Heavy Metals Pollution Assessment of Asa River Sediments in Ilorin, Kwara State, Nigeria

Oluwadurotimi Olutosin Akintade; Gbemisola Elizabeth Ogunleye; Rotimi Oderinde; Abiodun Ogbesejana; Wasiu Bolade Agbaje

doi:doi:10.11648/j.ajaic.20220601.14

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Heavy Metals Pollution Assessment of Asa River Sediments in Ilorin, Kwara State, Nigeria

Oluwadurotimi Olutosin Akintade, Gbemisola Elizabeth Ogunleye, Rotimi Oderinde, Abiodun Ogbesejana, Wasiu Bolade Agbaje

Published in American Journal of Applied and Industrial Chemistry (Volume 6, Issue 1)

Received: 8 March 2022 Accepted: 31 March 2022 Published: 31 May 2022

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Abstract

Asa River sediment samples (26) were collected and analyse to determine seasonal concentrations, spatial and assessment contamination of heavy metals which includes Pb, Cu, Co, Cr, Ni, Zn, Al, Fe and Mn. The purpose of this research is to assess concentrations of heavy metals and degree of contamination in the Asa River sediments. The mean concentrations are as follows 0.75 mg/kg for Pb, 47.70 mg/kg for Cu, 34.88 mg/kg for Co, 54.35 mg/kg for Cr, 25.06 mg/kg for Ni, 34.70 mg/kg for Zn, 30.53 mg/kg for Al, 16.74 mg/kg for Fe and 11.84 mg/kg for Mn. To assess metal contamination in sediments, sediment quality guidelines were applied. The mean concentration of Cu and Co exceeded the USEPA guidelines. The metal contamination in the sediments was also evaluated by applying Enrichment Factor (EF), Contamination Factor (CF), Geoaccumulation Index (I_geo) and Pollution Load Index (PLI). Based on EF, the Asa River sediments have less deficiency for Pb, Cr, Ni, Zn, Al, Fe and Mn while Cu and Co have moderate enrichment. According to CF: Cu, Co, Cr, Zn and Al have moderate contamination while Pb, Ni, Fe and Mn have low contamination. According to I_geo, the Asa River sediments are unpolluted to moderately polluted. Based on PLI, most sampling sites suggest no overall pollution of site quality.

Published in	American Journal of Applied and Industrial Chemistry (Volume 6, Issue 1)
DOI	10.11648/j.ajaic.20220601.14
Page(s)	20-30
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2022. Published by Science Publishing Group

Keywords

Asa River Sediments, Contamination Factor, Heavy Metals, Pollution

References

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APA Style

Oluwadurotimi Olutosin Akintade, Gbemisola Elizabeth Ogunleye, Rotimi Oderinde, Abiodun Ogbesejana, Wasiu Bolade Agbaje. (2022). Heavy Metals Pollution Assessment of Asa River Sediments in Ilorin, Kwara State, Nigeria. American Journal of Applied and Industrial Chemistry, 6(1), 20-30. https://doi.org/10.11648/j.ajaic.20220601.14

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ACS Style

Oluwadurotimi Olutosin Akintade; Gbemisola Elizabeth Ogunleye; Rotimi Oderinde; Abiodun Ogbesejana; Wasiu Bolade Agbaje. Heavy Metals Pollution Assessment of Asa River Sediments in Ilorin, Kwara State, Nigeria. Am. J. Appl. Ind. Chem. 2022, 6(1), 20-30. doi: 10.11648/j.ajaic.20220601.14

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AMA Style

Oluwadurotimi Olutosin Akintade, Gbemisola Elizabeth Ogunleye, Rotimi Oderinde, Abiodun Ogbesejana, Wasiu Bolade Agbaje. Heavy Metals Pollution Assessment of Asa River Sediments in Ilorin, Kwara State, Nigeria. Am J Appl Ind Chem. 2022;6(1):20-30. doi: 10.11648/j.ajaic.20220601.14

