In this work, the authors melt blending method fabrication of the composites. The physico-chemical, morphological and mechanical properties of the composites were investigated. The test results showed that, there was an improvement at all level. The optimal impact strength and tensile strength of the studied composite were 3441.79 MPa and 6.021 MPa. The flexural strengt was noted to improve from 11.92 MPa to 16.79 MPa. The incorporation of Snail shells to PVC blends decreased the density from 1.34 gcm-1 to 1.18 gcm-1 while water intake was noted to decrease from 0.18% to 0.12%. The FTIR revealed OH, which is an indication of the material hydrophobic nature. The stretching vibration of aliphatic C-H in the PVC structure was at 2918.5 and 2855.1 cm−1 in the control PVC blends corresponds with. The C=C bond of aromatic functional group at; 1602.8 cm-1 in the composites. The FTIR examination of the control PVC had absorption band at 1423.8 cm−1 corresponding to –CH2 of methylene group. The absorption band 1453.7 cm−1 corresponds with –CH2. It can also be observed that, the control PVC blend showed no absorption band that corresponds with –CH3. This is due to absence of a methyl group in the structure of polyvinyl chloride. The absorption band noticed in all the samples is that of absorption peaks of 697.0 and 752.9 cm-1 which corresponds to C-Cl bond which represents a chloride functional group in PVC. The SEM analysis showed that, the Snail Shell were uniformly dispersed in the polymer blends and, explained the improved mechanical properties observed in the study.
| Published in | American Journal of Polymer Science and Technology (Volume 9, Issue 4) |
| DOI | 10.11648/j.ajpst.20230904.11 |
| Page(s) | 45-54 |
| Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
| Copyright |
Copyright © The Author(s), 2023. Published by Science Publishing Group |
Polyvinyl Chloride, Polystyrene, Polypropylene, Snail Shells, Mechanical Properties
| [1] | Abdel-Gawad, N. M. K., El Dein, A. Z., Mansour, D. -E. A., Ahmed, H. M., Darwish, M. M. F. and Lehtonen, M. (2017). Enhancement of dielectric and mechanical properties of Polyvinyl Chloride nanocomposites using functionalized TiO2 nanoparticles," in IEEE Transactions on Dielectrics and Electrical Insulation, vol. 24, no. 6, pp. 3490-3499, Dec. 2017, doi: 10.1109/TDEI.2017.006692. |
| [2] | Adeosun, S. O., Akpan, E. I. and Akanegbu, H. A. (2015). Thermo-mechanical properties of unsaturated polyester reinforced with coconut and Snail shells. International journal of composite material, 5 (3): 52-64. |
| [3] | Owuamanam, S., & Cree, D. (2020). Progress of Bio-Calcium Carbonate Waste Eggshell and Seashell Fillers in Polymer Composites: A Review. Journal of Composites Science, 4 (2), 70. doi: 10.3390/jcs4020070. |
| [4] | Mark, U. C., Madufor, I. C., Obasi, H. C., & Mark, U. (2019). Influence of filler loading on the mechanical and morphological properties of carbonized coconut shell particles reinforced polypropylene composites. Journal of Composite Materials, 002199831985607. doi: 10.1177/0021998319856070. |
| [5] | Chen, R., Liu, X., Han, L., Zhang, Z. and Li, Y. (2020). Morphology, thermal behavior, rheological, and mechanical properties of polypropylene/polystyrene blends based on elongation flow. 1–11. https://doi. org/10.1002/pat.4998 |
| [6] | Abioye, T. E., Zuhailawati, H., Anasyida, A. S., Yahaya, S. A., and Dhindaw, B. K. (2019). Investigation of the microstructure, mechanical and wear properties of AA6o61-T6 friction stir weldment with different particulate reinforcement addition. Journal of materials Research and Technology, 8 (5): 3917-3928. |
| [7] | Tinastepe, N., Malkondu, O., and Kazazoglu, E. (2023). Hardness and surface roughness of differently processed denture base acrylic resins after immersion in simulated gastric acid. The journal of prosthetic Dentistry. |
| [8] | Punyapriya, M. (2012). Statistical Analysis for the Abrasive Wear Behaviour of Bagasse Fibre Reinforced Polymer Composite. International Journal of applied Research in Mechanical Engineering (Ijarme), 2 (2): 562-567. |
