Different Pyrazoline derivatives were synthesized by cyclization of substituted chalcone derivatives in presence of hydrazine hydrate. A series of novel 1,3,5-triaryl pyrazoline derivatives has been synthesized by the reaction of chalcone and phenylhydrazine in the presence of Silica-supported Preyssler Nanoparticles, H14[NaP5W30O110]/SiO2, Preyssler H14[NaP5W30O110] and Keggin heteropolyacids, H3PW12O40, H7[PMo8V4O40], H6[PMo9V3O40], H5[PMo10V2O40], H4[PMo11VO40], H3[PMo12O40] as catalyst under aqueous conditions is described. The best conditions were observed using Preyssler and Silica-supported Preyssler Nanoparticles as catalysts. The catalyst is recyclable and reusable. The structures of compounds obtained were determined by IR and 1H NMR spectra.
| Published in | American Journal of Heterocyclic Chemistry (Volume 1, Issue 1) |
| DOI | 10.11648/j.ajhc.20150101.12 |
| Page(s) | 6-12 |
| Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
| Copyright |
Copyright © The Author(s), 2015. Published by Science Publishing Group |
Pyrazoline, Nanoparticles, Preyssler, Heteropolyacids, Catalyst, Synthesis
| [1] | R. H. Wiley, Ed.; “Pyrazoles, Pyrazolines, Pyrazolidines, Indazoles and Condensed Rings; in the Chemistry of Heterocyclic Compounds;” Weissberger A, Ed.; Interscience Publishers: New York, 1967; Vol. 22, p 180. |
| [2] | K. Suresh, B. Sandhya, D. Sushma., Recent Patents Anti-Infect Drug Discov. 2009, 4, 154. |
| [3] | Z. A. Kaplancıklı, G. Turan-Zitouni, A. Özdemir, Phosphorus Sulfur Silicon Relat Elem. 2007, 182, 749. |
| [4] | A. Özdemir, G. Turan-Zitouni, Z. A. Kaplancıklı, European Journal Med Chem. 2007, 42, 403. |
| [5] | A. Özdemir, G. Turan-Zitouni, Z. A. Kaplancıklı, Journal Enzym Inhib Med Chem. 2010, 25, 565. |
| [6] | G. Turan-Zitouni, A. Özdemir and K. Güven, Arch Pharm Pharm Med Chem. 2005, 338, 96. |
| [7] | G. Turan-Zitouni, A. Özdemir and Z. A. Kaplancıklı, Phosphorus Sulfur Silicon Relat Elem. 2005, 180, 2717. |
| [8] | B. A. Bhat, K. L. Dhar, S. C. Puri et al., Bioorg Med Chem Lett. 2005, 15, 3177. |
| [9] | R. Chawla, U. Sahoo, A. Arora et al., Acta Pol Pharma Drug Res. 2010, 67, 51. |
| [10] | R. Gupta, N. Gupta and A. Jain, Indian Journal Chem. 2010, 49B, 3, 351. |
| [11] | A. Solankee, S. Lad, S. Solankee et al., Indian Journal Chem. 2009, 48B, 10, 1442. |
| [12] | B. C. Revanasiddappa, R. Nagendr Rao, E . V. S. Subramaniyam, E-J Chem. 2010, 7, 295. |
| [13] | A. Voskiene, V. Mickevicius and G. Mikulskiene, ARKIVOC. 2007, XV, 303 . |
| [14] | S. Kataade, U. Phalgune, S. Biswas, et al., Indian Journal Chem. 2008, 47B, 6, 927. |
| [15] | S. A. Al-Issa, N. A. L. Andis, Journal Saudi Chem Soc. 2005, 9, 687. |
| [16] | A. Levai, J. Jeko, ARKIVOC. 2007, I, 134. |
| [17] | D. G. Powers, D. S. Casebier, D. Fokas, Tetrahedron. 1998, 54, 4085. |
