Chemical Modification of Polystyrene Merrifield: Extraction of Zinc and Magnesium Located in Wastewater

Abid Ouerghui; Mokhtar Dardouri; Hichem Elamari; Faycel Ammari; Christian Girard

doi:doi:10.11648/j.ajpst.20190503.11

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Chemical Modification of Polystyrene Merrifield: Extraction of Zinc and Magnesium Located in Wastewater

Abid Ouerghui, Mokhtar Dardouri, Hichem Elamari, Faycel Ammari, Christian Girard

Published in American Journal of Polymer Science and Technology (Volume 5, Issue 3)

Received: 26 June 2019 Accepted: 19 July 2019 Published: 6 August 2019

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Abstract

In order to remove metals (Zn & Mg) located in wastewater, a new series of clickable polystyrene Merrifield grafted with azide and alkynes were synthesized and implicated in this domain. In a first step, we transformed the polystyrene Merrifield into the known Azidomethyl polystyrene, in a second step, a coupling reaction between the Azidomethyl polystyrene and dipropargylamine was realized for the synthesis of a new terminated polystyrene alkyne containing one unit of (1,4)-triazole. To increase the length of the chain grafted on the polystyrene Merrifield, several coupling reactions are applied, the main idea of this work was to increase the number of (1,2,3) –triazole units of this grafted chain. The click chemistry based on the Huygens’s reaction catalyzed by copper (I) was used in this synthesis, the new polymers containing (1,4)-disubstituted triazole are tested for the extraction of Mg and Zn located in wastewater. The structure of new obtained polymers was confirmed by infrared spectroscopy (ATR-FTIR), UV-visible spectroscopy and elemental analysis for nitrogen. Differential Thermal Analysis (DTA) and Thermo Gravimetric Analysis (TGA) were used to study crosslinking behavior of these polymers. This study shows a low selectivity of studied polymers for the retention of magnesium, while for the Zinc, the percentage removal was average, it’s in the order of 30%.

Published in	American Journal of Polymer Science and Technology (Volume 5, Issue 3)
DOI	10.11648/j.ajpst.20190503.11
Page(s)	73-80
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2019. Published by Science Publishing Group

Keywords

Polystyrene Merrifield, (1,4)-Triazoles, Extraction, Zinc and Magnesium in Wastewater

References

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APA Style

Abid Ouerghui, Mokhtar Dardouri, Hichem Elamari, Faycel Ammari, Christian Girard. (2019). Chemical Modification of Polystyrene Merrifield: Extraction of Zinc and Magnesium Located in Wastewater. American Journal of Polymer Science and Technology, 5(3), 73-80. https://doi.org/10.11648/j.ajpst.20190503.11

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ACS Style

Abid Ouerghui; Mokhtar Dardouri; Hichem Elamari; Faycel Ammari; Christian Girard. Chemical Modification of Polystyrene Merrifield: Extraction of Zinc and Magnesium Located in Wastewater. Am. J. Polym. Sci. Technol. 2019, 5(3), 73-80. doi: 10.11648/j.ajpst.20190503.11

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AMA Style

Abid Ouerghui, Mokhtar Dardouri, Hichem Elamari, Faycel Ammari, Christian Girard. Chemical Modification of Polystyrene Merrifield: Extraction of Zinc and Magnesium Located in Wastewater. Am J Polym Sci Technol. 2019;5(3):73-80. doi: 10.11648/j.ajpst.20190503.11

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@article{10.11648/j.ajpst.20190503.11,
  author = {Abid Ouerghui and Mokhtar Dardouri and Hichem Elamari and Faycel Ammari and Christian Girard},
  title = {Chemical Modification of Polystyrene Merrifield: Extraction of Zinc and Magnesium Located in Wastewater},
  journal = {American Journal of Polymer Science and Technology},
  volume = {5},
  number = {3},
  pages = {73-80},
  doi = {10.11648/j.ajpst.20190503.11},
  url = {https://doi.org/10.11648/j.ajpst.20190503.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpst.20190503.11},
  abstract = {In order to remove metals (Zn & Mg) located in wastewater, a new series of clickable polystyrene Merrifield grafted with azide and alkynes were synthesized and implicated in this domain. In a first step, we transformed the polystyrene Merrifield into the known Azidomethyl polystyrene, in a second step, a coupling reaction between the Azidomethyl polystyrene and dipropargylamine was realized for the synthesis of a new terminated polystyrene alkyne containing one unit of (1,4)-triazole. To increase the length of the chain grafted on the polystyrene Merrifield, several coupling reactions are applied, the main idea of this work was to increase the number of (1,2,3) –triazole units of this grafted chain. The click chemistry based on the Huygens’s reaction catalyzed by copper (I) was used in this synthesis, the new polymers containing (1,4)-disubstituted triazole are tested for the extraction of Mg and Zn located in wastewater. The structure of new obtained polymers was confirmed by infrared spectroscopy (ATR-FTIR), UV-visible spectroscopy and elemental analysis for nitrogen. Differential Thermal Analysis (DTA) and Thermo Gravimetric Analysis (TGA) were used to study crosslinking behavior of these polymers. This study shows a low selectivity of studied polymers for the retention of magnesium, while for the Zinc, the percentage removal was average, it’s in the order of 30%.},
 year = {2019}
}

