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Physico-chemical Analysis of Effluent Samples from Hermas Paint Industry Enugwu-Ukwu, Anambra State

Received: 28 April 2021     Accepted: 2 June 2021     Published: 16 June 2021
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Abstract

Hermas Paint Industry limited, Enugwu-ukwu, Anambra State, Nigeria is a polymer based industry that produces different types of paint from raw materials. Several hazardous and non-hazardous waste loads are produced during the paint manufacturing processes. Effluent generated by paint industries is one of the sources of pollution. Air, soil and water contaminated by effluent from the paint industry are associated with heavy disease burden resulting in short lifespan. Ground water and surface water contamination are also detrimental to health as aquatic life is jeopardized and in return, man is jeopardized. The aim of this work is to study the physico-chemical and Fourier Transform Infra-red (FTIR) analyses of effluent samples from the industry. The concentrations of the physico-chemical parameters were determined for three sampling periods: August, September and October, 2014, using standard chemical methods and Atomic Absorption Spectrophotometer (AAS). The Fourier Transform Infra-red analysis (FTIR) of the effluent samples was used to detect the organic functional groups present in the samples. The results obtained showed that the concentration of the mean physico-chemical parameters such as odour, pH, temperature, TDS, TSS, DO, CO32-, OH-, HCO3-, Cl-, NO3-, SO42- acidity and total alkalinity, cobalt, sodium, zinc, and calcium are within the recommended limits for WHO and NESREA with the exception of BOD, COD, TS, total hardness, cadmium, iron, lead, mercury, arsenic and chromium, some of which are slightly above the accepted limits, resulting in adverse effects on human health, plants and animals. The results of FTIR analysis showed the presence of the following functional groups: C– H of benzene, C=O stretch of amides, N-H, C-H stretch for amide and nitriles and O-H stretch for H- bond in alcohol and phenol and then N-H stretch of amides. Therefore, adequate and continuous monitoring should be conducted so as to prevent the bioaccumulation of waste loads which could be detrimental to human health. The WHO and NESREA should ensure that the effluents are well-treated so that the parameters remain within the permissible limits.

Published in American Journal of Applied and Industrial Chemistry (Volume 5, Issue 1)
DOI 10.11648/j.ajaic.20210501.14
Page(s) 22-26
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2021. Published by Science Publishing Group

Keywords

Physico-Chemical, Analysis, Effluent Samples, Hermas Paint

References
[1] World Health Organization (WHO) (2002). Guidelines for Drinking Water Quality Recommendation, 2nd Ed., Geneva, 3: 86-88.
[2] World Health Organization (WHO) (2003). Guideline for Drinking Water Quality. World Health Organization, Geneva, pp 112-123.
[3] Ezeonu E. (2003). Pollution and Industrial Wastes Management, Chemistry in Nigeria, 2 (2): 17-20.
[4] Onuegbu T. U; Ajiwe V. I. E; Arinze R. U. and Okoye, L. O. (2007). Analysis of Untreated Effluents from Guinness Breweries in Nigeria. Journal of Applied Sciences. 10 (4): 7466-7473.
[5] Onuegbu T. U., Umoh E. T and Onwukwe I. T. (2013). Physico-Chemical Analysis of Effluents from Jacbon Chemical Industries Limited, Makers of Bonalux Emulsion and Gloss Paints. Int. J. of Sci. and Technol 2 (2): 169-173.
[6] Womach, J. (2005). Water Supply and Sanitation in the United States. Congressional Research Service Document. CWA Sections 301, 306 and 307.
[7] Sangodeyin, A. Y. (1995). Characteristics and Control of Industrial Effluents-generating Pollution. Journal of Environmental Management and Health. 6 (4): 15-18.
[8] Ezeonu, E. (2005). Chemistry and Nigeria Economy, the Proceedings of the 28th International Conference of the Chemical Society of Nigeria. 2 (1): 6-8.
[9] Ajiwe V. I. E., Nnabuike B. O., Onochie C. C. and Ajibola J. O. (2005). Surface Water Pollution by Effluent from Industries in Nnewi Area, Journal of Applied Sciences, 3 (3): 1235-1280.
[10] Okonkwo, E. M. and Eboatu, A. N (1999). Environmental Pollution and Degradation, book 2, Onis Excel Publishing Ltd. Zaria, pp 2-81, 113-140.
[11] Programme of Chemical Society (PCS) (2001) Water Related Diseases, Geneva.
[12] Needlemana, H. L. and Bellingerc, D. (2001). Studies of Lead Exposure and the Developing Central nervous system: A reply to Kanfman. Arah. Clin. Neuropsych. 16 (4): 359-374.
[13] Howard, H. M. D, M. P. H, S. D (2002). Human Health and Heavy Metal Exposure, MIT Publication.
[14] Ademoroti, C. M. A (1998). Standard method for Water and Effluent Analysis, Fodulex Press Ltd. Ibadan, pp 20-121.
[15] American Public Health Association (APHA) (1998). Standard methods for the Examination of the Water and Waste Water: 20th Edition; American Public Health Association, pp 230-256.
[16] Eboagu N. C, Ajiwe V. I. E, and Odidika C. C (2018); Physico-chemical Parameters of Water from Selected Boreholes utilized as portable Water, International Journal of Environmental Science and Technology 16 (14): 1-10.
[17] Malakootian, M; Almasi, A and Hossaini H. (2008) Pb and Cd Removal from Paint Industries Effluent Using Wood Ash. International Journal of Environment Science Technology. 5 (2): 217-222).
[18] Edori, O. S and Kpee, F.(2018). “Assessment of Heavy Metal Content in Water at Effluent Discharge Points into the New Calabar River, Port Harcourt Southern Nigeria, Glob. J. Sci. Front. Res (B) 18 (2): 52-58
[19] Azogu C. I (2010). Laboratory Organic Chemistry Techniques: Qualitative Analysis Organic Preparations and Spectroscopy, 2nd Edition. Pp 103-109.
[20] Eboagu N. C, Ajiwe V. I. E, Ochiagha K. E and Odidika C. C (2020). Elemental Assessment of Borehole Water in Njikoka Local Government Area of Anambra State, Nigeria. Anachem Journal. 10 (1). 1881-1891.
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    Ebele Joy Morah, Theresa Uzoma Onuegbu, Priscilla Chinwe Okonkwo, Blessing Chidimma Ikezuagu, Nkiruka Charity Eboagu, et al. (2021). Physico-chemical Analysis of Effluent Samples from Hermas Paint Industry Enugwu-Ukwu, Anambra State. American Journal of Applied and Industrial Chemistry, 5(1), 22-26. https://doi.org/10.11648/j.ajaic.20210501.14