| [18] | K. Kidwar, S. Kukreja and R. Thakur, Lett Org Chem. 2006, 3, 135. |
| [19] | S. Wang, Z. Wang and Z. Zha, Dalton Trans. 2009, 9363. |
| [20] | M. M. Heravi, S. Sajadi, H.A. Oskooie, R. H. Shoar and F. F. Bamoharram, Catal. Commun. 2008, 9, 470. |
| [21] | H. Firouzabadi and A. A. Jafari, J. Iranian Chem. Soc. 2005, 2, 85. |
| [22] | M. M. Heravi, R. Motamedi, N. Seifi and F. F. Bamoharram, J. Mol. Catal., 2006, 249, 1. |
| [23] | C. R. Gorla, N. W. Emanetoglu, S. Liang,W. E. Mago, Y. Lu, M. Wraback and H. Shen, J. Appl. Phys. 1999, 85, 2595. |
| [24] | J. Zhang and R. M. J. Dickson, Phys.Rev. Lett. 2004, 93, 077402. |
| [25] | M. H. Alizadeh, S. P. Harmalker, Y. Jeannin, J. Martin-Frere, M. T. Pope, J. Am. Chem. Soc. 1985, 107, 2662. |
| [26] | F. F. Bamoharram, M. M. Heravi, M. Roshani, M. Jahangir and A. Gharib, Appl. Catal. 2006, 302, 42. |
| [27] | I. V. Kozhevnikov, Chem. Rev. 1998, 98, 171. |
| [28] | F. F. Bamoharram, M. M. Heravi, M. Roshani, A. Gharib, M. Jahangir, J. Mol. Catal. A: Chem. 2006, 252, 90. |
| [29] | G. A. Tsigdinos, C. Hallada, J. Inorg. Chem. 1968, 7, 437. |
| [30] | Y. Mahha, A. Atlamsani, J. C. Blais, M. Tessier, J. M. Brégeault, L. Salles, J. Mol. Catal. A: Chem. 2005, 234, 63. |
| [31] | Y. Ding, Q. Gao, G. Li, H. P. Zhang, J. M. Wang, L. Yan, J. S. Suo, J. Mol. Catal. A: Chem. 2004, 218, 161. |
| [32] | a) M. Misono, Stud. Surf. Sci. Catal. 1993, 75, 69. b) M. Misono, Catal. Rev. Sci. Eng. 1987, 29, 269. |
| [33] | M. Misono, N. Nojiri, Appl. Catal. 1990, 64, 1. |
| [34] | T. Okuhara, N. Mizuno, M. Misono, Adv. Catal. 1996, 41, 113. |
| [35] | I. V. Kozhevnikov, Appl. Catal. A: Gen. 2003, 256, 3. |
| [36] | I. V. Kozhevnikov, K. I. Matveev, Appl. Catal. 1983, 5, 135. |
| [37] | Pope M T, Heteropoly and Isopoly Oxometalates, Springer, Berlin, 1983. |
| [38] | G. T. Baronetti, L. Briand, U. Sedran and H. Thomas, Appl Catal A: Gen. 1998, 172, 265. |
APA Style
Ali Gharib, Nader Noroozi Pesyan, Leila Vojdani Fard, Mina Roshani. (2015). Catalytical Synthesis of Pyrazolines Using Nanoparticles of Preyssler Heteropolyacid Supported on Nano-SiO2, H14[NaP5W30O110]/SiO2: A Green and Reusable Catalyst. American Journal of Heterocyclic Chemistry, 1(1), 6-12. https://doi.org/10.11648/j.ajhc.20150101.12
ACS Style
Ali Gharib; Nader Noroozi Pesyan; Leila Vojdani Fard; Mina Roshani. Catalytical Synthesis of Pyrazolines Using Nanoparticles of Preyssler Heteropolyacid Supported on Nano-SiO2, H14[NaP5W30O110]/SiO2: A Green and Reusable Catalyst. Am. J. Heterocycl. Chem. 2015, 1(1), 6-12. doi: 10.11648/j.ajhc.20150101.12
AMA Style
Ali Gharib, Nader Noroozi Pesyan, Leila Vojdani Fard, Mina Roshani. Catalytical Synthesis of Pyrazolines Using Nanoparticles of Preyssler Heteropolyacid Supported on Nano-SiO2, H14[NaP5W30O110]/SiO2: A Green and Reusable Catalyst. Am J Heterocycl Chem. 2015;1(1):6-12. doi: 10.11648/j.ajhc.20150101.12