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TY  - JOUR
T1  - Chemical Modification of Polystyrene Merrifield: Extraction of Zinc and Magnesium Located in Wastewater
AU  - Abid Ouerghui
AU  - Mokhtar Dardouri
AU  - Hichem Elamari
AU  - Faycel Ammari
AU  - Christian Girard
Y1  - 2019/08/06
PY  - 2019
N1  - https://doi.org/10.11648/j.ajpst.20190503.11
DO  - 10.11648/j.ajpst.20190503.11
T2  - American Journal of Polymer Science and Technology
JF  - American Journal of Polymer Science and Technology
JO  - American Journal of Polymer Science and Technology
SP  - 73
EP  - 80
PB  - Science Publishing Group
SN  - 2575-5986
UR  - https://doi.org/10.11648/j.ajpst.20190503.11
AB  - In order to remove metals (Zn & Mg) located in wastewater, a new series of clickable polystyrene Merrifield grafted with azide and alkynes were synthesized and implicated in this domain. In a first step, we transformed the polystyrene Merrifield into the known Azidomethyl polystyrene, in a second step, a coupling reaction between the Azidomethyl polystyrene and dipropargylamine was realized for the synthesis of a new terminated polystyrene alkyne containing one unit of (1,4)-triazole. To increase the length of the chain grafted on the polystyrene Merrifield, several coupling reactions are applied, the main idea of this work was to increase the number of (1,2,3) –triazole units of this grafted chain. The click chemistry based on the Huygens’s reaction catalyzed by copper (I) was used in this synthesis, the new polymers containing (1,4)-disubstituted triazole are tested for the extraction of Mg and Zn located in wastewater. The structure of new obtained polymers was confirmed by infrared spectroscopy (ATR-FTIR), UV-visible spectroscopy and elemental analysis for nitrogen. Differential Thermal Analysis (DTA) and Thermo Gravimetric Analysis (TGA) were used to study crosslinking behavior of these polymers. This study shows a low selectivity of studied polymers for the retention of magnesium, while for the Zinc, the percentage removal was average, it’s in the order of 30%.
VL  - 5
IS  - 3
ER  -

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Author Information

Abid Ouerghui

Department of Chemistry, National Graduate School of Chemistry, Paris Sciences & Letters - PSL University, Paris, France
Mokhtar Dardouri

Departement of Chemistry, Faculty of Sciences of Bizerte, University of Carthage, Bizerte, Tunisia
Hichem Elamari

Departement of Chemistry, Faculty of Sciences of Bizerte, University of Carthage, Bizerte, Tunisia
Faycel Ammari

Departement of Chemistry, Faculty of Sciences of Bizerte, University of Carthage, Bizerte, Tunisia
Christian Girard

Department of Chemistry, National Graduate School of Chemistry, Paris Sciences & Letters - PSL University, Paris, France

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APA Style

Abid Ouerghui, Mokhtar Dardouri, Hichem Elamari, Faycel Ammari, Christian Girard. (2019). Chemical Modification of Polystyrene Merrifield: Extraction of Zinc and Magnesium Located in Wastewater. American Journal of Polymer Science and Technology, 5(3), 73-80. https://doi.org/10.11648/j.ajpst.20190503.11

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ACS Style

Abid Ouerghui; Mokhtar Dardouri; Hichem Elamari; Faycel Ammari; Christian Girard. Chemical Modification of Polystyrene Merrifield: Extraction of Zinc and Magnesium Located in Wastewater. Am. J. Polym. Sci. Technol. 2019, 5(3), 73-80. doi: 10.11648/j.ajpst.20190503.11

