/j.frontiers.20260604.17
    T2  - Frontiers
    JF  - Frontiers
    JO  - Frontiers
    SP  - 206
    EP  - 218
    PB  - Science Publishing Group
    SN  - 2994-7197
    UR  - https://doi.org/10.11648/j.frontiers.20260604.17
    AB  - The physiochemical properties of Natural Bentonite Clay (NBC) were modified in this work to increase its adsorption performance. The NBC was mined from Fika town in Yobe State and thereafter subjected to beneficiation to obtain various particle sizes. The modified NBC and Activated Bentonite Clay (ABC) were characterized using Fourier transform infrared (FTIR) spectroscopy for the determination of the effect of acid attack and the adsorbate Braunner-Emmet-Teller (BET) method for surface area determination was conducted on the clay sample before and after modification procedure. The surface areas of the adsorbents before and after modification were found to be 126.50 m2/g and 160.40 m2/g for NBC and ABC respectively. The raw and the modified samples had an adsorption capacity of 12.55 and 74.98 mg/g which were used to purify the simulated textile wastewater to investigate their adsorptive performance. The equilibrium data were fitted in Langmuir, Freundlich and Temkin adsorption isotherm models with the aid of origin 9 software using two statistical parameters- the correlation coefficient R and Sum of Square Errors SSE. Results showed the experimental data was best fitted in the Langmuir isotherm model where R values of ABC was consistently higher for dye 1-dye 4 than that of NBC. The SSE of ABC was also found to be consistently lower for all dye adsorption than that of NBC.
    VL  - 6
    IS  - 4
    ER  - 

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Author Information
  • Department of Chemical Engineering, Ahmadu Bello University, Zaria, Nigeria

  • Department of Chemistry, Ahmadu Bello University, Zaria, Nigeria

  • Department of Chemical Engineering, Ahmadu Bello University, Zaria, Nigeria

  • Department of Applied Chemistry, Federal University of Technology, Babura, Nigeria

  • Department of Applied Chemistry, Federal University of Technology, Babura, Nigeria

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