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Investigation of Polysulfone Based Aluminium Oxide Coated Membrane for Separation of Crude Oil Emulsion in the Niger Delta

Received: 1 October 2020     Accepted: 19 October 2020     Published: 16 December 2020
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Abstract

There is need for efficient separation of crude oil from its emulsion in oil and gas processes especially during production and refining activities. Among other methods used for crude oil emulsion demulsification, polymer membranes have attracted a lot of attention. The increasing interest in polymer membranes usage for ultrafiltration and micro filtration are mainly due to their versatility, efficiency and reduced operating cost when compared with conventional techniques such as use of chemical, flocculation etc. This paper illustrates experimental process for the separation of crude oil emulsion using Polysulfone membrane material coated with Aluminium oxide nanoparticle. The crude oil emulsion was prepared by mixing with distil water to obtain an oil in water emulsion. Because of the oleophilicity of Polysulfone membrane materials in oil/water separation, aluminum nanoparticles were used as metallic coatings to their Polysulfone membrane to improve efficiency and anti-fouling characteristics. Three parametres were investigated in the results, these include the separation efficiency in terms of oil rejection, the permeation flux, the filtrate volume for pressure application of 80% stroke and 60% stroke. The augmented membrane construction yields 98.5% and 97.6% efficiency in terms of oil rejection for a pressure application of 60% stroke and 80% stroke respectively while the permeation fluxes are 0.911 ml/cm2-min and 1.024 ml/cm2-min for 80% stroke and 60% stroke pressure application respectively.

Published in American Journal of Energy Engineering (Volume 8, Issue 4)
DOI 10.11648/j.ajee.20200804.11
Page(s) 34-39
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2020. Published by Science Publishing Group

Keywords

Polysulfone, Aluminium Oxide, Emulsion, Membrane, Nanoparticles

References
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[2] Tiron, L. G., Pintilie, S. C, Vlad, M., Birsan, I. G., and Baltă, S. (2017). Characterization of Polysulfone Membranes Prepared with Thermally Induced Phase Separation Technique. International Conference on Innovative Research, IOP Conf. Series: Materials Science and Engineering 209
[3] Zhu Yuzhang, Wang Dong, Jiang Lei, and Jin Jian. (2014). Recent progress in developing advanced membranes for emulsified oil/water separation. NPG Asia Materials. Nature publishing group. Vol 6.
[4] Mohammadian, E.; Taju Ariffin, T. S.; Azdarpour, A.; Hamidi, H.; Yusof, S.; Sabet, M.; Yahya, E. (2018). Demulsification of Light Malaysian Crude Oil Emulsions Using an Electric Field Method. Ind. Eng. Chem. Res., 57, 13247–13256.
[5] Shehzad, F.; Hussein, I. A.; Kamal, M. S.; Ahmad, W.; Sultan, A. S.; Nasser, M. S. (2018). Polymeric surfactants and emerging alternatives used in the demulsification of produced water: A review. Polym. Rev., 58, 63–101
[6] Roshan, N.; Ghader, S.; Rahimpour, M. R. (2018). Application of the response surface methodology for modeling demulsification of crude oil emulsion using a demulsifier. J. Dispers. Sci. Technol, 39, 700–710.
[7] Saad, M. A. Kamil, Mohammed Abdurahman, N. H. Yunus, R. M and Awad, O. I. (2019). An Overview of Recent Advances in State-of-the-Art Techniques in the Demulsification of Crude Oil Emulsions. Processes 2019, 7, 470; doi: 10.3390
[8] Saki Seda & Uzal Nigmet (2018). Preparation and characterization of PSF/PEI/CaCO3 nanocomposite membranes for oil/water separation. Environmental Science and Pollution Research. Springer-Verlag GmbH Germany.
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[10] Saththasivam Jayaprakash, Wang Kui, Yiming Wubulikasimu, Liu Zhaoyang and Mahmoud, Khaled, A. (2019) A flexible Ti3C2Tx (MXene)/paper membrane for efficient oil/water separation. RSC Advances, Issue 29,
[11] Yang Y. N., Zhang, H. X., Wang, P., Zheng, Q. Z. & Li, J., (2007) Journal of Membrane Science. 288, 231.
[12] Matsuyama Hideto and Yoshioka Tomohisa (2019). Development of ultrathin durable membrane for efficient oil and water separation. Journal of Material Chemistry.
[13] Liu Zhi, Qin Detao, Zhao Jianghui, Feng Quan, Li Zhengtao, Bai Hongwei, and Sun Darren D. (2019). Efficient Oil/Water Separation Membrane Derived from Super-Flexible and Superhydrophilic Core–Shell Organic/Inorganic Nanofibrous Architectures. Polymers (Basel) vol. 11 (6).
[14] Borisov Ilya, Ovcharova Anna, Bakhtin Danila, Bazhenov Stepan, Volkov Alexey, Ibragimov Rustem, Gallyamov Rustem, Bondarenko Galina, Mozhchil Rais, Bildyukevich Alexandr and Volkov Vladimir (2017). Development of Polysulfone Hollow Fiber Porous Supports for High Flux Composite Membranes: Air Plasma and Piranha Etching
[15] Oh S, Ki S, Ryu S, Shin MC, Lee J, Lee C, Nam Y.(2019). Performance Analysis of Gravity-Driven Oil-Water Separation Using Membranes with Special Wettability. ACS Publications, USA
[16] Yu Qianqian, Wenbo Zhang, Xinyue Zhao, Guoliang Cao, Feng Liu, Xin Di, Haiyue Yang, Yazhou Wang and Chengyu Wang (2018). A Simple, Green Method to Fabricate Composite Membranes for Effective Oil-in-Water Emulsion Separation. Polymers.
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  • APA Style

