Walnut Inspired Silicon Carbon Composites for Stable Lithium Ions Battery Anodes

Xuli Ding; Daowei Liang; Yi Liu

doi:doi:10.11648/j.cm.20200401.11

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Walnut Inspired Silicon Carbon Composites for Stable Lithium Ions Battery Anodes

Xuli Ding, Daowei Liang, Yi Liu

Published in Composite Materials (Volume 4, Issue 1)

Received: 29 November 2019 Accepted: 21 December 2019 Published: 6 January 2020

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Abstract

The distinct quality of silicon (Si) makes it a natural choice for employment as a competitive anode material in rechargeable high specific energy lithium-ion batteries (LIBs) for practical applications. However, the Si-based LIBs are still hindered for practical applications due to the weak electrical conductivity and unstable solid electrolyte interfaces (SEI). New structures with enhanced conduction are highly desired to push the advance of Si-based LIBs. Herein, the Si nanoparticles coated by few-layer graphene (fGra) has been wrapped into honeycomb porous carbon (Pc) framework with good Si-C contact and reliable void via a simple chemical vapor deposition accompanying with freeze drying strategy. The walnut-type structure noted as Si@Gra@Pc is obtained, in which the porous architecture not only shorten the transfer distance of the lithium ions but also provide good electrical conductivity for the charge carriers. Moreover, the porous structure permit the free expansion of Si during charging/discharging cycling and preserve the integrity of the electrode owing to the brawny mechanical strength of Gra and Pc framework. Importantly, it is found that the Si@Gra@Pc composites show good rate capability reached to 5Ag^-1 with specific capacity of 450 mAh g^-1 and good cycling stability with no distinct capacity decay even after 1000 cycles, which are obvious improving compared with that of the bare Si anodes. Combined with the simple and feasible fabrication method and improved electrochemical performance for the Si anodes in LIBs. The present walnut-type Si@Gra@Pc composite is considered as the promising and meaningful Si-based anode materials and candidates in the development of next-generation high specific energy LIBs.

Published in	Composite Materials (Volume 4, Issue 1)
DOI	10.11648/j.cm.20200401.11
Page(s)	1-7
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2020. Published by Science Publishing Group

Keywords

Silicon, Lithium-ion Battery, Anode, Graphene, CVD

References

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APA Style

Xuli Ding, Daowei Liang, Yi Liu. (2020). Walnut Inspired Silicon Carbon Composites for Stable Lithium Ions Battery Anodes. Composite Materials, 4(1), 1-7. https://doi.org/10.11648/j.cm.20200401.11

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ACS Style

Xuli Ding; Daowei Liang; Yi Liu. Walnut Inspired Silicon Carbon Composites for Stable Lithium Ions Battery Anodes. Compos. Mater. 2020, 4(1), 1-7. doi: 10.11648/j.cm.20200401.11

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AMA Style

Xuli Ding, Daowei Liang, Yi Liu. Walnut Inspired Silicon Carbon Composites for Stable Lithium Ions Battery Anodes. Compos Mater. 2020;4(1):1-7. doi: 10.11648/j.cm.20200401.11

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@article{10.11648/j.cm.20200401.11,
  author = {Xuli Ding and Daowei Liang and Yi Liu},
  title = {Walnut Inspired Silicon Carbon Composites for Stable Lithium Ions Battery Anodes},
  journal = {Composite Materials},
  volume = {4},
  number = {1},
  pages = {1-7},
  doi = {10.11648/j.cm.20200401.11},
  url = {https://doi.org/10.11648/j.cm.20200401.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.cm.20200401.11},
  abstract = {The distinct quality of silicon (Si) makes it a natural choice for employment as a competitive anode material in rechargeable high specific energy lithium-ion batteries (LIBs) for practical applications. However, the Si-based LIBs are still hindered for practical applications due to the weak electrical conductivity and unstable solid electrolyte interfaces (SEI). New structures with enhanced conduction are highly desired to push the advance of Si-based LIBs. Herein, the Si nanoparticles coated by few-layer graphene (fGra) has been wrapped into honeycomb porous carbon (Pc) framework with good Si-C contact and reliable void via a simple chemical vapor deposition accompanying with freeze drying strategy. The walnut-type structure noted as Si@Gra@Pc is obtained, in which the porous architecture not only shorten the transfer distance of the lithium ions but also provide good electrical conductivity for the charge carriers. Moreover, the porous structure permit the free expansion of Si during charging/discharging cycling and preserve the integrity of the electrode owing to the brawny mechanical strength of Gra and Pc framework. Importantly, it is found that the Si@Gra@Pc composites show good rate capability reached to 5Ag-1 with specific capacity of 450 mAh g-1 and good cycling stability with no distinct capacity decay even after 1000 cycles, which are obvious improving compared with that of the bare Si anodes. Combined with the simple and feasible fabrication method and improved electrochemical performance for the Si anodes in LIBs. The present walnut-type Si@Gra@Pc composite is considered as the promising and meaningful Si-based anode materials and candidates in the development of next-generation high specific energy LIBs.},
 year = {2020}
}

