Pine Wood Powder Treatment to BXH+ Homogeneous Catalyst (H+/H2SO4) Supported on Its Aromatics’ and PNA’ Alkenes – Application in Black Citric Acid Polymer Synthesis

Andry Tahina Rabeharitsara; Behevitra Rovatahianjanahary; Nambinina Richard Randriana

doi:doi:10.11648/j.ajpst.20180401.11

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Pine Wood Powder Treatment to B_XH⁺ Homogeneous Catalyst (H⁺/H₂SO₄) Supported on Its Aromatics’ and PNA’ Alkenes – Application in Black Citric Acid Polymer Synthesis

Andry Tahina Rabeharitsara, Behevitra Rovatahianjanahary, Nambinina Richard Randriana

Published in American Journal of Polymer Science and Technology (Volume 4, Issue 1)

Received: 9 March 2018 Accepted: 27 March 2018 Published: 4 May 2018

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Abstract

For a long time, many chemical reactions drew on catalysts, products used in smallest quantities compared to products-reagents, to accelerate their kinetics. In certain cases, one of the determining factors to improve these catalysts activities is the use of supports allowing dispersions and thereafter the effectiveness of its active sites.. It is the goal of our study, to increase the pine wood powders value like support of active acid H+ sites of sulphuric acid molecules by hydrogen bond connection with alkenes of aromatics and polynuclear aromatics which were pine wood components and their derivatives obtained after sulphuric acid solution (98%) treatment. Among these derivatives we quote water molecules formed during dehydration and esterification of wood components. Thus, we obtained homogeneous catalysts B_XH⁺, (H⁺/H₂SO₄) supported on pine wood powder which we tested by a test reaction: citric acid dehydration to prop-1-ene 1, 2, 3 acid- tricarboxylic acid. Also, the active acid sites (H⁺/H₂SO₄) contents and alkenes on BXH+ catalysts were quantified by measuring out respectively with NaOH 0.05N and hydrofluoric acid (HF). This last measuring out enabled us to evaluate the nature of the aromatics and polynuclear aromatics which were the real supports contained in pine wood. At the end, we used these B_XH⁺ synthesized catalysts to catalyze the citric acid black polymer synthesis (PN). The soluble coke and insoluble coke in polar solvent dichloromethane and non-polar solvent hexane of citric acid black polymer synthesized by each catalyst were quantified.

Published in	American Journal of Polymer Science and Technology (Volume 4, Issue 1)
DOI	10.11648/j.ajpst.20180401.11
Page(s)	1-27
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2018. Published by Science Publishing Group

Keywords

Supported Homogeneous Catalyst, Sulphuric Acid, Pine Wood, Alkene, Aromatics, PNA, Citric Acid Polymers, Coke

References

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APA Style

Andry Tahina Rabeharitsara, Behevitra Rovatahianjanahary, Nambinina Richard Randriana. (2018). Pine Wood Powder Treatment to BXH+ Homogeneous Catalyst (H+/H2SO4) Supported on Its Aromatics’ and PNA’ Alkenes – Application in Black Citric Acid Polymer Synthesis. American Journal of Polymer Science and Technology, 4(1), 1-27. https://doi.org/10.11648/j.ajpst.20180401.11

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ACS Style

Andry Tahina Rabeharitsara; Behevitra Rovatahianjanahary; Nambinina Richard Randriana. Pine Wood Powder Treatment to BXH+ Homogeneous Catalyst (H+/H2SO4) Supported on Its Aromatics’ and PNA’ Alkenes – Application in Black Citric Acid Polymer Synthesis. Am. J. Polym. Sci. Technol. 2018, 4(1), 1-27. doi: 10.11648/j.ajpst.20180401.11

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AMA Style

Andry Tahina Rabeharitsara, Behevitra Rovatahianjanahary, Nambinina Richard Randriana. Pine Wood Powder Treatment to BXH+ Homogeneous Catalyst (H+/H2SO4) Supported on Its Aromatics’ and PNA’ Alkenes – Application in Black Citric Acid Polymer Synthesis. Am J Polym Sci Technol. 2018;4(1):1-27. doi: 10.11648/j.ajpst.20180401.11