@article{10.11648/j.ajhc.20150101.12,
author = {Ali Gharib and Nader Noroozi Pesyan and Leila Vojdani Fard and Mina Roshani},
title = {Catalytical Synthesis of Pyrazolines Using Nanoparticles of Preyssler Heteropolyacid Supported on Nano-SiO2, H14[NaP5W30O110]/SiO2: A Green and Reusable Catalyst},
journal = {American Journal of Heterocyclic Chemistry},
volume = {1},
number = {1},
pages = {6-12},
doi = {10.11648/j.ajhc.20150101.12},
url = {https://doi.org/10.11648/j.ajhc.20150101.12},
eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajhc.20150101.12},
abstract = {Different Pyrazoline derivatives were synthesized by cyclization of substituted chalcone derivatives in presence of hydrazine hydrate. A series of novel 1,3,5-triaryl pyrazoline derivatives has been synthesized by the reaction of chalcone and phenylhydrazine in the presence of Silica-supported Preyssler Nanoparticles, H14[NaP5W30O110]/SiO2, Preyssler H14[NaP5W30O110] and Keggin heteropolyacids, H3PW12O40, H7[PMo8V4O40], H6[PMo9V3O40], H5[PMo10V2O40], H4[PMo11VO40], H3[PMo12O40] as catalyst under aqueous conditions is described. The best conditions were observed using Preyssler and Silica-supported Preyssler Nanoparticles as catalysts. The catalyst is recyclable and reusable. The structures of compounds obtained were determined by IR and 1H NMR spectra.},
year = {2015}
}
TY - JOUR T1 - Catalytical Synthesis of Pyrazolines Using Nanoparticles of Preyssler Heteropolyacid Supported on Nano-SiO2, H14[NaP5W30O110]/SiO2: A Green and Reusable Catalyst AU - Ali Gharib AU - Nader Noroozi Pesyan AU - Leila Vojdani Fard AU - Mina Roshani Y1 - 2015/04/28 PY - 2015 N1 - https://doi.org/10.11648/j.ajhc.20150101.12 DO - 10.11648/j.ajhc.20150101.12 T2 - American Journal of Heterocyclic Chemistry JF - American Journal of Heterocyclic Chemistry JO - American Journal of Heterocyclic Chemistry SP - 6 EP - 12 PB - Science Publishing Group SN - 2575-5722 UR - https://doi.org/10.11648/j.ajhc.20150101.12 AB - Different Pyrazoline derivatives were synthesized by cyclization of substituted chalcone derivatives in presence of hydrazine hydrate. A series of novel 1,3,5-triaryl pyrazoline derivatives has been synthesized by the reaction of chalcone and phenylhydrazine in the presence of Silica-supported Preyssler Nanoparticles, H14[NaP5W30O110]/SiO2, Preyssler H14[NaP5W30O110] and Keggin heteropolyacids, H3PW12O40, H7[PMo8V4O40], H6[PMo9V3O40], H5[PMo10V2O40], H4[PMo11VO40], H3[PMo12O40] as catalyst under aqueous conditions is described. The best conditions were observed using Preyssler and Silica-supported Preyssler Nanoparticles as catalysts. The catalyst is recyclable and reusable. The structures of compounds obtained were determined by IR and 1H NMR spectra. VL - 1 IS - 1 ER -