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Predictions and Magnetic Characterization of M-type Hexaferrites Doped with Two Cations in the Fe3+ Site

Received: 29 September 2019     Accepted: 5 November 2019     Published: 2 December 2019
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Abstract

A theoretical and experimental study of magnetic properties of M-type barium hexaferrites, doped with two cations in the Fe3+ sites: (Co3+, Al3+), (Co2+, Ti4+) and (Co2+, Sn4+) is reported. The theoretical predictions were made using the generalization of a model on the distribution of dopants in the crystallographic sites under study. This approach allows a better interpretation of the kinetics of obtaining the samples from the structural and magnetic characterization. In the reported model, the maximum limit refers to theoretical optimum parameters. With these concepts, were established quantitative relationships between dopant amount per crystallographic site and magnetic properties predicted of these systems. The comparison between the experimental values and the predicted magnitudes showed that, in general, the samples were obtained with parameters obtained close to the theoretical ones for traditional ceramic methods. Such an approach is rarely taken into account in the reported bibliography.

Published in American Journal of Engineering and Technology Management (Volume 4, Issue 6)
DOI 10.11648/j.ajetm.20190406.12
Page(s) 83-90
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2019. Published by Science Publishing Group

Keywords

Sol-Gel Methods, Magnetic Properties, Hexaferrite, Theoretical Predictions, Rietveld Refinement

References
[1] T. Kaur, B. Kaur, B. H. Bhat, S. Kumar and A. K. Srivastava, “Effect of calcination temperature on microstructure, dielectric, magnetic and optical properties of Ba0.7La0.3Fe11.7Co0.3O19 hexaferrites“, Physica B: Condensed Matter 456, (2015) 206–212.
[2] X. Zhang, Y. Zhang, Z. Yue, J. Zhang, “Influences of sintering atmosphere on the magnetic and electrical properties of barium hexaferrites”, AIP Advances 9, 085129 (2019) 1-6.
[3] R. S. Alam, M. Moradi, M. Rostami, H. Nikmanesh, R. Moayedi, Y. Bai, J. Magn. Magn. Mater. 381 (2015) 1–9.
[4] P. A. Mariño, “Estudio de la hexaferrita de bario Tipo-M dopada: predicciones y resultados experimentales”, 2012, La Habana Editorial Universitaria ISBN 978-959-16-1960-0.
[5] H. Nikmanesh, S. Hoghoghifard, B. Hadi-Sichani, “Study of the structural, magnetic, and microwave absorption properties of the simultaneous substitution of several cations in the barium hexaferrite structure”, Journal of Alloys and Compounds 775 (2019) 1101-1108.
[6] P. A Mariño-Castellanos, A. C. Moreno-Borges, G. Orozco-Melgar, J. A. García and E. Govea-Alcaide, “Structural and magnetic study of the Ti4+-doped barium hexaferrite ceramic samples: Theoretical and experimental results”, Physica B: Condensed Matter 406 (2011) 3130–3136.
[7] P. A. Mariño, V. A. Lapshinsky, C. Pupo, J. Matilla, and A. Vega, “Obtaining and Structural Characterization of M-type Hexaferrites Doped with Two Cations in the Fe 3+ Sites” in MEPhI’s Section of the Scientific Session on “Breakthrough directions of scientific research at MEPhI: Development prospects within the Strategic Academic Units”, KnE Engineering, (2018), pages 328–335.
[8] L. Glasser, “Lattice energies of crystals with multiple ions: a generalized Kapustinskii equation”, 1995, Inorg. Chem. 34 4935-4936.
[9] J. Matilla-Arias, E. Govea-Alcaide, P. Mariño-Castellanos, F. Rosales-Saiz “Phenomenological Model for Prediction of Cation Substitution Distribution and Some Physical Properties in Mn3+-Doped Barium Hexaferrite”, J Supercond Nov Magn 31 (2018) 251–256.
[10] B. B. Rath, “Kinetics of nucleation and growth processes”, July 1995, Materials Science and Engineering: B 32 (3) 101-106.
[11] J. Matilla-Arias, E. Govea-Alcaide, P. Mariño-Castellanos, F. Rosales-Saiz, I. F. Machado, K. Montero-Rey, “Effects of Lanthanum on Structural and Magnetic Properties of Sr1−xLa2x/3Fe12O19 Compounds: Theoretical and Experimental Results”, JSupercondNovMagn (2019) 152-158.
[12] S. Asiri, S. Güner, A. D. Korkmaz, Md. Amir, K. M. Batoo, M. A. Almessiere, H. Gungunes, H. Sözeri, A. Baykal, “ Magneto-optical properties of BaCryFe12-yO19 (0.0≤ y≤1.0) hexaferrites”, Journal of Magnetism and Magnetic Materials 451 (2018) 463–472
[13] F. L Wei, H. C. Fang, C. K. Ong, C. S. Wang and Z. Yang, “Magnetic properties of BaFe12-2xZnxZrxO19 particles”, June 2000, J. Appl. Phys. 87 (12) 8636-8639.
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  • APA Style