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AMA Style

Abid Ouerghui, Mokhtar Dardouri, Hichem Elamari, Faycel Ammari, Christian Girard. Chemical Modification of Polystyrene Merrifield: Extraction of Zinc and Magnesium Located in Wastewater. Am J Polym Sci Technol. 2019;5(3):73-80. doi: 10.11648/j.ajpst.20190503.11

Copy | Download

@article{10.11648/j.ajpst.20190503.11,
  author = {Abid Ouerghui and Mokhtar Dardouri and Hichem Elamari and Faycel Ammari and Christian Girard},
  title = {Chemical Modification of Polystyrene Merrifield: Extraction of Zinc and Magnesium Located in Wastewater},
  journal = {American Journal of Polymer Science and Technology},
  volume = {5},
  number = {3},
  pages = {73-80},
  doi = {10.11648/j.ajpst.20190503.11},
  url = {https://doi.org/10.11648/j.ajpst.20190503.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpst.20190503.11},
  abstract = {In order to remove metals (Zn & Mg) located in wastewater, a new series of clickable polystyrene Merrifield grafted with azide and alkynes were synthesized and implicated in this domain. In a first step, we transformed the polystyrene Merrifield into the known Azidomethyl polystyrene, in a second step, a coupling reaction between the Azidomethyl polystyrene and dipropargylamine was realized for the synthesis of a new terminated polystyrene alkyne containing one unit of (1,4)-triazole. To increase the length of the chain grafted on the polystyrene Merrifield, several coupling reactions are applied, the main idea of this work was to increase the number of (1,2,3) –triazole units of this grafted chain. The click chemistry based on the Huygens’s reaction catalyzed by copper (I) was used in this synthesis, the new polymers containing (1,4)-disubstituted triazole are tested for the extraction of Mg and Zn located in wastewater. The structure of new obtained polymers was confirmed by infrared spectroscopy (ATR-FTIR), UV-visible spectroscopy and elemental analysis for nitrogen. Differential Thermal Analysis (DTA) and Thermo Gravimetric Analysis (TGA) were used to study crosslinking behavior of these polymers. This study shows a low selectivity of studied polymers for the retention of magnesium, while for the Zinc, the percentage removal was average, it’s in the order of 30%.},
 year = {2019}
}

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TY  - JOUR
T1  - Chemical Modification of Polystyrene Merrifield: Extraction of Zinc and Magnesium Located in Wastewater
AU  - Abid Ouerghui
AU  - Mokhtar Dardouri
AU  - Hichem Elamari
AU  - Faycel Ammari
AU  - Christian Girard
Y1  - 2019/08/06
PY  - 2019
N1  - https://doi.org/10.11648/j.ajpst.20190503.11
DO  - 10.11648/j.ajpst.20190503.11
T2  - American Journal of Polymer Science and Technology
JF  - American Journal of Polymer Science and Technology
JO  - American Journal of Polymer Science and Technology
SP  - 73
EP  - 80
PB  - Science Publishing Group
SN  - 2575-5986
UR  - https://doi.org/10.11648/j.ajpst.20190503.11
AB  - In order to remove metals (Zn & Mg) located in wastewater, a new series of clickable polystyrene Merrifield grafted with azide and alkynes were synthesized and implicated in this domain. In a first step, we transformed the polystyrene Merrifield into the known Azidomethyl polystyrene, in a second step, a coupling reaction between the Azidomethyl polystyrene and dipropargylamine was realized for the synthesis of a new terminated polystyrene alkyne containing one unit of (1,4)-triazole. To increase the length of the chain grafted on the polystyrene Merrifield, several coupling reactions are applied, the main idea of this work was to increase the number of (1,2,3) –triazole units of this grafted chain. The click chemistry based on the Huygens’s reaction catalyzed by copper (I) was used in this synthesis, the new polymers containing (1,4)-disubstituted triazole are tested for the extraction of Mg and Zn located in wastewater. The structure of new obtained polymers was confirmed by infrared spectroscopy (ATR-FTIR), UV-visible spectroscopy and elemental analysis for nitrogen. Differential Thermal Analysis (DTA) and Thermo Gravimetric Analysis (TGA) were used to study crosslinking behavior of these polymers. This study shows a low selectivity of studied polymers for the retention of magnesium, while for the Zinc, the percentage removal was average, it’s in the order of 30%.
VL  - 5
IS  - 3
ER  -

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