    Ngozi Claribelle Nwogu, Nkemakolam Chinedu Izuwa, Chioma Deborah Mbakaogu, Stanley Toochukwu Ekwueme. (2020). Investigation of Polysulfone Based Aluminium Oxide Coated Membrane for Separation of Crude Oil Emulsion in the Niger Delta. American Journal of Energy Engineering, 8(4), 34-39. https://doi.org/10.11648/j.ajee.20200804.11

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    ACS Style

    Ngozi Claribelle Nwogu; Nkemakolam Chinedu Izuwa; Chioma Deborah Mbakaogu; Stanley Toochukwu Ekwueme. Investigation of Polysulfone Based Aluminium Oxide Coated Membrane for Separation of Crude Oil Emulsion in the Niger Delta. Am. J. Energy Eng. 2020, 8(4), 34-39. doi: 10.11648/j.ajee.20200804.11

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    AMA Style

    Ngozi Claribelle Nwogu, Nkemakolam Chinedu Izuwa, Chioma Deborah Mbakaogu, Stanley Toochukwu Ekwueme. Investigation of Polysulfone Based Aluminium Oxide Coated Membrane for Separation of Crude Oil Emulsion in the Niger Delta. Am J Energy Eng. 2020;8(4):34-39. doi: 10.11648/j.ajee.20200804.11