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@article{10.11648/j.ajaic.20220601.14,
  author = {Oluwadurotimi Olutosin Akintade and Gbemisola Elizabeth Ogunleye and Rotimi Oderinde and Abiodun Ogbesejana and Wasiu Bolade Agbaje},
  title = {Heavy Metals Pollution Assessment of Asa River Sediments in Ilorin, Kwara State, Nigeria},
  journal = {American Journal of Applied and Industrial Chemistry},
  volume = {6},
  number = {1},
  pages = {20-30},
  doi = {10.11648/j.ajaic.20220601.14},
  url = {https://doi.org/10.11648/j.ajaic.20220601.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajaic.20220601.14},
  abstract = {Asa River sediment samples (26) were collected and analyse to determine seasonal concentrations, spatial and assessment contamination of heavy metals which includes Pb, Cu, Co, Cr, Ni, Zn, Al, Fe and Mn. The purpose of this research is to assess concentrations of heavy metals and degree of contamination in the Asa River sediments. The mean concentrations are as follows 0.75 mg/kg for Pb, 47.70 mg/kg for Cu, 34.88 mg/kg for Co, 54.35 mg/kg for Cr, 25.06 mg/kg for Ni, 34.70 mg/kg for Zn, 30.53 mg/kg for Al, 16.74 mg/kg for Fe and 11.84 mg/kg for Mn. To assess metal contamination in sediments, sediment quality guidelines were applied. The mean concentration of Cu and Co exceeded the USEPA guidelines. The metal contamination in the sediments was also evaluated by applying Enrichment Factor (EF), Contamination Factor (CF), Geoaccumulation Index (Igeo) and Pollution Load Index (PLI). Based on EF, the Asa River sediments have less deficiency for Pb, Cr, Ni, Zn, Al, Fe and Mn while Cu and Co have moderate enrichment. According to CF: Cu, Co, Cr, Zn and Al have moderate contamination while Pb, Ni, Fe and Mn have low contamination. According to Igeo, the Asa River sediments are unpolluted to moderately polluted. Based on PLI, most sampling sites suggest no overall pollution of site quality.},
 year = {2022}
}

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TY - JOUR
T1 - Heavy Metals Pollution Assessment of Asa River Sediments in Ilorin, Kwara State, Nigeria
AU - Oluwadurotimi Olutosin Akintade
AU - Gbemisola Elizabeth Ogunleye
AU - Rotimi Oderinde
AU - Abiodun Ogbesejana
AU - Wasiu Bolade Agbaje
Y1 - 2022/05/31
PY - 2022
N1 - https://doi.org/10.11648/j.ajaic.20220601.14
DO - 10.11648/j.ajaic.20220601.14
T2 - American Journal of Applied and Industrial Chemistry
JF - American Journal of Applied and Industrial Chemistry
JO - American Journal of Applied and Industrial Chemistry
SP - 20
EP - 30
PB - Science Publishing Group
SN - 2994-7294
UR - https://doi.org/10.11648/j.ajaic.20220601.14
AB - Asa River sediment samples (26) were collected and analyse to determine seasonal concentrations, spatial and assessment contamination of heavy metals which includes Pb, Cu, Co, Cr, Ni, Zn, Al, Fe and Mn. The purpose of this research is to assess concentrations of heavy metals and degree of contamination in the Asa River sediments. The mean concentrations are as follows 0.75 mg/kg for Pb, 47.70 mg/kg for Cu, 34.88 mg/kg for Co, 54.35 mg/kg for Cr, 25.06 mg/kg for Ni, 34.70 mg/kg for Zn, 30.53 mg/kg for Al, 16.74 mg/kg for Fe and 11.84 mg/kg for Mn. To assess metal contamination in sediments, sediment quality guidelines were applied. The mean concentration of Cu and Co exceeded the USEPA guidelines. The metal contamination in the sediments was also evaluated by applying Enrichment Factor (EF), Contamination Factor (CF), Geoaccumulation Index (Igeo) and Pollution Load Index (PLI). Based on EF, the Asa River sediments have less deficiency for Pb, Cr, Ni, Zn, Al, Fe and Mn while Cu and Co have moderate enrichment. According to CF: Cu, Co, Cr, Zn and Al have moderate contamination while Pb, Ni, Fe and Mn have low contamination. According to Igeo, the Asa River sediments are unpolluted to moderately polluted. Based on PLI, most sampling sites suggest no overall pollution of site quality.
VL - 6
IS - 1
ER -