| [9] | Jacob, J., Mamza, P., Ahmed, A., and Yaro, S. (2018). Effect of benzoyl chloride treatment on the mechanical and viscoelastic properties of plantain peel powder-reinforced polyethylene composites. Science world journal, 13 (4): 25-29. |
| [10] | Sommerhuber, P. F., Wang, T. and Krause, A. (2016). Wood-plastic composites as potential applications of recycled plastics of electronic waste and recycled particleboard. Journal of Cleaner Production. |
| [11] | Aigbodion, V. S., Hassan, S. B., Ause, T. and Nyior, G. B. (2010). Potential Utilization of Solid Waste (Bagasse) Ash). Journal of Minerals and Mineral Characterization Engineering, 9, 67-77. |
| [12] | Elmanovich, I. V., Stakhanov, A. I., Zefirov, A. A., Pavlov, A. A., Lokshin, B V. and Gallyamov, M. O. (2020). Thermal oxidation of polypropylene catalysed by manganese oxide aerogel in oxygen-enriched supercritical carbon dioxide. The journal of supercritical fluids, 158, 104744. |
| [13] | Tan, W., Muyiyadi, M. and Ooi, Z. (2019). Characterization and feasibility of mimusops elengi seed shells powder as filler for thermoplastic material. AIP conference proceedings, 2157, 1-8. |
| [14] | Oladele, I. O., Adediran, A. A., Akinwekomi, A. D., Adegun, M. H., Olumakinde, O. O., & Daramola, O. O. (2020). Development of Ecofriendly Snail Shells Particulate-Reinforced Recycled Waste Plastic Composites for Automobile Application. The Scientific World Journal, 1–8. |
| [15] | Samir, A., El-Nashar, D. E., Ashour, A. H., Medhat, M. and El-kameesy, S. U. (2019). Polyvinyl chloride/styrene butadiene rubber polymeric blend filled with bismuth subcarbonate (BiO)2CO3 as a shield material for gamma rays. Polymer composites, 1-9. |
| [16] | Liang, D., Ding, Z., Yan, Q., Hasanagic, Fathi, L., Yang, Z., Li, Wang, J., Luo, H. and Wang, Q. (2023). a primary study on mechanical properties of heat-treated wood via in-situ synthesis of calcium carbonate. Journal of reneweal materials, 11 (1): 435-451. |
| [17] | Ervina, J., Mariatti, M., & Hamdan, S. (2016). Effect of Filler Loading on the Tensile Properties of Multi-walled Carbon Nanotube and Graphene Nanopowder filled Epoxy Composites. Procedia Chemistry, 19, 897–905. doi: 10.1016/j.proche.2016.03.132. |
| [18] | Ozsoy, I., Demirkol, A., Mimaroglu, A., Unal, H. and Demir, Z. (2015). The influence of micro and nano-filler content on the mechanical properties of epoxy composites. Journal of mechanical engineering, 61 (10): 601-609. |
| [19] | Abraham, A., Soloman, P. A., & Rejini, V. O. (2016). Preparation of Chitosan-Polyvinyl Alcohol Blends and Studies on Thermal and Mechanical Properties. Procedia Technology, 24, 741–748. doi: 10.1016/j.protcy.2016.05.206. |
| [20] | Ugur, K., Sherif, M. M. and Ozbulut, O. E. (2019). Tensile properties of graphene nanoplatelets/epoxy composites fabricated by various dispersion techniques. Polymer testing, 76, 181-191. |
| [21] | Dasan, Y. K., Bhat, A. H., and Faiza, A. (2017). Polymer blend of PLA/PHBV based bionanocomposites reinforced with nanocrystalline cellulose for potential application as packaging materials. Carbohydrate polymers, 157, 1323-1332. |
| [22] | Zheng, N., Wu, D., Sun, P., Liu, H., Lou, B. and Li, L. (2019). Mechanical properties and fire resistance of magnesium-cemented popular particleboard. Materials, 12 (19): 3161. |
| [23] | Tan, W. C. (2020). Characterisation and Development of New Bio-filler using Mimusops Elengi Seed shells Powder for Polypropylene Composites. A dissertation submitted to the Faculty of Engineering and Green Technology, University Tunku Abdul Rahman, in partial fulfillment of the requirements for the degree of Master of Engineering Science. |
| [24] | Tarani, E., Chrysafi, I., Kállay-Menyhárd, A., Pavlidou, E., Kehagias, T., Bikiaris, D. N., Chrissafis, K. (2020). Influence of Graphene Platelet Aspect Ratio on the Mechanical Properties of HDPE Nanocomposites: Microscopic Observation and Micromechanical Modeling. Polymers, 12 (8), 1719. |