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  • @article{10.11648/j.ajee.20200804.11,
      author = {Ngozi Claribelle Nwogu and Nkemakolam Chinedu Izuwa and Chioma Deborah Mbakaogu and Stanley Toochukwu Ekwueme},
      title = {Investigation of Polysulfone Based Aluminium Oxide Coated Membrane for Separation of Crude Oil Emulsion in the Niger Delta},
      journal = {American Journal of Energy Engineering},
      volume = {8},
      number = {4},
      pages = {34-39},
      doi = {10.11648/j.ajee.20200804.11},
      url = {https://doi.org/10.11648/j.ajee.20200804.11},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajee.20200804.11},
      abstract = {There is need for efficient separation of crude oil from its emulsion in oil and gas processes especially during production and refining activities. Among other methods used for crude oil emulsion demulsification, polymer membranes have attracted a lot of attention. The increasing interest in polymer membranes usage for ultrafiltration and micro filtration are mainly due to their versatility, efficiency and reduced operating cost when compared with conventional techniques such as use of chemical, flocculation etc. This paper illustrates experimental process for the separation of crude oil emulsion using Polysulfone membrane material coated with Aluminium oxide nanoparticle. The crude oil emulsion was prepared by mixing with distil water to obtain an oil in water emulsion. Because of the oleophilicity of Polysulfone membrane materials in oil/water separation, aluminum nanoparticles were used as metallic coatings to their Polysulfone membrane to improve efficiency and anti-fouling characteristics. Three parametres were investigated in the results, these include the separation efficiency in terms of oil rejection, the permeation flux, the filtrate volume for pressure application of 80% stroke and 60% stroke. The augmented membrane construction yields 98.5% and 97.6% efficiency in terms of oil rejection for a pressure application of 60% stroke and 80% stroke respectively while the permeation fluxes are 0.911 ml/cm2-min and 1.024 ml/cm2-min for 80% stroke and 60% stroke pressure application respectively.},
     year = {2020}
    }
    

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  • TY  - JOUR
    T1  - Investigation of Polysulfone Based Aluminium Oxide Coated Membrane for Separation of Crude Oil Emulsion in the Niger Delta
    AU  - Ngozi Claribelle Nwogu
    AU  - Nkemakolam Chinedu Izuwa
    AU  - Chioma Deborah Mbakaogu
    AU  - Stanley Toochukwu Ekwueme
    Y1  - 2020/12/16
    PY  - 2020
    N1  - https://doi.org/10.11648/j.ajee.20200804.11
    DO  - 10.11648/j.ajee.20200804.11
    T2  - American Journal of Energy Engineering
    JF  - American Journal of Energy Engineering
    JO  - American Journal of Energy Engineering
    SP  - 34
    EP  - 39
    PB  - Science Publishing Group
    SN  - 2329-163X
    UR  - https://doi.org/10.11648/j.ajee.20200804.11
    AB  - There is need for efficient separation of crude oil from its emulsion in oil and gas processes especially during production and refining activities. Among other methods used for crude oil emulsion demulsification, polymer membranes have attracted a lot of attention. The increasing interest in polymer membranes usage for ultrafiltration and micro filtration are mainly due to their versatility, efficiency and reduced operating cost when compared with conventional techniques such as use of chemical, flocculation etc. This paper illustrates experimental process for the separation of crude oil emulsion using Polysulfone membrane material coated with Aluminium oxide nanoparticle. The crude oil emulsion was prepared by mixing with distil water to obtain an oil in water emulsion. Because of the oleophilicity of Polysulfone membrane materials in oil/water separation, aluminum nanoparticles were used as metallic coatings to their Polysulfone membrane to improve efficiency and anti-fouling characteristics. Three parametres were investigated in the results, these include the separation efficiency in terms of oil rejection, the permeation flux, the filtrate volume for pressure application of 80% stroke and 60% stroke. The augmented membrane construction yields 98.5% and 97.6% efficiency in terms of oil rejection for a pressure application of 60% stroke and 80% stroke respectively while the permeation fluxes are 0.911 ml/cm2-min and 1.024 ml/cm2-min for 80% stroke and 60% stroke pressure application respectively.
    VL  - 8
    IS  - 4
    ER  - 

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Author Information
  • Department of Petroleum Engineering, Federal University of Technology, Owerri, Nigeria

  • Department of Petroleum Engineering, Federal University of Technology, Owerri, Nigeria

  • Department of Petroleum Engineering, Federal University of Technology, Owerri, Nigeria

  • Department of Petroleum Engineering, Federal University of Technology, Owerri, Nigeria

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