A Study of Electrochemical Behavior for Redox Current Peaks of Sodium Saccharin at Different Temperature Using Nano-Sensor

Muhammed Mizher Radhi; Yousif A. Kadium; Anfal Ismael Ibrahim

doi:doi:10.11648/j.ejcbs.20170302.12

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A Study of Electrochemical Behavior for Redox Current Peaks of Sodium Saccharin at Different Temperature Using Nano-Sensor

Muhammed Mizher Radhi, Yousif A. Kadium, Anfal Ismael Ibrahim

Published in European Journal of Clinical and Biomedical Sciences (Volume 3, Issue 2)

Received: 25 January 2017 Accepted: 24 February 2017 Published: 25 April 2017

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Abstract

The study of Sodium Saccharin (NaSc), this one of the chemical compounds was used as a replacement for natural sugar, which taking by diabetic patients. NaSc was studied by cyclic voltammetric technique to analysis at different temperature using modified glassy carbon electrode (GCE) with carbon nanotubes (CNT) as working electrode (CNT/GCE). Activation energy (E_a^*) of NaSc was studied in 1M Na₂SO₄ as an electrolyte at different temperature using Arrhenius equation at both GCE and CNT/GCE. Other thermodynamic parameters such as activation free energy (∆G*), activation enthalpy (∆H*) and activation entropy (∆S*) were determined at both GCE and CNT/GCE using Eyring equation. Other thermodynamic parameters such as the values of entropy for cathodic current peak of NaSc on GCE and CNT/GCE are positive value, this means that the reaction is spontaneous reversible, but the negative values of entropy is irreversible reaction.

Published in	European Journal of Clinical and Biomedical Sciences (Volume 3, Issue 2)
DOI	10.11648/j.ejcbs.20170302.12
Page(s)	47-52
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2017. Published by Science Publishing Group

Keywords

Sodium Saccharin, Nano-Sensor, Cyclic Voltammetry, Different Temperature, Thermodynamic Parameters, Non-aqueous Electrolyte

References

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APA Style

Muhammed Mizher Radhi, Yousif A. Kadium, Anfal Ismael Ibrahim. (2017). A Study of Electrochemical Behavior for Redox Current Peaks of Sodium Saccharin at Different Temperature Using Nano-Sensor. European Journal of Clinical and Biomedical Sciences, 3(2), 47-52. https://doi.org/10.11648/j.ejcbs.20170302.12

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ACS Style

Muhammed Mizher Radhi; Yousif A. Kadium; Anfal Ismael Ibrahim. A Study of Electrochemical Behavior for Redox Current Peaks of Sodium Saccharin at Different Temperature Using Nano-Sensor. Eur. J. Clin. Biomed. Sci. 2017, 3(2), 47-52. doi: 10.11648/j.ejcbs.20170302.12

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AMA Style

Muhammed Mizher Radhi, Yousif A. Kadium, Anfal Ismael Ibrahim. A Study of Electrochemical Behavior for Redox Current Peaks of Sodium Saccharin at Different Temperature Using Nano-Sensor. Eur J Clin Biomed Sci. 2017;3(2):47-52. doi: 10.11648/j.ejcbs.20170302.12

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@article{10.11648/j.ejcbs.20170302.12,
  author = {Muhammed Mizher Radhi and Yousif A. Kadium and Anfal Ismael Ibrahim},
  title = {A Study of Electrochemical Behavior for Redox Current Peaks of Sodium Saccharin at Different Temperature Using Nano-Sensor},
  journal = {European Journal of Clinical and Biomedical Sciences},
  volume = {3},
  number = {2},
  pages = {47-52},
  doi = {10.11648/j.ejcbs.20170302.12},
  url = {https://doi.org/10.11648/j.ejcbs.20170302.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ejcbs.20170302.12},
  abstract = {The study of Sodium Saccharin (NaSc), this one of the chemical compounds was used as a replacement for natural sugar, which taking by diabetic patients. NaSc was studied by cyclic voltammetric technique to analysis at different temperature using modified glassy carbon electrode (GCE) with carbon nanotubes (CNT) as working electrode (CNT/GCE). Activation energy (Ea*) of NaSc was studied in 1M Na2SO4 as an electrolyte at different temperature using Arrhenius equation at both GCE and CNT/GCE. Other thermodynamic parameters such as activation free energy (∆G*), activation enthalpy (∆H*) and activation entropy (∆S*) were determined at both GCE and CNT/GCE using Eyring equation. Other thermodynamic parameters such as the values of entropy for cathodic current peak of NaSc on GCE and CNT/GCE are positive value, this means that the reaction is spontaneous reversible, but the negative values of entropy is irreversible reaction.},
 year = {2017}
}

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TY  - JOUR
T1  - A Study of Electrochemical Behavior for Redox Current Peaks of Sodium Saccharin at Different Temperature Using Nano-Sensor
AU  - Muhammed Mizher Radhi
AU  - Yousif A. Kadium
AU  - Anfal Ismael Ibrahim
Y1  - 2017/04/25
PY  - 2017
N1  - https://doi.org/10.11648/j.ejcbs.20170302.12
DO  - 10.11648/j.ejcbs.20170302.12
T2  - European Journal of Clinical and Biomedical Sciences
JF  - European Journal of Clinical and Biomedical Sciences
JO  - European Journal of Clinical and Biomedical Sciences
SP  - 47
EP  - 52
PB  - Science Publishing Group
SN  - 2575-5005
UR  - https://doi.org/10.11648/j.ejcbs.20170302.12
AB  - The study of Sodium Saccharin (NaSc), this one of the chemical compounds was used as a replacement for natural sugar, which taking by diabetic patients. NaSc was studied by cyclic voltammetric technique to analysis at different temperature using modified glassy carbon electrode (GCE) with carbon nanotubes (CNT) as working electrode (CNT/GCE). Activation energy (Ea*) of NaSc was studied in 1M Na2SO4 as an electrolyte at different temperature using Arrhenius equation at both GCE and CNT/GCE. Other thermodynamic parameters such as activation free energy (∆G*), activation enthalpy (∆H*) and activation entropy (∆S*) were determined at both GCE and CNT/GCE using Eyring equation. Other thermodynamic parameters such as the values of entropy for cathodic current peak of NaSc on GCE and CNT/GCE are positive value, this means that the reaction is spontaneous reversible, but the negative values of entropy is irreversible reaction.
VL  - 3
IS  - 2
ER  -

