Polysaccharide-based hydrogels act like smart materials and exhibit a wide range of properties that can be utilized for several applications. Polysaccharide-based super water absorbent (SWA) hydrogel was prepared from an aqueous solution of carboxymethylcellulose (CMC)/acrylamide (AAm) Using gamma radiation from a Co-60 gamma source at room temperature (~27°C). Functional groups of the prepared hydrogel were characterized in terms of Fourier Transform Infrared Spectroscopy-Attenuated Total Reflectance (FTIR-ATR). The swelling of the SWA in water and the saline solutions (NaCl, CaCl2, and AlCl3) was examined. It was found that the swelling value of the SWA in water is higher (27900%) than those of in the saline solutions (2074% in NaCl, 1718% in CaCl2 and 796% in AlCl3). Results also indicated that the swelling capacity of SWA in saline solution decreases with an increased charge of cation in salt. Swelling ratio in NaCl solution was the highest which was 26, followed by 12.48 in CaCl2 and 6.22 in AlCl3 solution. A comparative swelling study was done by changing the cationic size of the same group elements (between KCl and NaCl). This study suggested that the swelling of the SWA depends upon the cationic size. Compared to the swelling of 2074% in NaCl solution, the swelling in KCl was found to be slightly higher (2442%). This behavior can be attributed to the charge screening effect for monovalent cations, as well as the ionic crosslinking of the SWA with the multivalent cations.
| Published in | American Journal of Applied and Industrial Chemistry (Volume 2, Issue 2) |
| DOI | 10.11648/j.ajaic.20180202.13 |
| Page(s) | 20-26 |
| Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
| Copyright |
Copyright © The Author(s), 2018. Published by Science Publishing Group |
Hydrogel, Carboxymethylcellulose, Swelling, Super Water Absorbent, Radiation
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APA Style
Salma Sultana, Md. Saifur Rahaman, Shah Md. Marzuk Hasnine. (2018). Effect of Salinity on Swelling Behaviors of Superwater Absorbent Hydrogel Prepared from Carboxymethyl cellulose/Acrylamide Blends by Gamma Radiation. American Journal of Applied and Industrial Chemistry, 2(2), 20-26. https://doi.org/10.11648/j.ajaic.20180202.13
ACS Style
Salma Sultana; Md. Saifur Rahaman; Shah Md. Marzuk Hasnine. Effect of Salinity on Swelling Behaviors of Superwater Absorbent Hydrogel Prepared from Carboxymethyl cellulose/Acrylamide Blends by Gamma Radiation. Am. J. Appl. Ind. Chem. 2018, 2(2), 20-26. doi: 10.11648/j.ajaic.20180202.13
AMA Style
Salma Sultana, Md. Saifur Rahaman, Shah Md. Marzuk Hasnine. Effect of Salinity on Swelling Behaviors of Superwater Absorbent Hydrogel Prepared from Carboxymethyl cellulose/Acrylamide Blends by Gamma Radiation. Am J Appl Ind Chem. 2018;2(2):20-26. doi: 10.11648/j.ajaic.20180202.13
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Download@article{10.11648/j.ajaic.20180202.13,
author = {Salma Sultana and Md. Saifur Rahaman and Shah Md. Marzuk Hasnine},
title = {Effect of Salinity on Swelling Behaviors of Superwater Absorbent Hydrogel Prepared from Carboxymethyl cellulose/Acrylamide Blends by Gamma Radiation},
journal = {American Journal of Applied and Industrial Chemistry},
volume = {2},
number = {2},
pages = {20-26},
doi = {10.11648/j.ajaic.20180202.13},
url = {https://doi.org/10.11648/j.ajaic.20180202.13},
eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajaic.20180202.13},
abstract = {Polysaccharide-based hydrogels act like smart materials and exhibit a wide range of properties that can be utilized for several applications. Polysaccharide-based super water absorbent (SWA) hydrogel was prepared from an aqueous solution of carboxymethylcellulose (CMC)/acrylamide (AAm) Using gamma radiation from a Co-60 gamma source at room temperature (~27°C). Functional groups of the prepared hydrogel were characterized in terms of Fourier Transform Infrared Spectroscopy-Attenuated Total Reflectance (FTIR-ATR). The swelling of the SWA in water and the saline solutions (NaCl, CaCl2, and AlCl3) was examined. It was found that the swelling value of the SWA in water is higher (27900%) than those of in the saline solutions (2074% in NaCl, 1718% in CaCl2 and 796% in AlCl3). Results also indicated that the swelling capacity of SWA in saline solution decreases with an increased charge of cation in salt. Swelling ratio in NaCl solution was the highest which was 26, followed by 12.48 in CaCl2 and 6.22 in AlCl3 solution. A comparative swelling study was done by changing the cationic size of the same group elements (between KCl and NaCl). This study suggested that the swelling of the SWA depends upon the cationic size. Compared to the swelling of 2074% in NaCl solution, the swelling in KCl was found to be slightly higher (2442%). This behavior can be attributed to the charge screening effect for monovalent cations, as well as the ionic crosslinking of the SWA with the multivalent cations.},
year = {2018}
}
TY - JOUR T1 - Effect of Salinity on Swelling Behaviors of Superwater Absorbent Hydrogel Prepared from Carboxymethyl cellulose/Acrylamide Blends by Gamma Radiation AU - Salma Sultana AU - Md. Saifur Rahaman AU - Shah Md. Marzuk Hasnine Y1 - 2018/10/25 PY - 2018 N1 - https://doi.org/10.11648/j.ajaic.20180202.13 DO - 10.11648/j.ajaic.20180202.13 T2 - American Journal of Applied and Industrial Chemistry JF - American Journal of Applied and Industrial Chemistry JO - American Journal of Applied and Industrial Chemistry SP - 20 EP - 26 PB - Science Publishing Group SN - 2994-7294 UR - https://doi.org/10.11648/j.ajaic.20180202.13 AB - Polysaccharide-based hydrogels act like smart materials and exhibit a wide range of properties that can be utilized for several applications. Polysaccharide-based super water absorbent (SWA) hydrogel was prepared from an aqueous solution of carboxymethylcellulose (CMC)/acrylamide (AAm) Using gamma radiation from a Co-60 gamma source at room temperature (~27°C). Functional groups of the prepared hydrogel were characterized in terms of Fourier Transform Infrared Spectroscopy-Attenuated Total Reflectance (FTIR-ATR). The swelling of the SWA in water and the saline solutions (NaCl, CaCl2, and AlCl3) was examined. It was found that the swelling value of the SWA in water is higher (27900%) than those of in the saline solutions (2074% in NaCl, 1718% in CaCl2 and 796% in AlCl3). Results also indicated that the swelling capacity of SWA in saline solution decreases with an increased charge of cation in salt. Swelling ratio in NaCl solution was the highest which was 26, followed by 12.48 in CaCl2 and 6.22 in AlCl3 solution. A comparative swelling study was done by changing the cationic size of the same group elements (between KCl and NaCl). This study suggested that the swelling of the SWA depends upon the cationic size. Compared to the swelling of 2074% in NaCl solution, the swelling in KCl was found to be slightly higher (2442%). This behavior can be attributed to the charge screening effect for monovalent cations, as well as the ionic crosslinking of the SWA with the multivalent cations. VL - 2 IS - 2 ER -
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