| [25] | Rashid, B., Leman, Z., Jawaid, M., Ghazali, M. and Ishak, M. (2016). Physicochemical and thermal properties of lignocellulosic fiber from sugar palm fibers: effect of treatment. Cellulose, 23 (5), pp. 2905-2916. |
| [26] | Jia, P., Hu, L., Zhang, M., & Zhou, Y. (2015). TG-FTIR and TG-MS analysis applied to study the flame retardancy of PVC–castor oil-based chlorinated phosphate ester blends. Journal of Thermal Analysis and Calorimetry, 124 (3), 1331–1339. |
| [27] | Hajibeygi, M., Maleki, M., & Shabanian, M. (2018). The effects of poly (amide-imide) coating on the thermal, combustion and mechanical properties of polyvinyl chloride ZnO nanocomposites. Progress in Organic Coatings, 122, 96–106. |
| [28] | Damilalo, O., Ighalo, J., Adeniyi, A. and Hammed, K. (2020). Morphological and Thermal Properties of Polystyrene Composite Reinforced with Biochar from Plantain Stalk Fibre. Material International, 2 (2): 0150-0156. |
| [29] | Kim, M. H., Hwang, C. H., Kang, S. B., Kim, S., Park, S. W., Yun, Y.-S., & Won, S. W. (2015). Removal of hydrolyzed Reactive Black 5 from aqueous solution using a polyethylenimine-polyvinyl chloride composite fiber. Chemical Engineering Journal, 280, 18–25. |
| [30] | Mostafa, H., Airouyuawa, J. O., and Maqsood, S. (2022). A novel strategy for producing nano-particles from date seeds and enhancing their phenolic content and antioxidant properties using ultrasound-assisted extraction: A multivariate based optimization study. Ultrasonic sonochemistry, 87, 106017. |
| [31] | Abdelghany, A. M., Meikhail, M. S. and Asker, N. (2019). Synthesis and structural-biological correlation of PVC/PVAc polymers. Journal of materials Research and technology, 8 (5): 3908-3916. |
| [32] | Praveena, B. A., Santhosh, N., Abdulrajak, B., Srikanth, H. V., Shankar, G., Ramesha, K., Manjunath, N., Karthik, S. N., Rudra, N. M., and Praveen K. S. (2022). Experimental Investigation on Density and Volume Fraction of Void, and Mechanical Characteristics of Areca Nut Leaf Sheath Fiber-Reinforced Polymer Composites. International Journal of Polymer Science 1-13. |
| [33] | Han, X., Lu, X., & Vogt, R. D. (2019). An optimized density-based approach for extracting microplastics from soil and sediment samples. Environmental Pollution, 113009. |
| [34] | Hanana, F. E. and Rodrigue, D. (2021). Effect of particle size, fiber content, and surface treatment on the mechanical properties of maple-reinforced LLDPE produced by rotational molding. Polymers and Polymer Composites, 29 (5): 343–353. |
| [35] | Turku, I., Keskisaari, A., Kärki, T., Puurtinen, A., & Marttila, P. (2017). Characterization of wood plastic composites manufactured from recycled plastic blends. Composite Structures, 161, 469–476. |
APA Style
Levi Dooga, Casimir Emmanuel Gimba, Hamza Abba, Abdulrahman Musa. (2023). Study on the Morphological and Mechanical Properties of Polyvinyl Chloride Reinforced with Snail Shells. American Journal of Polymer Science and Technology, 9(4), 45-54. https://doi.org/10.11648/j.ajpst.20230904.11
ACS Style
Levi Dooga; Casimir Emmanuel Gimba; Hamza Abba; Abdulrahman Musa. Study on the Morphological and Mechanical Properties of Polyvinyl Chloride Reinforced with Snail Shells. Am. J. Polym. Sci. Technol. 2023, 9(4), 45-54. doi: 10.11648/j.ajpst.20230904.11
AMA Style
Levi Dooga, Casimir Emmanuel Gimba, Hamza Abba, Abdulrahman Musa. Study on the Morphological and Mechanical Properties of Polyvinyl Chloride Reinforced with Snail Shells. Am J Polym Sci Technol. 2023;9(4):45-54. doi: 10.11648/j.ajpst.20230904.11
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Download@article{10.11648/j.ajpst.20230904.11,
author = {Levi Dooga and Casimir Emmanuel Gimba and Hamza Abba and Abdulrahman Musa},
title = {Study on the Morphological and Mechanical Properties of Polyvinyl Chloride Reinforced with Snail Shells},
journal = {American Journal of Polymer Science and Technology},
volume = {9},
number = {4},
pages = {45-54},
