Nanopowder of Ba0.7Ca0.3TiO3 (BCT) lead free ferroelectric ceramic was synthesized by hydroxide co-precipitation method. As-synthesized powder is sintered using the microwave sintering technique at different temperature 1100°C and 1200°C. Sintered ceramic samples were investigated for its structural, morphological, and temperature dependent dielectric properties. Structural analysis confirms biphasic crystal structure, tetragonal phase corresponding to BaTiO3 lattice and orthorhombic phase resulting from the CaTiO3 lattice. Scanning electron microscope images reveals the formation of grains with higher density. Ferroelectric-Paraelectric transition (Tc) of the material shifts towards higher temperature (Tc ~ 155°C) with maximum dielectric constant and low loss tangent.
| Published in | Colloid and Surface Science (Volume 2, Issue 2) |
| DOI | 10.11648/j.css.20170202.15 |
| Page(s) | 76-80 |
| Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
| Copyright |
Copyright © The Author(s), 2017. Published by Science Publishing Group |
Ferroelectrics, Microwave Sintering, Dielectric Properties, Microstructure, Phase Transformation
| [1] | V. Sreenivas Puli, D. K. Pradhan, B. C. Riggs, D. B. Chrisey, R. S. Katiyar. J. Alloy. Compd.; 2014, 584, 369. |
| [2] | Z. Yu, C. Ang, R. Guo, A. S. Bhalla. J. Appl. Phys.; 2002, 92, 1489. |
| [3] | S. M. Mane, P. M. Tirmali, D. J. Salunkhe, P. B. Joshi, C. B. Kolekar, S. B. Kulkarni. J. Mater Sci: Mater Electron.; 2016, 27 (7), 7204. |
| [4] | S. Mane, P. Tirmali, S. Kadam, A. Tarale, C. Kolekar, S. Kulkarni. J. Chin. Adv. Mate. Soci.; 2016, 4 (4), 269. |
| [5] | P. Victor, R. Ranjith, S. B. Krupanidhi. J. Appl. Phys.; 2003, 94 (12), 7702. |
| [6] | R. S. da Silva, J. C. M’Peko, L. da Costa Fontes, A. C. Hernandes. Mate. Res.; 2009, 12 (3), 287. |
| [7] | O. P. Thakur, C. Prakash, D. K. Agrawal. Mate. Sci. Engg. B.; 2002, 96, 221. |
| [8] | O. P. Thakur, C. Prakash, D. K. Agrawal. Mate. Lett.; 2002, 56, 970. |
| [9] | X. Hao. J. Adv. Dielect.; 2013, 3 (1), (1330001) 1. |
| [10] | M. R. Panigrahi, S. Panigrahi. Phys. B.; 2010, 405, 2556. |
| [11] | N. Baskaran, H. Chang. Mate. Chem. Phys.; 2002, 77, 889. |
| [12] | Sonia, R. K. Patel, P. Kumar, C. Prakash, D. K. Agrawal. Ceram. Int.; 2012, 38, 1585. |
APA Style
Sagar M. Mane, Pravin M. Tirmali, Snehal L. Kadam, Chandrakant B. Kolekar, Shrinivas B. Kulkarni. (2017). Microstructural and High Tc Dielectric Properties of Microwave Sintered Ba0.7Ca0.3TiO3 (BCT) Ceramic. Colloid and Surface Science, 2(2), 76-80. https://doi.org/10.11648/j.css.20170202.15
ACS Style
Sagar M. Mane; Pravin M. Tirmali; Snehal L. Kadam; Chandrakant B. Kolekar; Shrinivas B. Kulkarni. Microstructural and High Tc Dielectric Properties of Microwave Sintered Ba0.7Ca0.3TiO3 (BCT) Ceramic. Colloid Surf. Sci. 2017, 2(2), 76-80. doi: 10.11648/j.css.20170202.15
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Download@article{10.11648/j.css.20170202.15,
author = {Sagar M. Mane and Pravin M. Tirmali and Snehal L. Kadam and Chandrakant B. Kolekar and Shrinivas B. Kulkarni},
title = {Microstructural and High Tc Dielectric Properties of Microwave Sintered Ba0.7Ca0.3TiO3 (BCT) Ceramic},
journal = {Colloid and Surface Science},
volume = {2},
number = {2},
pages = {76-80},
doi = {10.11648/j.css.20170202.15},
url = {https://doi.org/10.11648/j.css.20170202.15},
eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.css.20170202.15},
abstract = {Nanopowder of Ba0.7Ca0.3TiO3 (BCT) lead free ferroelectric ceramic was synthesized by hydroxide co-precipitation method. As-synthesized powder is sintered using the microwave sintering technique at different temperature 1100°C and 1200°C. Sintered ceramic samples were investigated for its structural, morphological, and temperature dependent dielectric properties. Structural analysis confirms biphasic crystal structure, tetragonal phase corresponding to BaTiO3 lattice and orthorhombic phase resulting from the CaTiO3 lattice. Scanning electron microscope images reveals the formation of grains with higher density. Ferroelectric-Paraelectric transition (Tc) of the material shifts towards higher temperature (Tc ~ 155°C) with maximum dielectric constant and low loss tangent.},
year = {2017}
}
TY - JOUR T1 - Microstructural and High Tc Dielectric Properties of Microwave Sintered Ba0.7Ca0.3TiO3 (BCT) Ceramic AU - Sagar M. Mane AU - Pravin M. Tirmali AU - Snehal L. Kadam AU - Chandrakant B. Kolekar AU - Shrinivas B. Kulkarni Y1 - 2017/04/10 PY - 2017 N1 - https://doi.org/10.11648/j.css.20170202.15 DO - 10.11648/j.css.20170202.15 T2 - Colloid and Surface Science JF - Colloid and Surface Science JO - Colloid and Surface Science SP - 76 EP - 80 PB - Science Publishing Group SN - 2578-9236 UR - https://doi.org/10.11648/j.css.20170202.15 AB - Nanopowder of Ba0.7Ca0.3TiO3 (BCT) lead free ferroelectric ceramic was synthesized by hydroxide co-precipitation method. As-synthesized powder is sintered using the microwave sintering technique at different temperature 1100°C and 1200°C. Sintered ceramic samples were investigated for its structural, morphological, and temperature dependent dielectric properties. Structural analysis confirms biphasic crystal structure, tetragonal phase corresponding to BaTiO3 lattice and orthorhombic phase resulting from the CaTiO3 lattice. Scanning electron microscope images reveals the formation of grains with higher density. Ferroelectric-Paraelectric transition (Tc) of the material shifts towards higher temperature (Tc ~ 155°C) with maximum dielectric constant and low loss tangent. VL - 2 IS - 2 ER -
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