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TY  - JOUR
T1  - Walnut Inspired Silicon Carbon Composites for Stable Lithium Ions Battery Anodes
AU  - Xuli Ding
AU  - Daowei Liang
AU  - Yi Liu
Y1  - 2020/01/06
PY  - 2020
N1  - https://doi.org/10.11648/j.cm.20200401.11
DO  - 10.11648/j.cm.20200401.11
T2  - Composite Materials
JF  - Composite Materials
JO  - Composite Materials
SP  - 1
EP  - 7
PB  - Science Publishing Group
SN  - 2994-7103
UR  - https://doi.org/10.11648/j.cm.20200401.11
AB  - The distinct quality of silicon (Si) makes it a natural choice for employment as a competitive anode material in rechargeable high specific energy lithium-ion batteries (LIBs) for practical applications. However, the Si-based LIBs are still hindered for practical applications due to the weak electrical conductivity and unstable solid electrolyte interfaces (SEI). New structures with enhanced conduction are highly desired to push the advance of Si-based LIBs. Herein, the Si nanoparticles coated by few-layer graphene (fGra) has been wrapped into honeycomb porous carbon (Pc) framework with good Si-C contact and reliable void via a simple chemical vapor deposition accompanying with freeze drying strategy. The walnut-type structure noted as Si@Gra@Pc is obtained, in which the porous architecture not only shorten the transfer distance of the lithium ions but also provide good electrical conductivity for the charge carriers. Moreover, the porous structure permit the free expansion of Si during charging/discharging cycling and preserve the integrity of the electrode owing to the brawny mechanical strength of Gra and Pc framework. Importantly, it is found that the Si@Gra@Pc composites show good rate capability reached to 5Ag-1 with specific capacity of 450 mAh g-1 and good cycling stability with no distinct capacity decay even after 1000 cycles, which are obvious improving compared with that of the bare Si anodes. Combined with the simple and feasible fabrication method and improved electrochemical performance for the Si anodes in LIBs. The present walnut-type Si@Gra@Pc composite is considered as the promising and meaningful Si-based anode materials and candidates in the development of next-generation high specific energy LIBs.
VL  - 4
IS  - 1
ER  -

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Author Information

Xuli Ding

School of Science, Jiangsu University of Science and Technology, Zhenjiang, The People’s Republic of China
Daowei Liang

School of Science, Jiangsu University of Science and Technology, Zhenjiang, The People’s Republic of China
Yi Liu

Shanghai Synchrotron Radiation Facility, Chinese Academy of Science, Shanghai, The People’s Republic of China

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APA Style

Xuli Ding, Daowei Liang, Yi Liu. (2020). Walnut Inspired Silicon Carbon Composites for Stable Lithium Ions Battery Anodes. Composite Materials, 4(1), 1-7. https://doi.org/10.11648/j.cm.20200401.11

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ACS Style

Xuli Ding; Daowei Liang; Yi Liu. Walnut Inspired Silicon Carbon Composites for Stable Lithium Ions Battery Anodes. Compos. Mater. 2020, 4(1), 1-7. doi: 10.11648/j.cm.20200401.11

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AMA Style

Xuli Ding, Daowei Liang, Yi Liu. Walnut Inspired Silicon Carbon Composites for Stable Lithium Ions Battery Anodes. Compos Mater. 2020;4(1):1-7. doi: 10.11648/j.cm.20200401.11