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    ACS Style

    Ebele Joy Morah; Theresa Uzoma Onuegbu; Priscilla Chinwe Okonkwo; Blessing Chidimma Ikezuagu; Nkiruka Charity Eboagu, et al. Physico-chemical Analysis of Effluent Samples from Hermas Paint Industry Enugwu-Ukwu, Anambra State. Am. J. Appl. Ind. Chem. 2021, 5(1), 22-26. doi: 10.11648/j.ajaic.20210501.14

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    AMA Style

    Ebele Joy Morah, Theresa Uzoma Onuegbu, Priscilla Chinwe Okonkwo, Blessing Chidimma Ikezuagu, Nkiruka Charity Eboagu, et al. Physico-chemical Analysis of Effluent Samples from Hermas Paint Industry Enugwu-Ukwu, Anambra State. Am J Appl Ind Chem. 2021;5(1):22-26. doi: 10.11648/j.ajaic.20210501.14

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  • @article{10.11648/j.ajaic.20210501.14,
      author = {Ebele Joy Morah and Theresa Uzoma Onuegbu and Priscilla Chinwe Okonkwo and Blessing Chidimma Ikezuagu and Nkiruka Charity Eboagu and Ozioma Juliana Anekwe},
      title = {Physico-chemical Analysis of Effluent Samples from Hermas Paint Industry Enugwu-Ukwu, Anambra State},
      journal = {American Journal of Applied and Industrial Chemistry},
      volume = {5},
      number = {1},
      pages = {22-26},
      doi = {10.11648/j.ajaic.20210501.14},
      url = {https://doi.org/10.11648/j.ajaic.20210501.14},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajaic.20210501.14},
      abstract = {Hermas Paint Industry limited, Enugwu-ukwu, Anambra State, Nigeria is a polymer based industry that produces different types of paint from raw materials. Several hazardous and non-hazardous waste loads are produced during the paint manufacturing processes. Effluent generated by paint industries is one of the sources of pollution. Air, soil and water contaminated by effluent from the paint industry are associated with heavy disease burden resulting in short lifespan. Ground water and surface water contamination are also detrimental to health as aquatic life is jeopardized and in return, man is jeopardized. The aim of this work is to study the physico-chemical and Fourier Transform Infra-red (FTIR) analyses of effluent samples from the industry. The concentrations of the physico-chemical parameters were determined for three sampling periods: August, September and October, 2014, using standard chemical methods and Atomic Absorption Spectrophotometer (AAS). The Fourier Transform Infra-red analysis (FTIR) of the effluent samples was used to detect the organic functional groups present in the samples. The results obtained showed that the concentration of the mean physico-chemical parameters such as odour, pH, temperature, TDS, TSS, DO, CO32-, OH-, HCO3-, Cl-, NO3-, SO42- acidity and total alkalinity, cobalt, sodium, zinc, and calcium are within the recommended limits for WHO and NESREA with the exception of BOD, COD, TS, total hardness, cadmium, iron, lead, mercury, arsenic and chromium, some of which are slightly above the accepted limits, resulting in adverse effects on human health, plants and animals. The results of FTIR analysis showed the presence of the following functional groups: C– H of benzene, C=O stretch of amides, N-H, C-H stretch for amide and nitriles and O-H stretch for H- bond in alcohol and phenol and then N-H stretch of amides. Therefore, adequate and continuous monitoring should be conducted so as to prevent the bioaccumulation of waste loads which could be detrimental to human health. The WHO and NESREA should ensure that the effluents are well-treated so that the parameters remain within the permissible limits.},
     year = {2021}
    }
    