doi = {10.11648/j.ajpst.20230904.11},
url = {https://doi.org/10.11648/j.ajpst.20230904.11},
eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpst.20230904.11},
abstract = {In this work, the authors melt blending method fabrication of the composites. The physico-chemical, morphological and mechanical properties of the composites were investigated. The test results showed that, there was an improvement at all level. The optimal impact strength and tensile strength of the studied composite were 3441.79 MPa and 6.021 MPa. The flexural strengt was noted to improve from 11.92 MPa to 16.79 MPa. The incorporation of Snail shells to PVC blends decreased the density from 1.34 gcm-1 to 1.18 gcm-1 while water intake was noted to decrease from 0.18% to 0.12%. The FTIR revealed OH, which is an indication of the material hydrophobic nature. The stretching vibration of aliphatic C-H in the PVC structure was at 2918.5 and 2855.1 cm−1 in the control PVC blends corresponds with. The C=C bond of aromatic functional group at; 1602.8 cm-1 in the composites. The FTIR examination of the control PVC had absorption band at 1423.8 cm−1 corresponding to –CH2 of methylene group. The absorption band 1453.7 cm−1 corresponds with –CH2. It can also be observed that, the control PVC blend showed no absorption band that corresponds with –CH3. This is due to absence of a methyl group in the structure of polyvinyl chloride. The absorption band noticed in all the samples is that of absorption peaks of 697.0 and 752.9 cm-1 which corresponds to C-Cl bond which represents a chloride functional group in PVC. The SEM analysis showed that, the Snail Shell were uniformly dispersed in the polymer blends and, explained the improved mechanical properties observed in the study.},
year = {2023}
}
TY - JOUR T1 - Study on the Morphological and Mechanical Properties of Polyvinyl Chloride Reinforced with Snail Shells AU - Levi Dooga AU - Casimir Emmanuel Gimba AU - Hamza Abba AU - Abdulrahman Musa Y1 - 2023/10/08 PY - 2023 N1 - https://doi.org/10.11648/j.ajpst.20230904.11 DO - 10.11648/j.ajpst.20230904.11 T2 - American Journal of Polymer Science and Technology JF - American Journal of Polymer Science and Technology JO - American Journal of Polymer Science and Technology SP - 45 EP - 54 PB - Science Publishing Group SN - 2575-5986 UR - https://doi.org/10.11648/j.ajpst.20230904.11 AB - In this work, the authors melt blending method fabrication of the composites. The physico-chemical, morphological and mechanical properties of the composites were investigated. The test results showed that, there was an improvement at all level. The optimal impact strength and tensile strength of the studied composite were 3441.79 MPa and 6.021 MPa. The flexural strengt was noted to improve from 11.92 MPa to 16.79 MPa. The incorporation of Snail shells to PVC blends decreased the density from 1.34 gcm-1 to 1.18 gcm-1 while water intake was noted to decrease from 0.18% to 0.12%. The FTIR revealed OH, which is an indication of the material hydrophobic nature. The stretching vibration of aliphatic C-H in the PVC structure was at 2918.5 and 2855.1 cm−1 in the control PVC blends corresponds with. The C=C bond of aromatic functional group at; 1602.8 cm-1 in the composites. The FTIR examination of the control PVC had absorption band at 1423.8 cm−1 corresponding to –CH2 of methylene group. The absorption band 1453.7 cm−1 corresponds with –CH2. It can also be observed that, the control PVC blend showed no absorption band that corresponds with –CH3. This is due to absence of a methyl group in the structure of polyvinyl chloride. The absorption band noticed in all the samples is that of absorption peaks of 697.0 and 752.9 cm-1 which corresponds to C-Cl bond which represents a chloride functional group in PVC. The SEM analysis showed that, the Snail Shell were uniformly dispersed in the polymer blends and, explained the improved mechanical properties observed in the study. VL - 9 IS - 4 ER -
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