Copy | Download

@article{10.11648/j.cm.20200401.11,
  author = {Xuli Ding and Daowei Liang and Yi Liu},
  title = {Walnut Inspired Silicon Carbon Composites for Stable Lithium Ions Battery Anodes},
  journal = {Composite Materials},
  volume = {4},
  number = {1},
  pages = {1-7},
  doi = {10.11648/j.cm.20200401.11},
  url = {https://doi.org/10.11648/j.cm.20200401.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.cm.20200401.11},
  abstract = {The distinct quality of silicon (Si) makes it a natural choice for employment as a competitive anode material in rechargeable high specific energy lithium-ion batteries (LIBs) for practical applications. However, the Si-based LIBs are still hindered for practical applications due to the weak electrical conductivity and unstable solid electrolyte interfaces (SEI). New structures with enhanced conduction are highly desired to push the advance of Si-based LIBs. Herein, the Si nanoparticles coated by few-layer graphene (fGra) has been wrapped into honeycomb porous carbon (Pc) framework with good Si-C contact and reliable void via a simple chemical vapor deposition accompanying with freeze drying strategy. The walnut-type structure noted as Si@Gra@Pc is obtained, in which the porous architecture not only shorten the transfer distance of the lithium ions but also provide good electrical conductivity for the charge carriers. Moreover, the porous structure permit the free expansion of Si during charging/discharging cycling and preserve the integrity of the electrode owing to the brawny mechanical strength of Gra and Pc framework. Importantly, it is found that the Si@Gra@Pc composites show good rate capability reached to 5Ag-1 with specific capacity of 450 mAh g-1 and good cycling stability with no distinct capacity decay even after 1000 cycles, which are obvious improving compared with that of the bare Si anodes. Combined with the simple and feasible fabrication method and improved electrochemical performance for the Si anodes in LIBs. The present walnut-type Si@Gra@Pc composite is considered as the promising and meaningful Si-based anode materials and candidates in the development of next-generation high specific energy LIBs.},
 year = {2020}
}

Copy | Download

TY  - JOUR
T1  - Walnut Inspired Silicon Carbon Composites for Stable Lithium Ions Battery Anodes
AU  - Xuli Ding
AU  - Daowei Liang
AU  - Yi Liu
Y1  - 2020/01/06
PY  - 2020
N1  - https://doi.org/10.11648/j.cm.20200401.11
DO  - 10.11648/j.cm.20200401.11
T2  - Composite Materials
JF  - Composite Materials
JO  - Composite Materials
SP  - 1
EP  - 7
PB  - Science Publishing Group
SN  - 2994-7103
UR  - https://doi.org/10.11648/j.cm.20200401.11
AB  - The distinct quality of silicon (Si) makes it a natural choice for employment as a competitive anode material in rechargeable high specific energy lithium-ion batteries (LIBs) for practical applications. However, the Si-based LIBs are still hindered for practical applications due to the weak electrical conductivity and unstable solid electrolyte interfaces (SEI). New structures with enhanced conduction are highly desired to push the advance of Si-based LIBs. Herein, the Si nanoparticles coated by few-layer graphene (fGra) has been wrapped into honeycomb porous carbon (Pc) framework with good Si-C contact and reliable void via a simple chemical vapor deposition accompanying with freeze drying strategy. The walnut-type structure noted as Si@Gra@Pc is obtained, in which the porous architecture not only shorten the transfer distance of the lithium ions but also provide good electrical conductivity for the charge carriers. Moreover, the porous structure permit the free expansion of Si during charging/discharging cycling and preserve the integrity of the electrode owing to the brawny mechanical strength of Gra and Pc framework. Importantly, it is found that the Si@Gra@Pc composites show good rate capability reached to 5Ag-1 with specific capacity of 450 mAh g-1 and good cycling stability with no distinct capacity decay even after 1000 cycles, which are obvious improving compared with that of the bare Si anodes. Combined with the simple and feasible fabrication method and improved electrochemical performance for the Si anodes in LIBs. The present walnut-type Si@Gra@Pc composite is considered as the promising and meaningful Si-based anode materials and candidates in the development of next-generation high specific energy LIBs.
VL  - 4
IS  - 1
ER  -

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