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Author Information

Oluwadurotimi Olutosin Akintade

Department of Chemical Sciences, Faculty of Applied Sciences, KolaDaisi University, Ibadan, Nigeria
Gbemisola Elizabeth Ogunleye

Department of Biological Sciences, Faculty of Applied Sciences, KolaDaisi University, Ibadan, Nigeria
Rotimi Oderinde

Department of Chemistry, University of Ibadan, Ibadan, Nigeria
Abiodun Ogbesejana

Department of Applied Chemistry, Federal University Dutsin-ma, Dutsin-ma, Nigeria
Wasiu Bolade Agbaje

Department of Pure and Applied Chemistry, Osun State University, Osogbo, Nigeria

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Oluwadurotimi Olutosin Akintade, Gbemisola Elizabeth Ogunleye, Rotimi Oderinde, Abiodun Ogbesejana, Wasiu Bolade Agbaje. (2022). Heavy Metals Pollution Assessment of Asa River Sediments in Ilorin, Kwara State, Nigeria. American Journal of Applied and Industrial Chemistry, 6(1), 20-30. https://doi.org/10.11648/j.ajaic.20220601.14

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Oluwadurotimi Olutosin Akintade; Gbemisola Elizabeth Ogunleye; Rotimi Oderinde; Abiodun Ogbesejana; Wasiu Bolade Agbaje. Heavy Metals Pollution Assessment of Asa River Sediments in Ilorin, Kwara State, Nigeria. Am. J. Appl. Ind. Chem. 2022, 6(1), 20-30. doi: 10.11648/j.ajaic.20220601.14

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AMA Style

Oluwadurotimi Olutosin Akintade, Gbemisola Elizabeth Ogunleye, Rotimi Oderinde, Abiodun Ogbesejana, Wasiu Bolade Agbaje. Heavy Metals Pollution Assessment of Asa River Sediments in Ilorin, Kwara State, Nigeria. Am J Appl Ind Chem. 2022;6(1):20-30. doi: 10.11648/j.ajaic.20220601.14

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@article{10.11648/j.ajaic.20220601.14,
  author = {Oluwadurotimi Olutosin Akintade and Gbemisola Elizabeth Ogunleye and Rotimi Oderinde and Abiodun Ogbesejana and Wasiu Bolade Agbaje},
  title = {Heavy Metals Pollution Assessment of Asa River Sediments in Ilorin, Kwara State, Nigeria},
  journal = {American Journal of Applied and Industrial Chemistry},
  volume = {6},
  number = {1},
  pages = {20-30},
  doi = {10.11648/j.ajaic.20220601.14},
  url = {https://doi.org/10.11648/j.ajaic.20220601.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajaic.20220601.14},
  abstract = {Asa River sediment samples (26) were collected and analyse to determine seasonal concentrations, spatial and assessment contamination of heavy metals which includes Pb, Cu, Co, Cr, Ni, Zn, Al, Fe and Mn. The purpose of this research is to assess concentrations of heavy metals and degree of contamination in the Asa River sediments. The mean concentrations are as follows 0.75 mg/kg for Pb, 47.70 mg/kg for Cu, 34.88 mg/kg for Co, 54.35 mg/kg for Cr, 25.06 mg/kg for Ni, 34.70 mg/kg for Zn, 30.53 mg/kg for Al, 16.74 mg/kg for Fe and 11.84 mg/kg for Mn. To assess metal contamination in sediments, sediment quality guidelines were applied. The mean concentration of Cu and Co exceeded the USEPA guidelines. The metal contamination in the sediments was also evaluated by applying Enrichment Factor (EF), Contamination Factor (CF), Geoaccumulation Index (Igeo) and Pollution Load Index (PLI). Based on EF, the Asa River sediments have less deficiency for Pb, Cr, Ni, Zn, Al, Fe and Mn while Cu and Co have moderate enrichment. According to CF: Cu, Co, Cr, Zn and Al have moderate contamination while Pb, Ni, Fe and Mn have low contamination. According to Igeo, the Asa River sediments are unpolluted to moderately polluted. Based on PLI, most sampling sites suggest no overall pollution of site quality.},
 year = {2022}
}

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