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@article{10.11648/j.ajpst.20180401.11,
  author = {Andry Tahina Rabeharitsara and Behevitra Rovatahianjanahary and Nambinina Richard Randriana},
  title = {Pine Wood Powder Treatment to BXH+ Homogeneous Catalyst (H+/H2SO4) Supported on Its Aromatics’ and PNA’ Alkenes – Application in Black Citric Acid Polymer Synthesis},
  journal = {American Journal of Polymer Science and Technology},
  volume = {4},
  number = {1},
  pages = {1-27},
  doi = {10.11648/j.ajpst.20180401.11},
  url = {https://doi.org/10.11648/j.ajpst.20180401.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpst.20180401.11},
  abstract = {For a long time, many chemical reactions drew on catalysts, products used in smallest quantities compared to products-reagents, to accelerate their kinetics. In certain cases, one of the determining factors to improve these catalysts activities is the use of supports allowing dispersions and thereafter the effectiveness of its active sites.. It is the goal of our study, to increase the pine wood powders value like support of active acid H+ sites of sulphuric acid molecules by hydrogen bond connection with alkenes of aromatics and polynuclear aromatics which were pine wood components and their derivatives obtained after sulphuric acid solution (98%) treatment. Among these derivatives we quote water molecules formed during dehydration and esterification of wood components. Thus, we obtained homogeneous catalysts BXH+, (H+/H2SO4) supported on pine wood powder which we tested by a test reaction: citric acid dehydration to prop-1-ene 1, 2, 3 acid- tricarboxylic acid. Also, the active acid sites (H+/H2SO4) contents and alkenes on BXH+ catalysts were quantified by measuring out respectively with NaOH 0.05N and hydrofluoric acid (HF). This last measuring out enabled us to evaluate the nature of the aromatics and polynuclear aromatics which were the real supports contained in pine wood. At the end, we used these BXH+ synthesized catalysts to catalyze the citric acid black polymer synthesis (PN). The soluble coke and insoluble coke in polar solvent dichloromethane and non-polar solvent hexane of citric acid black polymer synthesized by each catalyst were quantified.},
 year = {2018}
}

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TY  - JOUR
T1  - Pine Wood Powder Treatment to BXH+ Homogeneous Catalyst (H+/H2SO4) Supported on Its Aromatics’ and PNA’ Alkenes – Application in Black Citric Acid Polymer Synthesis
AU  - Andry Tahina Rabeharitsara
AU  - Behevitra Rovatahianjanahary
AU  - Nambinina Richard Randriana
Y1  - 2018/05/04
PY  - 2018
N1  - https://doi.org/10.11648/j.ajpst.20180401.11
DO  - 10.11648/j.ajpst.20180401.11
T2  - American Journal of Polymer Science and Technology
JF  - American Journal of Polymer Science and Technology
JO  - American Journal of Polymer Science and Technology
SP  - 1
EP  - 27
PB  - Science Publishing Group
SN  - 2575-5986
UR  - https://doi.org/10.11648/j.ajpst.20180401.11
AB  - For a long time, many chemical reactions drew on catalysts, products used in smallest quantities compared to products-reagents, to accelerate their kinetics. In certain cases, one of the determining factors to improve these catalysts activities is the use of supports allowing dispersions and thereafter the effectiveness of its active sites.. It is the goal of our study, to increase the pine wood powders value like support of active acid H+ sites of sulphuric acid molecules by hydrogen bond connection with alkenes of aromatics and polynuclear aromatics which were pine wood components and their derivatives obtained after sulphuric acid solution (98%) treatment. Among these derivatives we quote water molecules formed during dehydration and esterification of wood components. Thus, we obtained homogeneous catalysts BXH+, (H+/H2SO4) supported on pine wood powder which we tested by a test reaction: citric acid dehydration to prop-1-ene 1, 2, 3 acid- tricarboxylic acid. Also, the active acid sites (H+/H2SO4) contents and alkenes on BXH+ catalysts were quantified by measuring out respectively with NaOH 0.05N and hydrofluoric acid (HF). This last measuring out enabled us to evaluate the nature of the aromatics and polynuclear aromatics which were the real supports contained in pine wood. At the end, we used these BXH+ synthesized catalysts to catalyze the citric acid black polymer synthesis (PN). The soluble coke and insoluble coke in polar solvent dichloromethane and non-polar solvent hexane of citric acid black polymer synthesized by each catalyst were quantified.
VL  - 4
IS  - 1
ER  -

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Author Information

Andry Tahina Rabeharitsara

Chemical Process Engineering Department (E.S.P.A), Antananarivo University, Antananarivo, Madagascar
Behevitra Rovatahianjanahary

Chemical Process Engineering Department (E.S.P.A), Antananarivo University, Antananarivo, Madagascar
Nambinina Richard Randriana

Chemical Process Engineering Department (E.S.P.A), Antananarivo University, Antananarivo, Madagascar

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Plain Text BibTeX RIS

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Andry Tahina Rabeharitsara, Behevitra Rovatahianjanahary, Nambinina Richard Randriana. (2018). Pine Wood Powder Treatment to BXH+ Homogeneous Catalyst (H+/H2SO4) Supported on Its Aromatics’ and PNA’ Alkenes – Application in Black Citric Acid Polymer Synthesis. American Journal of Polymer Science and Technology, 4(1), 1-27. https://doi.org/10.11648/j.ajpst.20180401.11

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ACS Style

Andry Tahina Rabeharitsara; Behevitra Rovatahianjanahary; Nambinina Richard Randriana. Pine Wood Powder Treatment to BXH+ Homogeneous Catalyst (H+/H2SO4) Supported on Its Aromatics’ and PNA’ Alkenes – Application in Black Citric Acid Polymer Synthesis. Am. J. Polym. Sci. Technol. 2018, 4(1), 1-27. doi: 10.11648/j.ajpst.20180401.11