    Pedro Antonio Mariño-Castellanos, Valery Alexevich Lapshinsky, Carlos Pupo, Arles Vega-García, Eduardo Fernández-Cruz, et al. (2019). Predictions and Magnetic Characterization of M-type Hexaferrites Doped with Two Cations in the Fe3+ Site. American Journal of Engineering and Technology Management, 4(6), 83-90. https://doi.org/10.11648/j.ajetm.20190406.12

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    ACS Style

    Pedro Antonio Mariño-Castellanos; Valery Alexevich Lapshinsky; Carlos Pupo; Arles Vega-García; Eduardo Fernández-Cruz, et al. Predictions and Magnetic Characterization of M-type Hexaferrites Doped with Two Cations in the Fe3+ Site. Am. J. Eng. Technol. Manag. 2019, 4(6), 83-90. doi: 10.11648/j.ajetm.20190406.12

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    AMA Style

    Pedro Antonio Mariño-Castellanos, Valery Alexevich Lapshinsky, Carlos Pupo, Arles Vega-García, Eduardo Fernández-Cruz, et al. Predictions and Magnetic Characterization of M-type Hexaferrites Doped with Two Cations in the Fe3+ Site. Am J Eng Technol Manag. 2019;4(6):83-90. doi: 10.11648/j.ajetm.20190406.12

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  • @article{10.11648/j.ajetm.20190406.12,
      author = {Pedro Antonio Mariño-Castellanos and Valery Alexevich Lapshinsky and Carlos Pupo and Arles Vega-García and Eduardo Fernández-Cruz and Braddy Ivan Jimenez-Morales},
      title = {Predictions and Magnetic Characterization of M-type Hexaferrites Doped with Two Cations in the Fe3+ Site},
      journal = {American Journal of Engineering and Technology Management},
      volume = {4},
      number = {6},
      pages = {83-90},
      doi = {10.11648/j.ajetm.20190406.12},
      url = {https://doi.org/10.11648/j.ajetm.20190406.12},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajetm.20190406.12},
      abstract = {A theoretical and experimental study of magnetic properties of M-type barium hexaferrites, doped with two cations in the Fe3+ sites: (Co3+, Al3+), (Co2+, Ti4+) and (Co2+, Sn4+) is reported. The theoretical predictions were made using the generalization of a model on the distribution of dopants in the crystallographic sites under study. This approach allows a better interpretation of the kinetics of obtaining the samples from the structural and magnetic characterization. In the reported model, the maximum limit refers to theoretical optimum parameters. With these concepts, were established quantitative relationships between dopant amount per crystallographic site and magnetic properties predicted of these systems. The comparison between the experimental values and the predicted magnitudes showed that, in general, the samples were obtained with parameters obtained close to the theoretical ones for traditional ceramic methods. Such an approach is rarely taken into account in the reported bibliography.},
     year = {2019}
    }
    

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    T1  - Predictions and Magnetic Characterization of M-type Hexaferrites Doped with Two Cations in the Fe3+ Site
    AU  - Pedro Antonio Mariño-Castellanos
    AU  - Valery Alexevich Lapshinsky
    AU  - Carlos Pupo
    AU  - Arles Vega-García
    AU  - Eduardo Fernández-Cruz
    AU  - Braddy Ivan Jimenez-Morales
    Y1  - 2019/12/02
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    N1  - https://doi.org/10.11648/j.ajetm.20190406.12
    DO  - 10.11648/j.ajetm.20190406.12
    T2  - American Journal of Engineering and Technology Management
    JF  - American Journal of Engineering and Technology Management
    JO  - American Journal of Engineering and Technology Management
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    EP  - 90
    PB  - Science Publishing Group
    SN  - 2575-1441
    UR  - https://doi.org/10.11648/j.ajetm.20190406.12
    AB  - A theoretical and experimental study of magnetic properties of M-type barium hexaferrites, doped with two cations in the Fe3+ sites: (Co3+, Al3+), (Co2+, Ti4+) and (Co2+, Sn4+) is reported. The theoretical predictions were made using the generalization of a model on the distribution of dopants in the crystallographic sites under study. This approach allows a better interpretation of the kinetics of obtaining the samples from the structural and magnetic characterization. In the reported model, the maximum limit refers to theoretical optimum parameters. With these concepts, were established quantitative relationships between dopant amount per crystallographic site and magnetic properties predicted of these systems. The comparison between the experimental values and the predicted magnitudes showed that, in general, the samples were obtained with parameters obtained close to the theoretical ones for traditional ceramic methods. Such an approach is rarely taken into account in the reported bibliography.
    VL  - 4
    IS  - 6
    ER  - 

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Author Information
  • Peoples Friendship University of Russia, Moscow, Russian Federation

  • University of Holguin, Holguin, Cuba

  • University of Holguin, Holguin, Cuba

  • Department of Physics, University of Camagüey, Camagüey, Cuba

  • Physics Institute, Kazan Federal University, Kazan, Russian Federation

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