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  • TY  - JOUR
    T1  - Physico-chemical Analysis of Effluent Samples from Hermas Paint Industry Enugwu-Ukwu, Anambra State
    AU  - Ebele Joy Morah
    AU  - Theresa Uzoma Onuegbu
    AU  - Priscilla Chinwe Okonkwo
    AU  - Blessing Chidimma Ikezuagu
    AU  - Nkiruka Charity Eboagu
    AU  - Ozioma Juliana Anekwe
    Y1  - 2021/06/16
    PY  - 2021
    N1  - https://doi.org/10.11648/j.ajaic.20210501.14
    DO  - 10.11648/j.ajaic.20210501.14
    T2  - American Journal of Applied and Industrial Chemistry
    JF  - American Journal of Applied and Industrial Chemistry
    JO  - American Journal of Applied and Industrial Chemistry
    SP  - 22
    EP  - 26
    PB  - Science Publishing Group
    SN  - 2994-7294
    UR  - https://doi.org/10.11648/j.ajaic.20210501.14
    AB  - Hermas Paint Industry limited, Enugwu-ukwu, Anambra State, Nigeria is a polymer based industry that produces different types of paint from raw materials. Several hazardous and non-hazardous waste loads are produced during the paint manufacturing processes. Effluent generated by paint industries is one of the sources of pollution. Air, soil and water contaminated by effluent from the paint industry are associated with heavy disease burden resulting in short lifespan. Ground water and surface water contamination are also detrimental to health as aquatic life is jeopardized and in return, man is jeopardized. The aim of this work is to study the physico-chemical and Fourier Transform Infra-red (FTIR) analyses of effluent samples from the industry. The concentrations of the physico-chemical parameters were determined for three sampling periods: August, September and October, 2014, using standard chemical methods and Atomic Absorption Spectrophotometer (AAS). The Fourier Transform Infra-red analysis (FTIR) of the effluent samples was used to detect the organic functional groups present in the samples. The results obtained showed that the concentration of the mean physico-chemical parameters such as odour, pH, temperature, TDS, TSS, DO, CO32-, OH-, HCO3-, Cl-, NO3-, SO42- acidity and total alkalinity, cobalt, sodium, zinc, and calcium are within the recommended limits for WHO and NESREA with the exception of BOD, COD, TS, total hardness, cadmium, iron, lead, mercury, arsenic and chromium, some of which are slightly above the accepted limits, resulting in adverse effects on human health, plants and animals. The results of FTIR analysis showed the presence of the following functional groups: C– H of benzene, C=O stretch of amides, N-H, C-H stretch for amide and nitriles and O-H stretch for H- bond in alcohol and phenol and then N-H stretch of amides. Therefore, adequate and continuous monitoring should be conducted so as to prevent the bioaccumulation of waste loads which could be detrimental to human health. The WHO and NESREA should ensure that the effluents are well-treated so that the parameters remain within the permissible limits.
    VL  - 5
    IS  - 1
    ER  - 

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Author Information
  • Department of Pure and Industrial Chemistry, Nnamdi Azikiwe University, Awka, Nigeria

  • Department of Pure and Industrial Chemistry, Nnamdi Azikiwe University, Awka, Nigeria

  • Department of Pure and Industrial Chemistry, Nnamdi Azikiwe University, Awka, Nigeria

  • Department of Pure and Industrial Chemistry, Nnamdi Azikiwe University, Awka, Nigeria

  • Department of Pure and Industrial Chemistry, Nnamdi Azikiwe University, Awka, Nigeria

  • Department of Pure and Industrial Chemistry, Nnamdi Azikiwe University, Awka, Nigeria

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