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AMA Style

Andry Tahina Rabeharitsara, Behevitra Rovatahianjanahary, Nambinina Richard Randriana. Pine Wood Powder Treatment to BXH+ Homogeneous Catalyst (H+/H2SO4) Supported on Its Aromatics’ and PNA’ Alkenes – Application in Black Citric Acid Polymer Synthesis. Am J Polym Sci Technol. 2018;4(1):1-27. doi: 10.11648/j.ajpst.20180401.11

Copy | Download

@article{10.11648/j.ajpst.20180401.11,
  author = {Andry Tahina Rabeharitsara and Behevitra Rovatahianjanahary and Nambinina Richard Randriana},
  title = {Pine Wood Powder Treatment to BXH+ Homogeneous Catalyst (H+/H2SO4) Supported on Its Aromatics’ and PNA’ Alkenes – Application in Black Citric Acid Polymer Synthesis},
  journal = {American Journal of Polymer Science and Technology},
  volume = {4},
  number = {1},
  pages = {1-27},
  doi = {10.11648/j.ajpst.20180401.11},
  url = {https://doi.org/10.11648/j.ajpst.20180401.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpst.20180401.11},
  abstract = {For a long time, many chemical reactions drew on catalysts, products used in smallest quantities compared to products-reagents, to accelerate their kinetics. In certain cases, one of the determining factors to improve these catalysts activities is the use of supports allowing dispersions and thereafter the effectiveness of its active sites.. It is the goal of our study, to increase the pine wood powders value like support of active acid H+ sites of sulphuric acid molecules by hydrogen bond connection with alkenes of aromatics and polynuclear aromatics which were pine wood components and their derivatives obtained after sulphuric acid solution (98%) treatment. Among these derivatives we quote water molecules formed during dehydration and esterification of wood components. Thus, we obtained homogeneous catalysts BXH+, (H+/H2SO4) supported on pine wood powder which we tested by a test reaction: citric acid dehydration to prop-1-ene 1, 2, 3 acid- tricarboxylic acid. Also, the active acid sites (H+/H2SO4) contents and alkenes on BXH+ catalysts were quantified by measuring out respectively with NaOH 0.05N and hydrofluoric acid (HF). This last measuring out enabled us to evaluate the nature of the aromatics and polynuclear aromatics which were the real supports contained in pine wood. At the end, we used these BXH+ synthesized catalysts to catalyze the citric acid black polymer synthesis (PN). The soluble coke and insoluble coke in polar solvent dichloromethane and non-polar solvent hexane of citric acid black polymer synthesized by each catalyst were quantified.},
 year = {2018}
}

Copy | Download

TY  - JOUR
T1  - Pine Wood Powder Treatment to BXH+ Homogeneous Catalyst (H+/H2SO4) Supported on Its Aromatics’ and PNA’ Alkenes – Application in Black Citric Acid Polymer Synthesis
AU  - Andry Tahina Rabeharitsara
AU  - Behevitra Rovatahianjanahary
AU  - Nambinina Richard Randriana
Y1  - 2018/05/04
PY  - 2018
N1  - https://doi.org/10.11648/j.ajpst.20180401.11
DO  - 10.11648/j.ajpst.20180401.11
T2  - American Journal of Polymer Science and Technology
JF  - American Journal of Polymer Science and Technology
JO  - American Journal of Polymer Science and Technology
SP  - 1
EP  - 27
PB  - Science Publishing Group
SN  - 2575-5986
UR  - https://doi.org/10.11648/j.ajpst.20180401.11
AB  - For a long time, many chemical reactions drew on catalysts, products used in smallest quantities compared to products-reagents, to accelerate their kinetics. In certain cases, one of the determining factors to improve these catalysts activities is the use of supports allowing dispersions and thereafter the effectiveness of its active sites.. It is the goal of our study, to increase the pine wood powders value like support of active acid H+ sites of sulphuric acid molecules by hydrogen bond connection with alkenes of aromatics and polynuclear aromatics which were pine wood components and their derivatives obtained after sulphuric acid solution (98%) treatment. Among these derivatives we quote water molecules formed during dehydration and esterification of wood components. Thus, we obtained homogeneous catalysts BXH+, (H+/H2SO4) supported on pine wood powder which we tested by a test reaction: citric acid dehydration to prop-1-ene 1, 2, 3 acid- tricarboxylic acid. Also, the active acid sites (H+/H2SO4) contents and alkenes on BXH+ catalysts were quantified by measuring out respectively with NaOH 0.05N and hydrofluoric acid (HF). This last measuring out enabled us to evaluate the nature of the aromatics and polynuclear aromatics which were the real supports contained in pine wood. At the end, we used these BXH+ synthesized catalysts to catalyze the citric acid black polymer synthesis (PN). The soluble coke and insoluble coke in polar solvent dichloromethane and non-polar solvent hexane of citric acid black polymer synthesized by each catalyst were quantified.
VL  - 4
IS  - 1
ER  -

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