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Author Information

Muhammed Mizher Radhi

Radiological Techniques Department, Health and Medical Technology College-Baghdad, Middle Technology University, Baghdad, Iraq
Yousif A. Kadium

Chemistry Department, Science College, Al-Mustansiriyah University, Baghdad, Iraq
Anfal Ismael Ibrahim

Chemistry Department, Science College, Al-Mustansiriyah University, Baghdad, Iraq

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Plain Text BibTeX RIS

APA Style

Muhammed Mizher Radhi, Yousif A. Kadium, Anfal Ismael Ibrahim. (2017). A Study of Electrochemical Behavior for Redox Current Peaks of Sodium Saccharin at Different Temperature Using Nano-Sensor. European Journal of Clinical and Biomedical Sciences, 3(2), 47-52. https://doi.org/10.11648/j.ejcbs.20170302.12

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ACS Style

Muhammed Mizher Radhi; Yousif A. Kadium; Anfal Ismael Ibrahim. A Study of Electrochemical Behavior for Redox Current Peaks of Sodium Saccharin at Different Temperature Using Nano-Sensor. Eur. J. Clin. Biomed. Sci. 2017, 3(2), 47-52. doi: 10.11648/j.ejcbs.20170302.12

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AMA Style

Muhammed Mizher Radhi, Yousif A. Kadium, Anfal Ismael Ibrahim. A Study of Electrochemical Behavior for Redox Current Peaks of Sodium Saccharin at Different Temperature Using Nano-Sensor. Eur J Clin Biomed Sci. 2017;3(2):47-52. doi: 10.11648/j.ejcbs.20170302.12

Copy | Download

@article{10.11648/j.ejcbs.20170302.12,
  author = {Muhammed Mizher Radhi and Yousif A. Kadium and Anfal Ismael Ibrahim},
  title = {A Study of Electrochemical Behavior for Redox Current Peaks of Sodium Saccharin at Different Temperature Using Nano-Sensor},
  journal = {European Journal of Clinical and Biomedical Sciences},
  volume = {3},
  number = {2},
  pages = {47-52},
  doi = {10.11648/j.ejcbs.20170302.12},
  url = {https://doi.org/10.11648/j.ejcbs.20170302.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ejcbs.20170302.12},
  abstract = {The study of Sodium Saccharin (NaSc), this one of the chemical compounds was used as a replacement for natural sugar, which taking by diabetic patients. NaSc was studied by cyclic voltammetric technique to analysis at different temperature using modified glassy carbon electrode (GCE) with carbon nanotubes (CNT) as working electrode (CNT/GCE). Activation energy (Ea*) of NaSc was studied in 1M Na2SO4 as an electrolyte at different temperature using Arrhenius equation at both GCE and CNT/GCE. Other thermodynamic parameters such as activation free energy (∆G*), activation enthalpy (∆H*) and activation entropy (∆S*) were determined at both GCE and CNT/GCE using Eyring equation. Other thermodynamic parameters such as the values of entropy for cathodic current peak of NaSc on GCE and CNT/GCE are positive value, this means that the reaction is spontaneous reversible, but the negative values of entropy is irreversible reaction.},
 year = {2017}
}

Copy | Download

TY  - JOUR
T1  - A Study of Electrochemical Behavior for Redox Current Peaks of Sodium Saccharin at Different Temperature Using Nano-Sensor
AU  - Muhammed Mizher Radhi
AU  - Yousif A. Kadium
AU  - Anfal Ismael Ibrahim
Y1  - 2017/04/25
PY  - 2017
N1  - https://doi.org/10.11648/j.ejcbs.20170302.12
DO  - 10.11648/j.ejcbs.20170302.12
T2  - European Journal of Clinical and Biomedical Sciences
JF  - European Journal of Clinical and Biomedical Sciences
JO  - European Journal of Clinical and Biomedical Sciences
SP  - 47
EP  - 52
PB  - Science Publishing Group
SN  - 2575-5005
UR  - https://doi.org/10.11648/j.ejcbs.20170302.12
AB  - The study of Sodium Saccharin (NaSc), this one of the chemical compounds was used as a replacement for natural sugar, which taking by diabetic patients. NaSc was studied by cyclic voltammetric technique to analysis at different temperature using modified glassy carbon electrode (GCE) with carbon nanotubes (CNT) as working electrode (CNT/GCE). Activation energy (Ea*) of NaSc was studied in 1M Na2SO4 as an electrolyte at different temperature using Arrhenius equation at both GCE and CNT/GCE. Other thermodynamic parameters such as activation free energy (∆G*), activation enthalpy (∆H*) and activation entropy (∆S*) were determined at both GCE and CNT/GCE using Eyring equation. Other thermodynamic parameters such as the values of entropy for cathodic current peak of NaSc on GCE and CNT/GCE are positive value, this means that the reaction is spontaneous reversible, but the negative values of entropy is irreversible reaction.
VL  - 3
IS  - 2
ER  -

Copy | Download